The DOI matches its Crossref record; 41 of the 41 references it cites were found in a registry or an index.
On the Dynamics of Charging in Nanoporous Carbon-Based Supercapacitors
Open accessAbstract
Supercapacitors are electricity storage systems with high power performances. Their short charge/discharge times are due to fast adsorption/desorption rates for the ions of the electrolyte on the electrode surface. Nanoporous carbon electrodes, which give larger capacitances than simpler geometries, might be expected to show poorer power performances because of the longer times taken by the ions to access the electrode interior. Experiments do not show such trends, however, and this remains to be explained at the molecular scale. Here we show that carbide-derived carbons exhibit heterogeneous and fast charging dynamics. We perform molecular dynamics simulations, with realistically modeled nanoporous electrodes and an ionic liquid electrolyte, in which the system, originally at equilibrium in the uncharged state, is suddenly perturbed by the application of an electric potential difference between the electrodes. The electrodes respond by charging progressively from the interface to the bulk as ions are exchanged between the nanopores and the electrolyte region. The simulation results are then injected into an equivalent circuit model, which allows us to calculate charging times for macroscopic-scale devices.
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Cites
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Simon, P., & Gogotsi, Y. (2008) · Nature Materials · doi:10.1038/nmat2297 · Cited by 16,427
Self-citationElectrochemical Supercapacitors : Scientific Fundamentals and Technological Applications
Conway, B. E. (2013) · CERN Document Server (European Organization for Nuclear Research) · Cited by 5,015
Electrochemical Capacitors for Energy Management
Miller, J. R., & Simon, P. (2008) · Science · doi:10.1126/science.1158736 · Cited by 4,831
Self-citationAnomalous Increase in Carbon Capacitance at Pore Sizes Less Than 1 Nanometer
Chmiola, J., Yushin, G., Gogotsi, Y., Portet, C., Simon, P., & Taberna, P. L. (2006) · Science · doi:10.1126/science.1132195 · Cited by 4,022
Self-citationElectrochemical Supercapacitors
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Relation between the Ion Size and Pore Size for an Electric Double-Layer Capacitor
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Self-citationElectrochemical Characteristics and Impedance Spectroscopy Studies of Carbon-Carbon Supercapacitors
Taberna, P. L., Simon, P., & Fauvarque, J. F. (2003) · Journal of The Electrochemical Society · doi:10.1149/1.1543948 · Cited by 1,998
Self-citationLiquid-Mediated Dense Integration of Graphene Materials for Compact Capacitive Energy Storage
Yang, X., Cheng, C., Wang, Y., Qiu, L., & Li, D. (2013) · Science · doi:10.1126/science.1239089 · Cited by 1,838
Cited by
Efficient storage mechanisms for building better supercapacitors
Salanne, M., Rotenberg, B., Naoi, K., Kaneko, K., Taberna, P.-L., Grey, C. P., Dunn, B., & Simon, P. (2016) · Nature Energy · doi:10.1038/nenergy.2016.70 · Cited by 2,181
Self-citationZhang, S., Zhang, J., Zhang, Y., & Deng, Y. (2017) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00509 · Cited by 659
Revitalizing carbon supercapacitor electrodes with hierarchical porous structures
Liu, T., Zhang, F., Song, Y., & Li, Y. (2017) · Journal of Materials Chemistry A · doi:10.1039/c7ta05646j · Cited by 621
Microscopic Simulations of Electrochemical Double-Layer Capacitors
Jeanmairet, G., Rotenberg, B., & Salanne, M. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00925 · Cited by 303
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Metadata
- Authors
- Péan, C., Merlet, C., Rotenberg, B., Madden, P. A., Taberna, P.-L., Daffos, B., Salanne, M., & Simon, P.
- Venue
- ACS Nano
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-01-15
- Volume
- 8
- Issue
- 2
- Pages
- 1576-1583
- ISSN
- 1936-0851 (ISSN-L)
- 1936-086X
- OpenAlex
- W1998873401
- Cited by
- 253
- References
- 41
- FWCI
- 7.74
- Type
- journal article
- Language
- en
- Open access
- green
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