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Sodium carbonate-bicarbonate minerals as indicators of P co2
Abstract
The CO2 content of a gas phase equilibrated with the assemblages nahcolite + trona + solution, nahcolite + trona + halite + solution, and trona + thermonatrite + solution has been determined at 1 atm pressure, using an infrared method. Equilibrium was approached from both sides. Between 20 and 60°C, the CO2 content of the gas for the assemblage nahcolite + trona + solution + gas varies from 1475 to 20,300 ppm, and that for the assemblage trona + thermonatrite + solution + gas changes from 20 ppm at 40°C to 435 ppm at 70°C. These results were applied to the Eocene Green River formation and the Pleistocene Searles Lake deposits. In both cases, it is concluded that the CO2 contents of the paleoatmospheres must have been within the range specified by the trona + solution assemblage, that is, between 10 times and 1/10 of the CO2 content of today's atmosphere.
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Nahcolite would not be an effective tracer of the early Martian atmosphere given the present Pco2 on Mars of ~6 mbar.
“Thus, while useful for studies of terrestrial palcoatmospheres (as originally suggested by Eugster [1966]), nahcolitc would not be an effective tracer of the early Martian atmosphere given the present Pco2 on Mars of •0 6 mbar.”
From A chemical model for evaporites on early Mars: Possible sedimentary tracers of the early climate and implications for exploration (1999) · cites this paper as Eugster, 1966
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Metadata
- Authors
- Eugster, H. P.
- Corresponding author
- Eugster, Hans P.
- Venue
- Journal of Geophysical Research
- Publisher
- American Geophysical Union (AGU)
- Published
- 1966-07-15
- Volume
- 71
- Issue
- 14
- Pages
- 3369-3377
- ISSN
- 0148-0227 (ISSN-L)
- OpenAlex
- W2107866190
- Cited by
- 84
- References
- 43
- Citations by year
- 2026: 2 · 2025: 4 · 2024: 4 · 2023: 5 · 2022: 3 · 2020: 3 · 2019: 7 · 2018: 3 · 2017: 4 · 2016: 1 · 2015: 4 · 2014: 5 · 2013: 4 · 2012: 2
- FWCI
- 0.00
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of Geophysical Research Atmospheres (publishedVersion)
- Topics
- Physical Sciences › Earth and Planetary Sciences › Paleontology › Paleontology and Stratigraphy of Fossils
- Physical Sciences › Earth and Planetary Sciences › Atmospheric Science › Geology and Paleoclimatology Research
- Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Geological and Geochemical Analysis
- Keywords
- paleoatmospheric CO2, nahcolite, trona, halite, CO2 solubility, Green River Formation, Eocene, Pleistocene, paleoclimate
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
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