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Cited by 300

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Raman Modes of MoS2 Used as Fingerprint of van der Waals Interactions in 2-D Crystal-Based Heterostructures

Zhou, Kai-Ge, Withers, Freddie, Cao, Yang, Hu, Sheng, Yu, Geliang, Casiraghi, Cinzia·2014·ACS Nano

Abstract

In this work, we use Raman spectroscopy as a nondestructive and rapid technique for probing the van der Waals (vdW) forces acting between two atomically thin crystals, where one is a transition metal dichalcogenide (TMDC). In this work, MoS2 is used as a Raman probe: we show that its two Raman-active phonon modes can provide information on the interaction between the two crystals. In particular, the in-plane vibration (E2g(1)) provides information on the in-plane strain, while the out-of-plane mode (A1g) gives evidence for the quality of the interfacial contact. We show that a vdW contact with MoS2 is characterized by a blue shift of +2 cm(-1) of the A1g peak. In the case of a MoS2/graphene heterostructure, the vdW contact is also characterized by a shift of +14 cm(-1) of the 2D peak of graphene. Our approach offers a very simple, nondestructive, and fast method to characterize the quality of the interface of heterostructures containing atomically thick TMDC crystals.

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Metadata

Authors
Zhou, K.-G., Withers, F., Cao, Y., Hu, S., Yu, G., & Casiraghi, C.
Venue
ACS Nano
Published
2014-09-17
Volume
8
Issue
10
Pages
9914-9924
ISSN
  • 1936-0851 (ISSN-L)
  • 1936-086X
OpenAlex
W2149112880
Cited by
300
References
2
FWCI
8.49
Type
journal article
Language
en
Open access
closed

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