The DOI matches its Crossref record; 34 of the 34 references it cites were found in a registry or an index.
Dependence of nucleation rates on sulfuric acid vapor concentration in diverse atmospheric locations
Abstract
Correlations between concentrations of newly formed particles and sulfuric acid vapor were analyzed for twenty one nucleation events measured in diverse continental and marine atmospheric environments. A simple power law model for formation rates of 1 nm particles, J1 = K · [H2SO4]P, where P and K are least squares parameters, was tested for each environment. We found that, to within experimental uncertainty, P = 2. Constraining P to 2, the prefactor Kkinetic ranges from 10−14 to 10−11 cm 3 s−1. According to the nucleation theorem, an exponent value of 2 indicates that the critical cluster contains two sulfuric acid molecules. Existing nucleation rate expressions based on classical nucleation theory predict significantly larger values of P. The prefactor values vary with environment and are 1 to 4 orders of magnitude below the hard‐sphere collision limit. These results provide a simple parameterization for atmospheric new particle formation that could be used in global climate models.
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Impact of nucleation on global CCN
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Atmospheric new particle formation and growth: review of field observations
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Oxidation products of biogenic emissions contribute to nucleation of atmospheric particles
Riccobono, F., Schobesberger, S., Scott, C. E., Dommen, J., Ortega, I. K., Rondo, L., Almeida, J., Amorim, A., Bianchi, F., Breitenlechner, M., et al. (2014) · Science · doi:10.1126/science.1243527 · Cited by 642
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Metadata
- Authors
- Kuang, C., McMurry, P. H., McCormick, A. V., & Eisele, F. L.
- Venue
- Journal of Geophysical Research: Atmospheres
- Publisher
- American Geophysical Union (AGU)
- Published
- 2008-05-27
- Volume
- 113
- Issue
- D10
- ISSN
- 0148-0227 (ISSN-L)
- OpenAlex
- W2136884131
- Cited by
- 422
- References
- 34
- FWCI
- 21.98
- Type
- journal article
- Language
- en
- Open access
- closed
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