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Energy, volatile production, and climatic effects of the Chicxulub Cretaceous/Tertiary impact
Abstract
A comprehensive analysis of volatiles in the Chicxulub impact strongly supports the hypothesis that impact‐generated sulfate aerosols caused over a decade of global cooling, acid rain, and disruption of ocean circulation, which contributed to the mass extinction at the Cretaceous/Tertiary (K/T) boundary. The crater size, meteoritic content of the K/T boundary clay, and impact models indicate that the Chicxulub crater was formed by a short period comet or an asteroid impact that released 0.7–3.4×10 31 ergs of energy. Impact models and experiments combined with estimates of volatiles in the projectile and target rocks predict that over 200 gigatons (Gt) each of SO 2 and water vapor, and over 500 Gt Of CO 2, were globally distributed in the stratosphere by the impact. Additional volatiles may have been produced on a global or regional scale that formed sulfate aerosols rapidly in cooler parts of the vapor plume, causing an early, intense pulse of sulfuric acid rain. Estimates of the conversion rate of stratospheric SO 2 and water vapor to sulfate aerosol, based on volcanic production of sulfate aerosols, coupled with calculations of diffusion, coagulation, and sedimentation, demonstrate that the 200 Gt stratospheric SO 2 and water vapor reservoir would produce sulfate aerosols for 12 years. These sulfate aerosols caused a second pulse of acid rain that was global. Radiative transfer modeling of the aerosol clouds demonstrates (1) that if the initial rapid pulse of sulfate aerosols was global, photosynthesis may have been shut down for 6 months and (2) that for the second prolonged aerosol cloud, solar transmission dropped 80% by the end of first year and remained 50% below normal for 9 years. As a result, global average surface temperatures probably dropped between 5° and 31°K, suggesting that global near‐freezing conditions may have been reached. Impact‐generated CO 2 caused less than 1°K greenhouse warming and therefore was insignificant compared to the sulfate cooling. The magnitude of sulfate cooling depends largely upon the rate of ocean mixing as surface waters cool, sink, and are replaced by upwelling of deep ocean water. This upwelling apparently drastically altered ocean stratification and circulation, which may explain the global collapse of the delta 13 C gradient between surface and deep ocean waters at the K/T boundary.
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In the citing paper
“The lithology of the target rocks collided by the Chicxulub asteroid led to a massive release of hundreds of Gigatonnes (Gt) of sulfates (21, 22, 51)”
From Asteroid impact, not volcanism, caused the end-Cretaceous dinosaur extinction (2020) · cites this paper as [22]
In the citing paper
“Several modeling approaches have attempted to reproduce the climatic conditions at the K/Pg boundary (20–22), but none have so far quantified the abiotic effect on biological habitability.”
From Asteroid impact, not volcanism, caused the end-Cretaceous dinosaur extinction (2020) · cites this paper as [22]
In the citing paper
“Even assuming the highest intensity of sulfur injections caused by Deccan volcanism (and longest atmospheric residence times), the order of magnitude of these releases barely approaches the lowest estimates of release by the Chicxulub impactor (20–22).”
From Asteroid impact, not volcanism, caused the end-Cretaceous dinosaur extinction (2020) · cites this paper as [22]
In the citing paper
“with a correlated cooling effect of 27 °C (22).”
From Asteroid impact, not volcanism, caused the end-Cretaceous dinosaur extinction (2020) · cites this paper as [22]
In the citing paper
“A stratospheric residence time of ∼6 y for the sulfate aerosol was implemented taking into account the longer hypothesized residence time of Pierazzo et al. (20) due to increased atmospheric stratification (21, 22) as a result of concurrent surface cooling and stratospheric warming (70).”
From Asteroid impact, not volcanism, caused the end-Cretaceous dinosaur extinction (2020) · cites this paper as [22]
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Cited by
Asteroid impact, not volcanism, caused the end-Cretaceous dinosaur extinction
Chiarenza, A. A., Farnsworth, A., Mannion, P. D., Lunt, D. J., Valdes, P. J., Morgan, J. V., & Allison, P. A. (2020) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.2006087117 · Cited by 228
Metadata
- Authors
- Pope, K. O., Baines, K. H., Ocampo, A. C., & Ivanov, B. A.
- Venue
- Journal of Geophysical Research: Planets
- Publisher
- American Geophysical Union (AGU)
- Published
- 1997-09
- Volume
- 102
- Issue
- E9
- Pages
- 21645-21664
- ISSN
- 0148-0227
- Cited by
- 174
- References
- 1
- Language
- en
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