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Two Novel Carbazole Dyes for Dye-Sensitized Solar Cells with Open-Circuit Voltages up to 1 V Based on Br−/Br3− Electrolytes

Open access
Teng, Chao, Yang, Xichuan, Yuan, Chunze, Li, Chaoyan, Chen, Ruikui, Tian, Haining, Li, Shifeng, Hagfeldt, Anders, Sun, Licheng·2009·Organic Letters

Abstract

Dye-sensitized solar cells (DSCs) based on two novel carbazole dyes (TC301 and TC306) and a Br(-)/Br(3)(-) redox mediator in dried CH(3)CN solutions as electrolytes yielded a V(oc) of 1.156 V and a eta value of 3.68% and a V(oc) of 0.939 V and a eta value of 5.22% under simulated AM 1.5, respectively. The dyes TC301 and TC306 have more positive HOMO levels (1.59 and 1.38 V vs NHE) than the redox potential of Br(-)/Br(3)(-)-based electrolytes, which have sufficient driving force to regenerate dyes. Under similar conditions with an I(-)/I(3)(-) instead of a Br(-)/Br(3)(-) redox mediator, DSCs sensitized by the dyes TC301 and TC306 produced a V(oc) of 0.696 V and a eta value of 2.36% and a V(oc) of 0.621 V and a eta value of 4.10%, respectively.

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Metadata

Authors
Teng, C., Yang, X., Yuan, C., Li, C., Chen, R., Tian, H., Li, S., Hagfeldt, A., & Sun, L.
Venue
Organic Letters
Published
2009-11-09
Volume
11
Issue
23
Pages
5542-5545
ISSN
  • 1523-7052 (ISSN-L)
  • 1523-7060
OpenAlex
W2026748391
Cited by
171
References
0
FWCI
8.73
Type
journal article
Language
en
Open access
green

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CoChat. (2026). Citation check: Two Novel Carbazole Dyes for Dye-Sensitized Solar Cells with Open-Circuit Voltages up to 1 V Based on Br−/Br3− Electrolytes. https://app.cochat.ai/papers/10.1021/ol9022936
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Teng, C., Yang, X., Yuan, C., Li, C., Chen, R., Tian, H., Li, S., Hagfeldt, A., & Sun, L. (2009). Two Novel Carbazole Dyes for Dye-Sensitized Solar Cells with Open-Circuit Voltages up to 1 V Based on Br−/Br3− Electrolytes. Organic Letters. https://doi.org/10.1021/ol9022936

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