The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Kinetics of calcite nucleation: Magnesium ion inhibition and ionic strength catalysis
Abstract
Kinetics of calcite crystallization from dilute MgCl2 solutions equilibrated with aragonite and atmospheric CO2 were studied. Patterns of per cent calcite against time and Mg++ concentration against time indicate Mg++ inhibits calcite nucleation and in the process is incorporated into the calcite lattice. Uptake of Mg++ by calcite nuclei was then used to monitor calcite nucleation rates under conditions of constant supersaturation and varying ionic strength. Nucleation rates were found to be proportional to the square root of the ionic strength. An analogy between nucleation catalysis by ionic strength and colloid flocculation by salts in aqueous solution is suggested.
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Citations
Cites
Bischoff, J. L., & Fyfe, W. S. (1968) · American Journal of Science · doi:10.2475/ajs.266.2.65 · Cited by 225
Self-citation
Cited by
The role of magnesium in the crystal growth of calcite and aragonite from sea water
Berner, R. A. (1975) · Geochimica et Cosmochimica Acta · doi:10.1016/0016-7037(75)90102-7 · Cited by 807
The interaction of magnesium with calcite during crystal growth at 25–90°C and one atmosphere
Katz, A. (1973) · Geochimica et Cosmochimica Acta · doi:10.1016/0016-7037(73)90091-4 · Cited by 326
Stein, M., Starinsky, A., Katz, A., Goldstein, S. L., Machlus, M., & Schramm, A. (1997) · Geochimica et Cosmochimica Acta · doi:10.1016/s0016-7037(97)00191-9 · Cited by 289
The crystallization of calcium carbonate
Reddy, M. M., & Nancollas, G. H. (1976) · Journal of Crystal Growth · doi:10.1016/0022-0248(76)90240-2 · Cited by 203
Fluid supersaturation and crystallization in porous media
Putnis, A., Prieto, M., & Fernandez-Diaz, L. (1995) · Geological Magazine · doi:10.1017/s0016756800011389 · Cited by 192
Metadata
- Authors
- Bischoff, J. L.
- Venue
- Journal of Geophysical Research
- Publisher
- American Geophysical Union (AGU)
- Published
- 1968-05-15
- Volume
- 73
- Issue
- 10
- Pages
- 3315-3322
- ISSN
- 0148-0227 (ISSN-L)
- OpenAlex
- W2138544537
- Cited by
- 174
- References
- 1
- FWCI
- 1.90
- Type
- journal article
- Language
- en
- Open access
- closed
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
