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Intramolecular Alkyne Hydroalkoxylation and Hydroamination Catalyzed by Iridium Hydrides
Abstract
[reaction: see text] Iridium(III) hydrides prove to be air-stable active catalysts for intramolecular hydroalkoxylation and hydroamination of internal alkynes with proximate nucleophiles. The cyclization follows highly selective 6-endo-dig regiochemistry when regioselectivity is an issue.
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Citations
Cited by
Hydroamination: Direct Addition of Amines to Alkenes and Alkynes
Müller, T. E., Hultzsch, K. C., Yus, M., Foubelo, F., & Tada, M. (2008) · Chemical Reviews · doi:10.1021/cr0306788 · Cited by 2,090
Palladium-catalyzed hydroacyloxylation of ynamides
Smith, D. L., Goundry, W. R. F., & Lam, H. W. (2012) · Chem. Commun. · doi:10.1039/c1cc13595c · Cited by 95
Metadata
- Authors
- Li, X., Chianese, A. R., Vogel, T., & Crabtree, R. H.
- Venue
- Organic Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2005-10-27
- Volume
- 7
- Issue
- 24
- Pages
- 5437-5440
- ISSN
- 1523-7052 (ISSN-L)
- 1523-7060
- OpenAlex
- W2011508390
- Cited by
- 238
- References
- 0
- FWCI
- 7.54
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Intramolecular Alkyne Hydroalkoxylation and Hydroamination Catalyzed by Iridium Hydrides. https://app.cochat.ai/papers/10.1021/ol052186i
- The paper
- Li, X., Chianese, A. R., Vogel, T., & Crabtree, R. H. (2005). Intramolecular Alkyne Hydroalkoxylation and Hydroamination Catalyzed by Iridium Hydrides. Organic Letters. https://doi.org/10.1021/ol052186i
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
