Structure, absolute configuration and conformation of the antimalarial compound, artemisinin
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The unusual endoperoxide group in artemisinin has been confirmed by a variety of means, and the absolute stereochemistry of artemisinin has been established by X-ray crystallography.
“The unusual endoperoxide group in artemisinin has been confirmed by a variety of means [219,220,221,222,223,224,225,226] and the absolute stereochemistry of artemisinin has been established by X-ray crystallography [227].”
From The Biosynthesis of Artemisinin (Qinghaosu) and the Phytochemistry of Artemisia annua L. (Qinghao) (2010) · cites this paper as [227]
Cites
On enantiomorph-polarity estimation
Flack, H. D. (1983) · Acta Crystallographica Section A Foundations of Crystallography · doi:10.1107/s0108767383001762 · Cited by 10,396 · see citing works
Allen, F. H., Kennard, O., Watson, D. G., Brammer, L., Orpen, A. G., & Taylor, R. (1987) · Journal of the Chemical Society Perkin Transactions 2 · doi:10.1039/p298700000s1 · Cited by 8,029 · see citing works
Iron-dependent free radical generation from the antimalarial agent artemisinin (qinghaosu)
Meshnick, S. R., Yang, Y. Z., Lima, V, Kuypers, F., Kamchonwongpaisan, S., & Yuthavong, Y. (1993) · Antimicrobial Agents and Chemotherapy · doi:10.1128/aac.37.5.1108 · Cited by 327 · see citing works
Luo, X., & Shen, C. (1987) · Medicinal Research Reviews · doi:10.1002/med.2610070103 · Cited by 320 · see citing works
Hemin-catalyzed decomposition of artemisinin (qinghaosu)
Zhang, F., Gosser, D. K., & Meshnick, S. (1992) · Biochemical Pharmacology · doi:10.1016/0006-2952(92)90713-s · Cited by 148 · see citing works
Handbook of Drugs for Tropical Parasitic Infections
Hellgren, U., Ericsson, Ö., Ericsson, Ö., & Gustafsson, L. L. (2003) · CRC Press eBooks · doi:10.1201/9781482272536 · Cited by 81 · see citing works
Luo, X., Yeh, H. J. C., Brossi, A. R., et al. (1984) · Helvetica Chimica Acta · doi:10.1002/hlca.19840670615 · Cited by 77 · see citing works
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The Biosynthesis of Artemisinin (Qinghaosu) and the Phytochemistry of Artemisia annua L. (Qinghao)
Brown, G. D. (2010) · Molecules · doi:10.3390/molecules15117603 · Cited by 363 · see citing works
- Authors
- Lisgarten, J. N., Potter, B. S., Bantuzeko, C., & Palmer, R. A.
- Affiliations
- University of London (GB)
- Vrije Universiteit Brussel (BE)
- Venue
- Journal of Chemical Crystallography
- Published
- 1998-07
- Volume
- 28
- Issue
- 7
- Pages
- 539-543
- ISSN
- 1074-1542 (ISSN-L)
- 1572-8854
- OpenAlex
- W165124769
- Cited by
- 60
- References
- 7
- Citations by year
- 2025: 4 · 2024: 2 · 2023: 3 · 2022: 3 · 2021: 1 · 2020: 4 · 2019: 1 · 2018: 1 · 2017: 1 · 2016: 2 · 2015: 2 · 2014: 2 · 2013: 5 · 2012: 2
- FWCI
- 0.29
- Type
- journal article
- Language
- en
- Open access
- closed
- Licence
- Locations
- Journal of Chemical Crystallography (publishedVersion)
- Topics
- Physical Sciences › Chemistry › Inorganic Chemistry › Crystal structures of chemical compounds
- Physical Sciences › Chemistry › Spectroscopy › Molecular spectroscopy and chirality
- Life Sciences › Biochemistry, Genetics and Molecular Biology › Cancer Research › Sesquiterpenes and Asteraceae Studies
- Keywords
- artemisinin, crystal structure, absolute configuration, molecular conformation, fused ring systems, chair conformation, antimalarial compounds, Flack parameter
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
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