Influence of climate change and uplift on Colorado Plateau paleotemperatures from carbonate clumped isotope thermometry
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The elevation history of Earth's surface is key to understanding the geodynamic processes responsible for the rise of plateaus. We investigate the timing of Colorado Plateau uplift by estimating depositional temperatures of Tertiary lake sediments that blanket the plateau interior and adjacent lowlands using carbonate clumped isotope paleothermometry (a measure of the temperature‐dependent enrichment of 13 C‐18 O bonds in carbonates). Comparison of modern and ancient samples deposited near sea level provides an opportunity to quantify the influence of climate and therefore assess the contribution of changes in elevation to the variations of surface temperature on the plateau. Analysis of modern lake calcite from 350 to 3300 m elevation in the southwestern United States reveals a lake water carbonate temperature (LCT) lapse rate of 4.2 ± 0.6°C/km. Analysis of Miocene deposits from 88 to 1900 m elevation in the Colorado River drainage suggests that the ancient LCT lapse rate was 4.1 ± 0.7°C/km, and temperatures were 7.7 ± 2.0°C warmer at any one elevation than predicted by the modern trend. The inferred cooling is plausible in light of Pliocene temperature estimates off the coast of California, and the consistency of lapse rates through time supports the interpretation that there has been little or no elevation change for any of the samples since 6 Ma. Together with previous paleorelief estimates from apatite (U‐Th)/He data from the Grand Canyon, our results suggest most or all of the plateau's lithospheric buoyancy was acquired ∼80–60 Ma and do not support explanations that ascribe most plateau uplift to Oligocene or younger disposal of either the Farallon or North American mantle lithosphere.
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Early workers showed the power of clumped isotope data to develop previously impossible environmental temperature and δ18Ow reconstructions from terrestrial carbonates including pedogenic carbonates, lake sediments and freshwater mollusks, land snails, and spring and cave deposits.
“Early workers showed the power of clumped isotope data to get around this problem, developing previously impossible environmental temperature and δ 18 O w reconstructions from terrestrial carbonates including ancient pedogenic (soil) carbonates (e.g., Ghosh et al. 2006b, Passey et al. 2010), lake sediments and freshwater mollusks (e.g., Huntington et al. 2010, Dennis et al. 2013, Hren et al. 2013,”
From Frontiers of Carbonate Clumped Isotope Thermometry (2023) · cites this paper as Huntington et al. 2010
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Experimental — accuracy not yet measuredClumped isotope datasets can constrain paleotopography and tectonics.
“Such datasets can also constrain paleotopography and tectonics (e.g., Ghosh et al. 2006b, Huntington et al. 2010, Garzione et al. 2014, Li et al. 2019, Rugenstein et al. 2022).”
From Frontiers of Carbonate Clumped Isotope Thermometry (2023) · cites this paper as Huntington et al. 2010
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On the Isotopic Chemistry of Carbonates and a Paleotemperature Scale
McCrea, J. M. (1950) · The Journal of Chemical Physics · doi:10.1063/1.1747785 · Cited by 3,742 · see citing works
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13C–18O bonds in carbonate minerals: a new kind of paleothermometer
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Self-citation“Clumped-isotope” geochemistry—The study of naturally-occurring, multiply-substituted isotopologues
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Self-citationHuntington, K. W., Eiler, J. M., Affek, H. P., Guo, W., Bonifacie, M., Yeung, L. Y., Thiagarajan, N., Passey, B., Tripati, A., Daëron, M., et al. (2009) · Journal of Mass Spectrometry · doi:10.1002/jms.1614 · Cited by 436 · see citing works
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“CO2 was produced by anhydrous phosphoric acid digestion of ∼8 mg of carbonate powder from each sample at 25°C for 12–24 h using a McCrea‐type reaction vessel [McCrea, 1950; Swart et al., 1991].”
Method18O13C16O in Earth’s atmosphere
Eiler, J. M., & Schauble, E. (2004) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2004.05.035 · Cited by 362 · cited 1× · see citing works
“Measurements of D48 for the samples were used to screen for contaminants such as sulfur, hydrocarbons, and organics, through comparison of D48 for clean heated CO2 [Eiler and Schauble, 2004; Guo and Eiler, 2007; Huntington et al., 2009].”
MethodSelf-citationEquilibrium thermodynamics of multiply substituted isotopologues of molecular gases
Wang, Z., Schauble, E. A., & Eiler, J. M. (2004) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2004.05.039 · Cited by 338 · see citing works
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- Authors
- Huntington, K. W., Wernicke, B. P., & Eiler, J. M.
- Affiliations
- University of Washington (US)
- California Institute of Technology (US)
- Venue
- Tectonics
- Publisher
- American Geophysical Union (AGU)
- Published
- 2010-05-25
- Volume
- 29
- Issue
- 3
- ISSN
- 0278-7407 (ISSN-L)
- 1944-9194
- OpenAlex
- W1751304872
- Cited by
- 154
- References
- 9
- Citations by year
- 2026: 4 · 2025: 3 · 2024: 11 · 2023: 7 · 2022: 14 · 2021: 13 · 2020: 7 · 2019: 8 · 2018: 12 · 2017: 8 · 2016: 8 · 2015: 13 · 2014: 15 · 2013: 8 · 2012: 9
- FWCI
- 5.94
- Type
- journal article
- Language
- en
- Open access
- bronze
- doi.org
- Locations
- Tectonics (publishedVersion)
- CaltechAUTHORS (California Institute of Technology) (submittedVersion)
- Topics
- Physical Sciences › Earth and Planetary Sciences › Atmospheric Science › Geology and Paleoclimatology Research
- Physical Sciences › Earth and Planetary Sciences › Geophysics › Geological and Geochemical Analysis
- Physical Sciences › Earth and Planetary Sciences › Paleontology › Paleontology and Stratigraphy of Fossils
- Keywords
- Colorado Plateau, plateau uplift, paleotemperature, carbonate clumped isotopes, lapse rate, Miocene climate, lithospheric buoyancy, Grand Canyon
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