The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Photocatalytic Decarboxylative Reduction of Carboxylic Acids and Its Application in Asymmetric Synthesis
Abstract
The decarboxylative reduction of naturally abundant carboxylic acids such as α-amino acids and α-hydroxy acids has been achieved via visible-light photoredox catalysis. By using an organocatalytic photoredox system, this method offers a mild and rapid entry to a variety of high-value compounds including medicinally relevant scaffolds. Regioselective decarboxylation is achieved when differently substituted dicarboxylic acids are employed. The application of this method to the synthesis of enantioenriched 1-aryl-2,2,2-trifluoroethyl chiral amines starting from natural α-amino acids further testifies to the utility of the developed photocatalytic decarboxylative reduction protocol.
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Cites
Prier, C. K., Rankic, D. A., & MacMillan, D. W. C. (2013) · Chemical Reviews · doi:10.1021/cr300503r · Cited by 9,590
Natural products as sources of new drugs over the 30 years from 1981 to 2010
Newman, D. J., & Cragg, G. M. (2012) · Journal of Natural Products · doi:10.1021/np200906s · Cited by 4,687
Cited by
Photoredox Catalysis in Organic Chemistry
Shaw, M. H., Twilton, J., & MacMillan, D. W. C. (2016) · The Journal of Organic Chemistry · doi:10.1021/acs.joc.6b01449 · Cited by 3,186
Dual Catalysis Strategies in Photochemical Synthesis
Skubi, K. L., Blum, T. R., & Yoon, T. P. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00018 · Cited by 2,686
Zhou, Q., Guo, W., Ding, W., Wu, X., Chen, X., Lu, L., & Xiao, W. (2015) · Angewandte Chemie International Edition · doi:10.1002/anie.201504559 · Cited by 326
Visible Light-Mediated Direct Decarboxylative C–H Functionalization of Heteroarenes
Garza-Sanchez, R. A., Tlahuext-Aca, A., Tavakoli, G., & Glorius, F. (2017) · ACS Catalysis · doi:10.1021/acscatal.7b01133 · Cited by 285
Metadata
- Authors
- Cassani, C., Bergonzini, G., & Wallentin, C.-J.
- Venue
- Organic Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-07-28
- Volume
- 16
- Issue
- 16
- Pages
- 4228-4231
- ISSN
- 1523-7052 (ISSN-L)
- 1523-7060
- OpenAlex
- W1977017618
- Cited by
- 176
- References
- 2
- FWCI
- 9.97
- Type
- journal article
- Language
- en
- Open access
- closed
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- Cassani, C., Bergonzini, G., & Wallentin, C.-J. (2014). Photocatalytic Decarboxylative Reduction of Carboxylic Acids and Its Application in Asymmetric Synthesis. Organic Letters. https://doi.org/10.1021/ol5019294
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
