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Spectral reflectance of carbonate minerals in the visible and near infrared (0.35–2.55 um): Anhydrous carbonate minerals

Gaffey, Susan J.·1987·Journal of Geophysical Research: Solid Earth

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Abstract

Reflectance spectroscopy in the visible and near infrared (0.35–2.55 um) offers a rapid, inexpensive, nondestructive technique for determining the mineralogy and gaining information on the minor element chemistry of carbonate minerals and rocks. Spectra of all commonly occurring anhydrous end‐member carbonate minerals contain seven strong absorption bands at wavelengths >1.6 um due to vibrations of the carbonate radical. Positions, widths, and spacing between carbonate bands are diagnostic of mineralogy. Differences in positions of carbonate bands between spectra of different minerals are primarily due to differences in mass of the major cation, with cation electronegativity playing a secondary role. Spectra of calcite group minerals may contain absorption features due to transition metal cations such as Fe and Mn, which can also aid in mineral identification. Spectra confirm the occurrence of both cations in the divalent state. Fe 2+ produces a broad feature near 1.1 um whose position and degree of doubling are related to the size and degree of distortion of the octahedral site, as predicted by crystal field theory. Mn 2+ and Fe 2+ produce very strong absorption bands in the minerals for which they are the major cation (rhodochrosite and siderite, respectively), making it easy to distinguish these from other carbonate minerals, even when presence of water bands may make it difficult to determine accurately carbonate band positions.

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Authors: Gaffey, S. J.
Corresponding author: Gaffey, Susan J.
Venue: Journal of Geophysical Research: Solid Earth
Publisher: American Geophysical Union (AGU)
Published: 1987-02-10
Volume: 92
Issue: B2
Pages: 1429-1440
ISSN: 0148-0227 (ISSN-L)
DOI: 10.1029/jb092ib02p01429
OpenAlex: W2016376046
Cited by: 323
References: 38
Citations by year: 2026: 24 · 2025: 14 · 2024: 10 · 2023: 15 · 2022: 18 · 2021: 20 · 2020: 22 · 2019: 17 · 2018: 12 · 2017: 17 · 2016: 15 · 2015: 16 · 2014: 11 · 2013: 9 · 2012: 12
FWCI: 0.76
Type: journal article
Language: en
Open access: closed
Licence: onlinelibrary.wiley.com/termsAndConditions#vor (vor, 9354 d)
Locations: Journal of Geophysical Research Atmospheres (publishedVersion)
Topics: Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Geochemistry and Geologic Mapping
Physical Sciences › Earth and Planetary Sciences › Space and Planetary Science › Planetary Science and Exploration
Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Mineralogy and Gemology Studies
Keywords: carbonate minerals, spectral reflectance, rhodochrosite, siderite, transition metal ions, ferrous iron, manganese(II), crystal field theory, mineral identification, near-infrared spectroscopy, visible spectroscopy

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Spectral reflectance of carbonate minerals in the visible and near infrared (0.35–2.55 um): Anhydrous carbonate minerals

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