The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Role of Chloride in the Morphological Evolution of Organo-Lead Halide Perovskite Thin Films
Abstract
A comprehensive morphological study was used to elucidate chloride's role in CH(3)NH(3)PbI(3-x)Cl(x) film evolution on a conducting polymer, PEDOT:PSS. Complex ion equilibria and aggregation in solution, as well as the role they play in nucleation, are found to ultimately be responsible for the unique morphological diversity observed in perovskite films grown in the presence of the chloride ion. An intermediate phase that is generated upon deposition and initial annealing templates continued self-assembly in the case of CH(3)NH(3)PbI(3-x)Cl(x). In the absence of chloride, the film growth of CH(3)NH(3)PbI(3) is directed by substrate interfacial energy. By employing the through-plane TEM analysis, we gain detailed insight into the unique crystallographic textures, grain structures, and elemental distributions across the breadth of films grown from precursor solutions with different chemistries. The lattice coherence seen in morphologies generated under the influence of chloride provides a physical rational for the enhancement in carrier diffusion length and lifetime.
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Stranks, S. D., Eperon, G. E., Grancini, G., Menelaou, C., Alcocer, M. J. P., Leijtens, T., Herz, L. M., Petrozza, A., & Snaith, H. J. (2013) · Science · doi:10.1126/science.1243982 · Cited by 10,413
Kim, H.-S., Lee, C.-R., Im, J.-H., Lee, K.-B., Moehl, T., Marchioro, A., Moon, S.-J., Humphry-Baker, R., Yum, J.-H., Moser, J. E., et al. (2012) · Scientific Reports · doi:10.1038/srep00591 · Cited by 8,092
Cited by
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Stranks, S. D., & Snaith, H. J. (2015) · Nature Nanotechnology · doi:10.1038/nnano.2015.90 · Cited by 3,392
Impact of microstructure on local carrier lifetime in perovskite solar cells
de Quilettes, D. W., Vorpahl, S. M., Stranks, S. D., Nagaoka, H., Eperon, G. E., Ziffer, M. E., Snaith, H. J., & Ginger, D. S. (2015) · Science · doi:10.1126/science.aaa5333 · Cited by 2,198
Trap States in Lead Iodide Perovskites
Wu, X., Trinh, M. T., Niesner, D., Zhu, H., Norman, Z., Owen, J. S., Yaffe, O., Kudisch, B. J., & Zhu, X.-Y. (2015) · Journal of the American Chemical Society · doi:10.1021/ja512833n · Cited by 988
Causes and Solutions of Recombination in Perovskite Solar Cells
Chen, J., & Park, N. (2019) · Advanced Materials · doi:10.1002/adma.201803019 · Cited by 733
The Importance of Moisture in Hybrid Lead Halide Perovskite Thin Film Fabrication
Eperon, G. E., Habisreutinger, S. N., Leijtens, T., Bruijnaers, B. J., van Franeker, J. J., deQuilettes, D. W., Pathak, S., Sutton, R. J., Grancini, G., Ginger, D. S., et al. (2015) · ACS Nano · doi:10.1021/acsnano.5b03626 · Cited by 574
Metadata
- Authors
- Williams, S. T., Zuo, F., Chueh, C.-C., Liao, C.-Y., Liang, P.-W., & Jen, A. K.-Y.
- Venue
- ACS Nano
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-10-09
- Volume
- 8
- Issue
- 10
- Pages
- 10640-10654
- ISSN
- 1936-0851 (ISSN-L)
- 1936-086X
- OpenAlex
- W2313540142
- Cited by
- 385
- References
- 2
- FWCI
- 34.14
- Type
- journal article
- Language
- en
- Open access
- closed
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