The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Rhodium and Iridium Complexes of N-Heterocyclic Carbenes via Transmetalation: Structure and Dynamics
Abstract
Rhodium and iridium complexes of N-heterocyclic carbenes ( 3a − c and 4a − c) were obtained by transmetalation from the corresponding Ag(I) complexes. The structure of 3b was verified by X-ray diffraction. The compounds display restricted rotation about the metal−carbene bond, the rate of which can be controlled by altering the steric bulk of the auxiliary ligands. Infrared spectroscopy provides an estimate of the electron-donor power of the carbene ligands from ν(CO) of the carbonyl derivatives.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Steric effects of phosphorus ligands in organometallic chemistry and homogeneous catalysis
Tolman, C. A. (1977) · Chemical Reviews · doi:10.1021/cr60307a002 · Cited by 4,824
Cited by
Díez-González, S., & Nolan, S. P. (2007) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2006.10.004 · Cited by 939
Chianese, A. R., Kovacevic, A., Zeglis, B. M., Faller, J. W., & Crabtree, R. H. (2004) · Organometallics · doi:10.1021/om049903h · Cited by 329
Self-citation
Metadata
- Authors
- Chianese, A. R., Li, X., Janzen, M. C., Faller, J. W., & Crabtree, R. H.
- Venue
- Organometallics
- Publisher
- American Chemical Society (ACS)
- Published
- 2003-03-13
- Volume
- 22
- Issue
- 8
- Pages
- 1663-1667
- ISSN
- 0276-7333 (ISSN-L)
- 1520-6041
- OpenAlex
- W2069989703
- Cited by
- 516
- References
- 1
- FWCI
- 21.37
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Rhodium and Iridium Complexes of N-Heterocyclic Carbenes via Transmetalation: Structure and Dynamics. https://app.cochat.ai/papers/10.1021/om021029+
- The paper
- Chianese, A. R., Li, X., Janzen, M. C., Faller, J. W., & Crabtree, R. H. (2003). Rhodium and Iridium Complexes of N-Heterocyclic Carbenes via Transmetalation: Structure and Dynamics. Organometallics. https://doi.org/10.1021/om021029%2B
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
