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Abundance of zinc isotopes as a marine biogeochemical tracer

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Maréchal, Chloé N., Nicolas, Emmanuel, Douchet, Chantal, Albarède, Francis·2000·Geochemistry, Geophysics, Geosystems

Abstract

The Zn isotopic compositions of ferromanganese nodules, sediment trap samples, sediments, and organic reference samples have been analyzed by multiple collector inductively coupled plasma–mass spectrometry (ICP‐MS). The range of isotopic variations (1‰ for 66 Zn/64 Zn) is significant with respect to the analytical precision (0.04‰ at the 95% confidence level). Marine argillaceous sediments show rather constant values consistent with those of continental shales and loess and with the value of a basalt from Réunion Island. We infer that the depletion of the light Zn isotopes in marine particles and in ferromanganese nodules (presumably equilibrated with seawater) results from biological activity in the upper water column. The δ 66 Zn values of sediment trap samples collected near the upwelling off the coast of Mauritania (central Atlantic) show a seasonal isotopic fluctuation consistent with biological pumping during the high‐productivity period. Higher values of δ 66 Zn in nodules appear to be associated with the amplitude of seasonal variations rather than with the mean values of the biological productivity.

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Crossref · 10.1029/1999gc000029

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Metadata

Authors
Maréchal, C. N., Nicolas, E., Douchet, C., & Albarède, F.
Venue
Geochemistry, Geophysics, Geosystems
Published
2000-05
Volume
1
Issue
5
ISSN
1525-2027 (ISSN-L)
OpenAlex
W1649947189
Cited by
234
References
1
FWCI
5.58
Type
journal article
Language
en
Open access
green

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CoChat. (2026). Citation check: Abundance of zinc isotopes as a marine biogeochemical tracer. https://app.cochat.ai/papers/10.1029/1999gc000029
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Maréchal, C. N., Nicolas, E., Douchet, C., & Albarède, F. (2000). Abundance of zinc isotopes as a marine biogeochemical tracer. Geochemistry, Geophysics, Geosystems. https://doi.org/10.1029/1999gc000029

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