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Mass Transfer Studies in Sorbing Porous Media I. Analytical Solutions
Abstract
An analytical solution is presented for the movement of chemicals through a sorbing porous medium with lateral or intra‐aggregate diffusion. The liquid phase in the porous medium is divided into mobile and immobile regions. Diffusional transfer between the two liquid regions is assumed to be proportional to the concentration difference between the mobile and immobile liquids. Sorption processes in both the dynamic and stagnant regions of the medium are assumed to be instantaneous and the adsorption isotherm is assumed to be linear. The analytical model derived here describes the extensive tailing observed during flow through an unsaturated, aggregated sorbing medium and explains the often observed early breakthrough of chemicals in the effluent.
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Cited by
Tedoldi, D., Chebbo, G., Pierlot, D., Kovacs, Y., & Gromaire, M.-C. (2016) · Science of The Total Environment · doi:10.1016/j.scitotenv.2016.04.215 · Cited by 160
Simulating PFAS transport influenced by rate-limited multi-process retention
Brusseau, M. L. (2020) · Water Research · doi:10.1016/j.watres.2019.115179 · Cited by 127
Brusseau, M. L. (1992) · Water Resources Research · doi:10.1029/91wr02498 · Cited by 87
Fesch, C., Simon, W., Haderlein, S. B., Reichert*, P., & Schwarzenbach, R. P. (1998) · Journal of Contaminant Hydrology · doi:10.1016/s0169-7722(97)00078-8 · Cited by 86
Stults, J. F., Choi, Y. J., Schaefer, C. E., Illangasekare, T. H., & Higgins, C. P. (2022) · Environmental Science & Technology · doi:10.1021/acs.est.2c00819 · Cited by 46
Metadata
- Authors
- van Genuchten, M. T., & Wierenga, P. J.
- Venue
- Soil Science Society of America Journal
- Publisher
- Wiley
- Published
- 1976-07
- Volume
- 40
- Issue
- 4
- Pages
- 473-480
- ISSN
- 0361-5995 (ISSN-L)
- 1435-0661
- OpenAlex
- W1977745027
- Cited by
- 1,569
- References
- 0
- FWCI
- 14.67
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Mass Transfer Studies in Sorbing Porous Media I. Analytical Solutions. https://app.cochat.ai/papers/10.2136/sssaj1976.03615995004000040011x
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- van Genuchten, M. T., & Wierenga, P. J. (1976). Mass Transfer Studies in Sorbing Porous Media I. Analytical Solutions. Soil Science Society of America Journal. https://doi.org/10.2136/sssaj1976.03615995004000040011x
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
