Steric effects of phosphorus ligands in organometallic chemistry and homogeneous catalysis
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ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSteric effects of phosphorus ligands in organometallic chemistry and homogeneous catalysisChadwick A. TolmanCite this: Chem. Rev. 1977, 77, 3, 313–348Publication Date (Print):June 1, 1977Publication History Published online1 May 2002Published inissue 1 June 1977https://pubs.acs.org/doi/10.1021/cr60307a002https://doi.org/10.1021/cr60307a002research-articleACS PublicationsRequest reuse permissionsArticle Views37168Altmetric-Citations4177LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-Alertsclose Get e-Alerts
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These include relationships between catalysis or ligand binding and the steric bulk of a ligand.
“These include relationships between catalysis or ligand binding and the steric bulk [e.g., Tolman cone angle (77,78) or buried volume (79)] of a ligand.”
From Machine Learning for the Discovery, Design, and Engineering of Materials. (2022) · cites this paper as [78]
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- Authors
- Tolman, C. A.
- Corresponding author
- Tolman, Chadwick A.
- Venue
- Chemical Reviews
- Publisher
- American Chemical Society (ACS)
- Published
- 1977-06-01
- Volume
- 77
- Issue
- 3
- Pages
- 313-348
- ISSN
- 0009-2665 (ISSN-L)
- 1520-6890
- OpenAlex
- W2091702998
- Cited by
- 4,824
- References
- 9
- Citations by year
- 2026: 92 · 2025: 107 · 2024: 143 · 2023: 144 · 2022: 129 · 2021: 134 · 2020: 168 · 2019: 147 · 2018: 153 · 2017: 178 · 2016: 144 · 2015: 153 · 2014: 120 · 2013: 147 · 2012: 156
- FWCI
- 69.96
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Chemical Reviews (publishedVersion)
- Topics
- Physical Sciences › Chemistry › Organic Chemistry › Organometallic Complex Synthesis and Catalysis
- Physical Sciences › Chemistry › Organic Chemistry › Inorganic and Organometallic Chemistry
- Physical Sciences › Chemistry › Inorganic Chemistry › Synthesis and characterization of novel inorganic/organometallic compounds
- Keywords
- steric effects, phosphine ligands, organophosphorus ligands, organometallic chemistry, homogeneous catalysis, metal-ligand interactions
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