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Two Novel Carbazole Dyes for Dye-Sensitized Solar Cells with Open-Circuit Voltages up to 1 V Based on Br−/Br3− Electrolytes
Open accessAbstract
Dye-sensitized solar cells (DSCs) based on two novel carbazole dyes (TC301 and TC306) and a Br(-)/Br(3)(-) redox mediator in dried CH(3)CN solutions as electrolytes yielded a V(oc) of 1.156 V and a eta value of 3.68% and a V(oc) of 0.939 V and a eta value of 5.22% under simulated AM 1.5, respectively. The dyes TC301 and TC306 have more positive HOMO levels (1.59 and 1.38 V vs NHE) than the redox potential of Br(-)/Br(3)(-)-based electrolytes, which have sufficient driving force to regenerate dyes. Under similar conditions with an I(-)/I(3)(-) instead of a Br(-)/Br(3)(-) redox mediator, DSCs sensitized by the dyes TC301 and TC306 produced a V(oc) of 0.696 V and a eta value of 2.36% and a V(oc) of 0.621 V and a eta value of 4.10%, respectively.
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Cited by
Zhao, Y., Ding, Y., Li, Y., Peng, L., Byon, H. R., Goodenough, J. B., & Yu, G. (2015) · Chemical Society Reviews · doi:10.1039/c5cs00289c · Cited by 458
Tsao, H. N., Yi, C., Moehl, T., Yum, J., Zakeeruddin, S. M., Nazeeruddin, M. K., & Grätzel, M. (2011) · ChemSusChem · doi:10.1002/cssc.201100120 · Cited by 339
Cheng, M., Yang, X., Chen, C., Zhao, J., Zhang, F., & Sun, L. (2013) · Physical Chemistry Chemical Physics · doi:10.1039/c3cp51980e · Cited by 22
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Metadata
- Authors
- Teng, C., Yang, X., Yuan, C., Li, C., Chen, R., Tian, H., Li, S., Hagfeldt, A., & Sun, L.
- Venue
- Organic Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2009-11-09
- Volume
- 11
- Issue
- 23
- Pages
- 5542-5545
- ISSN
- 1523-7052 (ISSN-L)
- 1523-7060
- OpenAlex
- W2026748391
- Cited by
- 171
- References
- 0
- FWCI
- 8.73
- Type
- journal article
- Language
- en
- Open access
- green
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- Teng, C., Yang, X., Yuan, C., Li, C., Chen, R., Tian, H., Li, S., Hagfeldt, A., & Sun, L. (2009). Two Novel Carbazole Dyes for Dye-Sensitized Solar Cells with Open-Circuit Voltages up to 1 V Based on Br−/Br3− Electrolytes. Organic Letters. https://doi.org/10.1021/ol9022936
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