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A Brief Review on Industrial Alternatives for the Manufacturing of Glycerol Carbonate, a Green Chemical
Abstract
Glycerol carbonate is one the glycerol derivatives which attracts attention for industrial applications. This review compares strategies for its synthesis, and their analyses lead to the conclusion that (indirect) procedures starting from glycerol- and/or CO 2 -derivatives are the most attractive. These are described and compared, taking criteria of industrial feasibility into account. As a result, the transesterification of dimethyl carbonate or ethylene carbonate with glycerol using uncalcined CaO as catalyst appears to be currently the most suitable industrial process. Finally, potential applications of glycerol carbonate as a multifunctional compound are exemplified.
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Cites
Reactive Applications of Cyclic Alkylene Carbonates
Clements, J. H. (2003) · Industrial & Engineering Chemistry Research · doi:10.1021/ie020678i · Cited by 784
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Maisonneuve, L., Lamarzelle, O., Rix, E., Grau, E., & Cramail, H. (2015) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00355 · Cited by 731
A perspective approach to sustainable routes for non-isocyanate polyurethanes
Cornille, A., Auvergne, R., Figovsky, O., Boutevin, B., & Caillol, S. (2017) · European Polymer Journal · doi:10.1016/j.eurpolymj.2016.11.027 · Cited by 531
Continuous Flow Upgrading of Selected C2–C6Platform Chemicals Derived from Biomass
Gérardy, R., Debecker, D. P., Estager, J., Luis, P., & Monbaliu, J.-C. M. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00846 · Cited by 398
From Petrochemical Polyurethanes to Biobased Polyhydroxyurethanes
Nohra, B., Candy, L., Blanco, J.-F., Guerin, C., Raoul, Y., & Mouloungui, Z. (2013) · Macromolecules · doi:10.1021/ma400197c · Cited by 395
Metadata
- Authors
- Ochoa-Gómez, J. R., Gómez-Jiménez-Aberasturi, O., Ramírez-López, C., & Belsué, M.
- Venue
- Organic Process Research & Development
- Publisher
- American Chemical Society (ACS)
- Published
- 2012-02-13
- Volume
- 16
- Issue
- 3
- Pages
- 389-399
- ISSN
- 1083-6160 (ISSN-L)
- 1520-586X
- OpenAlex
- W2329640882
- Cited by
- 245
- References
- 1
- FWCI
- 6.41
- Type
- journal article
- Language
- en
- Open access
- closed
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- Ochoa-Gómez, J. R., Gómez-Jiménez-Aberasturi, O., Ramírez-López, C., & Belsué, M. (2012). A Brief Review on Industrial Alternatives for the Manufacturing of Glycerol Carbonate, a Green Chemical. Organic Process Research & Development. https://doi.org/10.1021/op200369v
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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