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Cited by 87

The DOI matches its Crossref record; 57 of the 57 references it cites were found in a registry or an index.

Rate-limited mass transfer and transport of organic solutes in porous media that contain immobile immiscible organic liquid

Brusseau, Mark L.·1992·Water Resources Research
DOI 10.1029/91wr02498
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Abstract

A general model is presented that simulates the effect of an immobile immiscible organic liquid, as well as rate‐limited solid phase sorption, on the transport of dissolved organic contaminants in heterogeneous porous media. Specific models are developed for four cases (1) immobile immiscible liquid that resides in nonadvective domains of a heterogeneous porous medium; (2) immobile immiscible liquid that resides in the advective domain; (3) homogeneous porous media wherein mass transfer within the immiscible liquid, as well as across the liquid‐water interface, is rate limited; (4) homogeneous porous media with a single resistance to liquid‐liquid mass transfer. The performance of the homogeneous‐based, single‐resistance model was evaluated by attempting to predict a break‐through curve reported in the literature. Based on the successful prediction of the data, where values for all parameters were obtained independent of the data being simulated, it appears that the conceptual basis of the model is valid. Through a series of simulations, the effect of the immiscible liquid on retention was shown to be great, even at relatively low levels of saturation. Release of solute from residual saturation located within regions of relatively low hydraulic conductivity can be significantly rate limited, even when mass transfer between immiscible liquid and water is rapid. This has ramifications concerning the efficacy of remediation systems based on imposed hydraulic gradients (e.g., pump‐and‐treat). The model should prove useful in further investigations of the effect of immobile immiscible organic liquids on the retention and transport of organic solutes in porous media.

Overview

Integrity signals

Registry

Crossref · 10.1029/91wr02498

Cites

57 of 57 references verified0 citation errors · 0 not checkable

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Citations

Cites

Research works printed but not linked: 4

  1. Bouchard D. C., 1989, Reactions and Movement of Organic Chemicals in Soils, SSSA Spec. Publ., 349
  2. Pellett G. L., 1966, Longitudinal dispersion, intraparticle diffusion, and liquid‐phase mass transfer during flow through multiparticle systems, Tappi, 49, 75
  3. Schwille F., 1988, Dense Chlorinated Solvents in Porous and Fractured Media
  4. Wilson J. L. S. H.Conrad Is physical displacement of residual hydrocarbons a realistic possibility in aquifer restoration?conference on Petroleum Hydrocarbons and Organic Chemicals in Ground WaterNatl. Water Well Assoc.Houston Tex.Nov. 5–7 1984.

Cited by

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Metadata

Authors
Brusseau, M. L.
Venue
Water Resources Research
Publisher
American Geophysical Union (AGU)
Published
1992-01
Volume
28
Issue
1
Pages
33-45
ISSN
  • 0043-1397
  • 1944-7973
DOI
10.1029/91wr02498
Cited by
87
References
57
Language
en
Licence
onlinelibrary.wiley.com/termsAndConditions#vor (vor, 6764 d)

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Data sources

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.