Cited by 346Battery Modeling and ManagementAdvancements in Battery MaterialsAdvanced Battery Materials and Technologies

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Runaway risk of forming toxic compounds

Hammami, Amer, Raymond, Nathalie, Armand, Michel·2003·Nature

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Abstract

Lithium-ion batteries are stabilized by an ultrathin protective film that is 10-50 nanometers thick and coats both electrodes. Here we artificially simulate the 'thermal-runaway' conditions that would arise should this coating be destroyed, which could happen in a battery large enough to overheat beyond 80 degrees C. We find that under these conditions the reaction of the battery electrolyte with the material of the unprotected positive electrode results in the formation of toxic fluoro-organic compounds. Although not a concern for the small units used in today's portable devices, this unexpected chemical hazard should be taken into account as larger and larger lithium-ion batteries are developed, for example for incorporation into electric-powered vehicles.

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Organic fluorine compounds. Part XXXV. The reaction of ethylene carbonates with nucleophilic reagents
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Gitter, S., Blank, I. & Bergmann, E. D. K. Ned. Akad. Wetenschap. Proc. C 56, 427–430 (1953).

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Authors: Hammami, A., Raymond, N., & Armand, M.
Affiliations: Centre National de la Recherche Scientifique (FR)
Corresponding author: Armand, Michel
ORCID: Armand, Michel
Venue: Nature
Publisher: Springer Science and Business Media LLC
Published: 2003-08
Volume: 424
Issue: 6949
Pages: 635-636
ISSN: 0028-0836 (ISSN-L)
1476-4687
DOI: 10.1038/424635b
OpenAlex: W2003015218
Cited by: 346
References: 1
Citations by year: 2026: 8 · 2025: 13 · 2024: 16 · 2023: 20 · 2022: 28 · 2021: 20 · 2020: 28 · 2019: 29 · 2018: 30 · 2017: 26 · 2016: 25 · 2015: 17 · 2014: 19 · 2013: 13 · 2012: 13
FWCI: 16.13
Type: journal article
Language: en
Open access: closed
Licence: www.springer.com/tdm (tdm)
Locations: Nature (publishedVersion)
PubMed (publishedVersion)
RePEc: Research Papers in Economics (submittedVersion)
Topics: Physical Sciences › Engineering › Automotive Engineering › Battery Modeling and Management
Physical Sciences › Engineering › Electrical and Electronic Engineering › Advancements in Battery Materials
Physical Sciences › Engineering › Electrical and Electronic Engineering › Advanced Battery Materials and Technologies
Keywords: lithium-ion batteries, thermal runaway, protective coatings, positive electrode, electrolyte decomposition, electric vehicles, battery safety

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