Evolution of Neoproterozoic Wonoka–Shuram Anomaly-aged carbonates: Evidence from clumped isotope paleothermometry
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The high temperatures in earlier Doushantuo studies are inferred to reflect postdepositional hydrothermal alteration of host rocks and loss of original Δ47 signals.
“These high temperatures are inferred to reflect postdepositional hydrothermal alteration of the host rocks and loss of original Δ 47 signals (23,24)”
From Massive formation of early diagenetic dolomite in the Ediacaran ocean: Constraints on the "dolomite problem" (2020) · cites this paper as [24]
Section 5.1 (page unavailable) says the South China carbonate temperatures are consistent with burial heating and interprets the rocks as recrystallized and reequilibrated; §5.4.2 links high clumped-isotope temperatures to burial recrystallization. The paper does not identify hydrothermal alteration as the cause of those temperatures or specifically establish loss of the original Δ47 signals in earlier Doushantuo studies. (LLM, conf=0.86)
Experimental — accuracy not yet measuredThe TΔ47 records from the Zhangcunping drillcores differ from earlier Doushantuo dolostone studies at Huajipo and Jiulongwan, which yielded generally low Δ47 values corresponding to significantly higher temperatures up to 224 °C.
“We note that the T Δ47 records from the Zhangcunping drillcores differ from results for Doushantuo dolostones in earlier studies of the Huajipo (23) and Jiulongwan (23,24) shelf sections in the Yangtze Gorges area”
From Massive formation of early diagenetic dolomite in the Ediacaran ocean: Constraints on the "dolomite problem" (2020) · cites this paper as [24]
The Results (section 4) report clumped-isotope temperatures for South China carbonates, and Table 1 lists Doushantuo dolomite samples. But our copy does not identify Huajipo or report a temperature of 224 °C for those samples; it gives a South China range of 38–164 °C. It also does not compare either named shelf section with Zhangcunping drillcores. (LLM, conf=0.83)
Experimental — accuracy not yet measuredOriginal TΔ47 signatures are subject to secondary alteration via meteoric diagenesis, recrystallization, and solid-state reordering during geological burial, all of which shift values to higher-than-original TΔ47 values.
“Original T Δ47 signatures are subject to secondary alteration via meteoric diagenesis, recrystallization, and solid-state reordering during geological burial, all of which result in shifts to higher-than-original T Δ47 values (7,(23)(24)(25).”
From Massive formation of early diagenetic dolomite in the Ediacaran ocean: Constraints on the "dolomite problem" (2020) · cites this paper as [24]
Section 5.2 says solid-state reordering can produce higher clumped-isotope temperatures, and §5.4.2 links high temperatures to burial recrystallization. But §5.4.1 treats meteoric diagenesis as a possible earlier signal, not as a process that necessarily raises TΔ47; §5.3 also finds evidence against pervasive reordering in the studied carbonates. The claim overstates the paper by saying all three processes shift values higher than the original temperature. (LLM, conf=0.84)
Experimental — accuracy not yet measuredNo geological process is known to reduce TΔ47 values.
“Because no geological process is known to reduce T Δ47 values (7, 23-25)”
From Massive formation of early diagenetic dolomite in the Ediacaran ocean: Constraints on the "dolomite problem" (2020) · cites this paper as [24]
Section 5.3 discusses burial heating and solid-state reordering as processes that can alter Δ47 values, while section 5.1 describes a trend toward higher clumped-isotope temperatures during burial. Neither passage states that no geological process can reduce TΔ47 values. Searches for lower clumped-isotope temperatures and the claimed absence of such a process did not find that assertion in our copy. (LLM, conf=0.70)
Experimental — accuracy not yet measured
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Rare earth element geochemistry of carbonates as a proxy for deep-time environmental reconstruction
Zhao, Y., Wei, W., Li, S., Yang, T., Zhang, R., Somerville, I. D., Santosh, M., Wei, H., Wu, J., Yang, J. L., et al. (2021) · Palaeogeography Palaeoclimatology Palaeoecology · doi:10.1016/j.palaeo.2021.110443 · Cited by 90 · see citing works
Testing the preservation potential of early diagenetic dolomites as geochemical archives
Mueller, M., Igbokwe, O. A., Walter, B. F., Pederson, C., Riechelmann, S., Richter, D., Albert, R., Gerdes, A., Buhl, D., Neuser, R. D., et al. (2019) · Sedimentology · doi:10.1111/sed.12664 · Cited by 72 · see citing works
“…non-conventional proxies, such as boron isotopes and calcium isotopes (Kasemann et al., 2005), magnesium isotopes (Kasemann et al., 2014), clumped isotope palaeothermometry (Loyd et al., 2015) and cadmium isotopes (Hohl et al., 2017), may offer a new perspective of the Neoproterozoic world.”
BackgroundMangenot, X., Gasparrini, M., Rouchon, V., & Bonifacie, M. (2017) · Sedimentology · doi:10.1111/sed.12427 · Cited by 70 · see citing works
“…to subsurface problems, such as burial and structural diagenesis, water and hydrocarbon fluid flows, and basin thermal evolution (Bristow et al., 2011; Huntington et al., 2011; Loyd et al., 2012, 2015; Budd et al., 2013; Dale et al., 2014; Huntington & Lechler, 2015; Swart et al., 2016).”
BackgroundSelf-citationMangenot, X., Bonifacie, M., Gasparrini, M., Götz, A., Chaduteau, C., Ader, M., & Rouchon, V. (2017) · Chemical Geology · doi:10.1016/j.chemgeo.2017.10.011 · Cited by 51 · see citing works
“Yet, the number of studies focusing on hightemperature settings remained limited (e.g, Bristow et al., 2011; Ferry et al., 2011; Loyd et al., 2012; Loyd et al. 2015; Dale et al., 2014; Henkes et al., 2014; Huntington and Lechler, 2015 ; Millan et al. 2016), likely resulting from the only recent…”
Self-citationZhou, C., Guan, C., Cui, H., Ouyang, Q., & Wang, W. (2016) · Palaeogeography Palaeoclimatology Palaeoecology · doi:10.1016/j.palaeo.2016.08.017 · Cited by 49 · see citing works
“…low δ18O values may indicate a diagenetic overprint to the original oxygen isotopic composition due to its higher sensitivity to diagenetic alteration than carbon isotopic composition (cf. Lohmann, 1988; Banner and Hanson, 1990; Jacobsen and Kaufman, 1999; Bishop et al., 2014; Loyd et al., 2015).”
BackgroundAnsari, A. H., Pandey, S. K., Шарма, М., Agrawal, S., & Kumar, Y. (2018) · Precambrian Research · doi:10.1016/j.precamres.2018.02.002 · Cited by 42 · see citing works
Lukoczki, G., Haas, J., Gregg, J. M., Machel, H. G., Kele, S., & John, C. M. (2018) · Marine and Petroleum Geology · doi:10.1016/j.marpetgeo.2018.12.004 · Cited by 38 · see citing works
Frederiksen, J. A., Wei, W., Rugen, E. J., Ling, H., & Frei, R. (2022) · Palaeogeography Palaeoclimatology Palaeoecology · doi:10.1016/j.palaeo.2022.111096 · Cited by 31 · see citing works
Gómez-Peral, L. E., Kaufman, A. J., Arrouy, M. J., Richiano, S., Sial, A. N., Poiré, D. G., & Ferreira, V. P. (2018) · Precambrian Research · doi:10.1016/j.precamres.2018.07.005 · Cited by 30 · see citing works
Came, R. E., Azmy, K., Tripati, A., & Olanipekun, B.-J. (2017) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2016.10.028 · Cited by 29 · see citing works
Self-citationAtapour, H., & Aftabi, A. (2017) · Ore Geology Reviews · doi:10.1016/j.oregeorev.2017.05.033 · Cited by 25 · see citing works
Palaeobiology of Indian Proterozoic and Early Cambrian Successions— Recent Developments
Шарма, М., Tiwari, M., Ahmad, S., Shukla, R., Shukla, B., Singh, V. K., Pandey, S. K., Ansari, A. H., Shukla, Y., & Kumar, S. (2016) · Revista de Fomento Social · doi:10.16943/ptinsa/2016/48468 · Cited by 24 · see citing works
“The cause and coverage of Shuram excursion and its possible link with the radiation of metazoa is still under debate (Gamper t al., 2015; Loyd et al., 2015; Macdonald et al., 2013; Osburn et al., 2015; Schrag et al., 2013; Tahata et al., 2015).”
BackgroundWang, Z., Wang, J., Kouketsu, Y., Bodnar, R. J., Gill, B. C., & Xiao, S. (2017) · Precambrian Research · doi:10.1016/j.precamres.2017.06.013 · Cited by 24 · see citing works
Lukoczki, G., Haas, J., Gregg, J. M., Machel, H. G., Kele, S., & John, C. M. (2020) · International Journal of Earth Sciences · doi:10.1007/s00531-020-01851-7 · Cited by 23 · see citing works
Witkosky, R., & Wernicke, B. P. (2018) · Geosphere · doi:10.1130/ges01678.1 · Cited by 22 · see citing works
Barron, A. J., Paz-Moreno, F. A., & Hagadorn, J. W. (2018) · Journal of South American Earth Sciences · doi:10.1016/j.jsames.2018.11.003 · Cited by 19 · see citing works
Self-citationIdentification of multiple magnetizations of the Ediacaran strata in South China
Jing, X., Yang, Z., Tong, Y., Wang, H., & Xu, Y. (2017) · Geophysical Journal International · doi:10.1093/gji/ggx396 · Cited by 17 · see citing works
“This explanation is also supported by previous studies (Jackson et al. 1988; McCabe & Elmore 1989; Jackson 1990; Lu et al. 1990), which did not find thermoviscous magnetization characteristics in carbonate rocks that had undergone burial temperatures below 250 ◦C. Interestingly, from the carbonate…”
ResultChang, B., Defliese, W. F., Li, C., Huang, J., Tripati, A., & Algeo, T. J. (2019) · Rapid Communications in Mass Spectrometry · doi:10.1002/rcm.8678 · Cited by 17 · see citing works
Self-citationBojanowski, M. J., Marciniak‐Maliszewska, B., Środoń, J., & Liivamägi, S. (2021) · Precambrian Research · doi:10.1016/j.precamres.2021.106379 · Cited by 15 · see citing works
Yang, C., Li, M., Ni, Z., Wang, T., Qiu, N., Fang, R., & Wen, L. (2021) · Geoscience Frontiers · doi:10.1016/j.gsf.2021.101324 · Cited by 13 · see citing works
Bennett, C. E., Williams, M., Leng, M. J., Lee, M., Bonifacie, M., Calmels, D., Fortey, R. A., Laurie, J. R., Owen, A. W., Page, A. A., et al. (2018) · Gondwana Research · doi:10.1016/j.gr.2018.01.006 · Cited by 11 · see citing works
Self-citationAftabi, A., Atapour, H., & Mohseni, S. (2022) · Precambrian Research · doi:10.1016/j.precamres.2022.106740 · Cited by 11 · see citing works
Bouskri, I., Ilmen, S., Souhassou, M., Ikenne, M., Zoheir, B., Hajjar, Z., Maacha, L., Benzougagh, B., Kader, S., Jabbour, M., et al. (2025) · Ore Geology Reviews · doi:10.1016/j.oregeorev.2025.106533 · Cited by 10 · see citing works
Microbial Autotrophy Recorded by Carbonate Dual Clumped Isotope Disequilibrium
Ingalls, M., Leapaldt, H. C., & Lloyd, M. K. (2024) · Geochemistry Geophysics Geosystems · doi:10.1029/2024gc011590 · Cited by 9 · see citing works
“Either case highlights the importance of careful sampling campaigns to avoid recrystallized carbonate, which is challenging further back in geologic history when late diagenetic recrystallization tends to be the rule and not the exception (Cummins et al., 2014; Loyd et al., 2015).”
BackgroundAdineh, S., Závada, P., Mukherjee, S., Bruthans, J., & Zare, M. (2024) · Marine and Petroleum Geology · doi:10.1016/j.marpetgeo.2024.107228 · Cited by 6 · see citing works
Adineh, S., Závada, P., Bruthans, J., & Zare, M. (2024) · Palaeogeography, Palaeoclimatology, Palaeoecology · doi:10.1016/j.palaeo.2024.112670 · Cited by 4 · see citing works
Li, D., Hu, C., Li, X., Su, H., Quaye, J. A., & Yuan, Q. (2025) · Marine and Petroleum Geology · doi:10.1016/j.marpetgeo.2025.107352 · Cited by 5 · see citing works
Reconstructing the basin thermal history with clumped isotope
Xu, Q., Qiu, N., Liu, W., & Chang, Q. H. (2018) · Chinese Science Bulletin (Chinese Version) · doi:10.1360/n972018-00458 · Cited by 5 · see citing works
“更为具体的实验流程参见文献 [28].”
Seawater temperatures during the early to middle Ediacaran: Phosphate oxygen isotope records
Fan, H., Chen, Z., Zhang, F., Zhu, C., Du, S., Zhang, Y., Wen, H., Khan, D., & Algeo, T. J. (2025) · Chemical Geology · doi:10.1016/j.chemgeo.2025.122642 · Cited by 4 · see citing works
Hu, A., Shen, A., Wang, Y., Pan, L., Wang, Y., Hao, Y., & Zhang, J. (2019) · Journal of Natural Gas Geoscience · doi:10.1016/j.jnggs.2019.04.002 · Cited by 4 · see citing works
Kapcsolt izotópok (clumped isotopes) a földtudományi kutatásokban
Kele, S., & Bajnai, D. (2017) · Földtani Közlöny · doi:10.23928/foldt.kozl.2017.147.2.177 · Cited by 2 · see citing works
Witkosky, R., & Wernicke, B. P. (2018) · Abstracts with programs - Geological Society of America · doi:10.1130/abs/2018rm-314317
MAJOR CONTROLS ON DIAGENESIS IN THE MARTIN BRIDGE FORMATION: WALLOWA MOUNTAINS, OREGON
Eisenberg, J. L., & Bershaw, J. (2021) · Abstracts with programs - Geological Society of America · doi:10.1130/abs/2021am-370334
“Similar approaches have been used by Loyd et al. (2015) and Huntington et al. (2011) to explore clumped isotope temperature and isotope 15 relationships of diagenetic calcites in limestones both (relatively) modern and ancient.”
BackgroundMethodInfluentialLange, L., Diório, G. R., Bahniuk, A. M., & Cury, L. F. (2023) · Journal of South American Earth Sciences · doi:10.1016/j.jsames.2023.104459
Ping, H., Deng, W., Chen, H., Guo, Y., Kong, K., Yang, X., & Liu, J. (2024) · Marine and Petroleum Geology · doi:10.1016/j.marpetgeo.2024.106773
Ortega, T., Woods, A., Tripati, A., Westrick-Snapp, B., & Loyd, S. J. (2025) · Journal of Sedimentary Research · doi:10.2110/jsr.2025.042
Self-citationWostbrock, J. A. G., & Planavsky, N. J. (2026) · Earth and Planetary Science Letters · doi:10.1016/j.epsl.2026.120005
- Authors
- Loyd, S. J., Corsetti, F. A., Eagle, R. A., Hagadorn, J. W., Shen, Y., Zhang, X., Bonifacie, M., & Tripati, A. K.
- Affiliations
- University of Southern California (US)
- California Institute of Technology (US)
- Denver Museum of Nature and Science (US)
- University of Science and Technology of China (CN)
- Centre National de la Recherche Scientifique (FR)
- California NanoSystems Institute (US)
- Corresponding author
- Loyd, S.J.
- Tripati, A.K.
- Venue
- Precambrian Research
- Publisher
- Elsevier BV
- Published
- 2015-07
- Volume
- 264
- Pages
- 179-191
- ISSN
- 0301-9268 (ISSN-L)
- OpenAlex
- W2071598269
- Cited by
- 45
- References
- 82
- Citations by year
- 2026: 1 · 2025: 4 · 2024: 4 · 2023: 1 · 2022: 2 · 2021: 5 · 2020: 2 · 2019: 3 · 2018: 8 · 2017: 8 · 2016: 7
- FWCI
- 5.82
- Type
- journal article
- Language
- en
- Open access
- bronze
- doi.org
- Licence
- Locations
- Precambrian Research (acceptedVersion)
- CaltechAUTHORS (California Institute of Technology) (submittedVersion)
- HAL (submittedVersion, other-oa)
- eScholarship (California Digital Library) (submittedVersion)
- OSTI OAI (U.S. Department of Energy Office of Scientific and Technical Information) (submittedVersion)
- Funders
- Agouron Institute
- National Science Foundation (ARC-1215551, EAR-1024929, EAR-0949191, EAR-1325054, EAR-1352212)
- BES (DE-SC0010288)
- American Chemical Society (51182-DNI2)
- National Natural Science Foundation of China (NNSFC 41025011)
- Topics
- Physical Sciences › Earth and Planetary Sciences › Paleontology › Paleontology and Stratigraphy of Fossils
- Physical Sciences › Earth and Planetary Sciences › Geophysics › Geological and Geochemical Analysis
- Physical Sciences › Earth and Planetary Sciences › Atmospheric Science › Geology and Paleoclimatology Research
- Keywords
- Neoproterozoic carbonates, clumped isotope thermometry, carbonate recrystallization, carbon isotope excursion, diagenesis
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