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Eosin Y Catalyzed Visible Light Oxidative C–C and C–P bond Formation
Abstract
Eosin Y catalyzes efficiently the visible light mediated coupling of sp(3) C-H bonds adjacent to the nitrogen atom in tetrahydroisoquinoline derivatives in the absence of an external oxidant. Nitroalkanes, dialkyl malonates, malononitrile, and dialkyl phophonates were used as pronucleophiles in this metal-free, visible light oxidative coupling reaction.
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Citations
Cited by
Prier, C. K., Rankic, D. A., & MacMillan, D. W. C. (2013) · Chemical Reviews · doi:10.1021/cr300503r · Cited by 9,590
Visible‐Light Photoredox Catalysis
Xuan, J., & Xiao, W. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201200223 · Cited by 2,262
The Cross‐Dehydrogenative Coupling of CH Bonds: A Versatile Strategy for CC Bond Formations
Girard, S. A., Knauber, T., & Li, C. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201304268 · Cited by 1,861
Metal-Free, Visible-Light-Mediated Direct C–H Arylation of Heteroarenes with Aryl Diazonium Salts
Hari, D. P., Schroll, P., & König, B. (2012) · Journal of the American Chemical Society · doi:10.1021/ja212099r · Cited by 798
Self-citationOrganocatalysis in Inert C–H Bond Functionalization
Qin, Y., Zhu, L., & Luo, S. (2017) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00657 · Cited by 785
Metadata
- Authors
- Hari, D. P., & König, B.
- Venue
- Organic Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2011-07-11
- Volume
- 13
- Issue
- 15
- Pages
- 3852-3855
- ISSN
- 1523-7052 (ISSN-L)
- 1523-7060
- OpenAlex
- W2040168806
- Cited by
- 601
- References
- 0
- FWCI
- 30.08
- Type
- journal article
- Language
- en
- Open access
- closed
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- Hari, D. P., & König, B. (2011). Eosin Y Catalyzed Visible Light Oxidative C–C and C–P bond Formation. Organic Letters. https://doi.org/10.1021/ol201376v
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