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Cited by 350

The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.

Isotopic exchange effects in the evaporation of water: 1. Low-temperature experimental results

Craig, H., Gordon, L. I., Horibe, Y.·1963·Journal of Geophysical Research

Abstract

The deuterium and oxygen 18 concentrations of water evaporating into air of nonzero humidity do not follow the simple batch distillation equation but increase asymptotically to a stationary isotopic state as the mass of water decreases to zero. This effect is due to a rapid molecular exchange between liquid and vapor, which predominates over the simple separation effect of removal of vapor. In diy air the batch distillation law is obeyed, and the isotopic enrichment continually increases; however, the separation factor is larger than the equilibrium isotopic vapor pressure ratio when the evaporation rate is comparable to natural rates. The HDO and H2O18 enrichments in our experiments show a linear correlation with a slope of about 5.5, as found in the evaporation of natural water bodies. The mechanism of the molecular exchange will be described in following papers.

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Research works printed but not linked: 8

  1. Baertschi, 1960, Isotopie-effekt fur die trennung der sauerstoff-isotopen O16 und O18 bei der rektifikation von leichtem und schwerem wasser, Helv. Chim. Acta, 43, 80, 10.1002/hlca.19600430111 · DOI
  2. Craig, 1961, Isotopic variations in meteoric waters, Science, 133, 1702, 10.1126/science.133.3465.1702 · DOI · Paper page
  3. Craig, 1961, Mass spectrometer analyses of radiocarbon standards, Radiocarbon, 3, 1, 10.1017/S0033822200020774 · DOI
  4. Friedman, 1953, Deuterium content of natural water and other substances, Geochim. Cosmochim. Acta, 4, 89, 10.1016/0016-7037(53)90066-0 · DOI
  5. Horibe, 1960, Deuterium abundance of natural waters, Geochim. Cosmochim. Acta, 20, 273, 10.1016/0016-7037(60)90078-8 · doi:10.1016/0016-7037(60)90078-8
  6. Merlivat, 1963, Fractionment isotopique au cours de la distillation de l'eau, J. Chim. Phys., 60, 56, 10.1051/jcp/1963600056 · DOI
  7. Miles, 1936, The vapor pressure of deuterium water from 20 to 230°, J. Am. Chem. Soc., 58, 1067, 10.1021/ja01298a001 · doi:10.1021/ja01298a001
  8. Wahl, 1935, The vapor pressures of the isotopic forms of water, J. Chem. Phys., 3, 411, 10.1063/1.1749690 · doi:10.1063/1.1749690

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Metadata

Authors
Craig, H., Gordon, L. I., & Horibe, Y.
Venue
Journal of Geophysical Research
Published
1963-09-01
Volume
68
Issue
17
Pages
5079-5087
ISSN
0148-0227 (ISSN-L)
OpenAlex
W2052739880
Cited by
350
References
2
FWCI
12.38
Type
journal article
Language
en
Open access
closed
Licence
doi.wiley.com/10.1002/tdm_license_1.1 (tdm, 18993 d)

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CoChat. (2026). Citation check: Isotopic exchange effects in the evaporation of water: 1. Low-temperature experimental results. https://app.cochat.ai/papers/10.1029/jz068i017p05079
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Craig, H., Gordon, L. I., & Horibe, Y. (1963). Isotopic exchange effects in the evaporation of water: 1. Low-temperature experimental results. Journal of Geophysical Research. https://doi.org/10.1029/jz068i017p05079

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