The DOI matches its Crossref record; 27 of the 27 references it cites were found in a registry or an index.
Excellent Performance in Lithium-Ion Battery Anodes: Rational Synthesis of Co(CO3)0.5(OH)0.11H2O Nanobelt Array and Its Conversion into Mesoporous and Single-Crystal Co3O4
Abstract
Herein, we report a rational method to synthesize a Co3O4 nanobelt array on a conducting substrate and functionalize it in the application of Li-ion battery anodes, which is a novel and facile approach to access the nanobelt array of transition metal oxides. Compared to the previous reports, the as-prepared samples in our experiments exhibited both mesoporosity and single-crystallinity, and meanwhile, good contact with the conducting substrate (via a thin layer of TiO2) provided an express pathway for charge transfer when they were applied in Li-ion batteries without any need to add other ancillary materials (carbon black or binder) to enhance the system's conductivity and stability. Under the condition of high charge-discharge current density of 177 mA/g in Li-ion batteries' testing, the Co3O4 nanobelt array was capable of retaining the specific capacity of 770 mAh/g over 25 cycles. Moreover, even though the charge-discharge rates were increased to 1670 and 3350 mA/g, it still could have reached the stable retention of the specific capacity of 510 and 330 mAh/g beyond 30 cycles, respectively, indicating an obtainable excellent rate capability. More importantly, the improved performance in Li-ion battery testing was definitely ascribed to the unique structures in our samples after elaborate analysis. So the final conclusion would be given that the lab-synthesized Co3O4 nanobelt array potentially could be a highly qualified candidate for Li-ion battery anodes in some practical fields, where high capacity and good capability are strictly required.
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Metadata
- Authors
- Wang, Y., Xia, H., Lu, L., & Lin, J.
- Venue
- ACS Nano
- Publisher
- American Chemical Society (ACS)
- Published
- 2010-02-10
- Volume
- 4
- Issue
- 3
- Pages
- 1425-1432
- ISSN
- 1936-0851 (ISSN-L)
- 1936-086X
- OpenAlex
- W2012186966
- Cited by
- 276
- References
- 27
- FWCI
- 24.42
- Type
- journal article
- Language
- en
- Open access
- closed
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