Stability of magnesite and its high-pressure form in the lowermost mantle
Abstract
Carbonates are important constituents of marine sediments and play a fundamental role in the recycling of carbon into the Earth's deep interior via subduction of oceanic crust and sediments. Study of the stability of carbonates under high pressure and temperature is thus important for modelling the carbon budget in the entire Earth system. Such studies, however, have rarely been performed under appropriate lower-mantle conditions and no experimental data exist at pressures greater than 80 GPa (refs 3-6). Here we report an in situ X-ray diffraction study of the stability of magnesite (MgCO(3)), which is the major component of subducted carbonates, at pressure and temperature conditions approaching those of the core-mantle boundary. We found that magnesite transforms to an unknown form at pressures above approximately 115 GPa and temperatures of 2,100-2,200 K (depths of approximately 2,600 km) without any dissociation, suggesting that magnesite and its high-pressure form may be the major hosts for carbon throughout most parts of the Earth's lower mantle.
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High-pressure phase transitions were observed in magnesite and Fe-magnesite.
“High-pressure phase transitions were observed in magnesite and Fe-magnesite (Boulard et al., 2011;Isshiki et al., 2004).”
From Structures and Crystal Chemistry of Carbonate at Earth's Mantle Conditions (2020) · cites this paper as Isshiki et al., 2004
Magnesite is considered to be a potentially major reservoir of carbon in the Earth's mantle.
“Considered to be a potentially major reservoir of carbon in the Earth's mantle (Wang et al., 1996; Isshiki et al., 2004; Hazen and Schiffries, 2013)”
From Clumped-isotope thermometry of magnesium carbonates in ultramafic rocks (2016) · cites this paper as Isshiki et al., 2004
Cites
Preliminary reference Earth model
Dziewoński, A. M., & Anderson, D. L. (1981) · Physics of The Earth and Planetary Interiors · doi:10.1016/0031-9201(81)90046-7 · Cited by 10,334 · see citing works
Mao, H., Bell, P. M., Shaner, J. W., & Steinberg, D. (1978) · Journal of Applied Physics · doi:10.1063/1.325277 · Cited by 2,281 · see citing works
Chopin, C. (1984) · Contributions to Mineralogy and Petrology · doi:10.1007/bf00381838 · Cited by 1,350 · see citing works
Subducting slabs stagnant in the mantle transition zone
Fukao, Y., Obayashi, M., Inoue, H., & Nenbai, M. (1992) · Journal of Geophysical Research Atmospheres · doi:10.1029/91jb02749 · Cited by 669 · see citing works
High-Pressure Research in Geophysics
(1982) · Springer eBooks · doi:10.1007/978-94-009-7867-6 · Cited by 615 · see citing works
Thermodynamic parameters in the Earth as determined from seismic profiles
Brown, J. M., & Shankland, T. J. (1981) · Geophysical Journal International · doi:10.1111/j.1365-246x.1981.tb04891.x · Cited by 613 · see citing works
Tomographic imaging of subducted lithosphere below northwest Pacific island arcs
van der Hist, R., Engdahl, E. R., Spakman, W., & Nolet, G. (1991) · Nature · doi:10.1038/353037a0 · Cited by 570 · see citing works
Mars and Earth: Origin and Abundance of Volatiles
Anders, E., & Owen, T. (1977) · Science · doi:10.1126/science.198.4316.453 · Cited by 378 · see citing works
Seismic structure and origin of hotspots and mantle plumes
Zhao, D. (2001) · Earth and Planetary Science Letters · doi:10.1016/s0012-821x(01)00465-4 · Cited by 350 · see citing works
Hammouda, T. (2003) · Earth and Planetary Science Letters · doi:10.1016/s0012-821x(03)00361-3 · Cited by 337 · see citing works
Wyllie, P. J., & Huang, W.-L. (1976) · Contributions to Mineralogy and Petrology · doi:10.1007/bf00372117 · Cited by 322 · see citing works
Nature of the 650–km seismic discontinuity: implications for mantle dynamics and differentiation
Ringwood, A. E., & Irifune, T. (1988) · Nature · doi:10.1038/331131a0 · Cited by 308 · see citing works
Self-citationPressure Measurement at High Temperature in X-Ray Diffraction Studies: Gold as a Primary Standard
Jamieson, J. C., Fritz, J. N., & Manghnani, M. H. (1982) · Springer eBooks · doi:10.1007/978-94-009-7867-6_3 · Cited by 303 · see citing works
Experimental evidence for carbonate stability in the Earth's lower mantle
Biellmann, C., Gillet, P., Guyot, F., Peyronneau, J., & Reynard, B. (1993) · Earth and Planetary Science Letters · doi:10.1016/0012-821x(93)90157-5 · Cited by 167 · see citing works
Magnesite-bearing inclusion assemblage in natural diamond
Wang, A., Pasteris, J. D., Meyer, H. O. A., & Dele-Duboi, M. L. (1996) · Earth and Planetary Science Letters · doi:10.1016/0012-821x(96)00053-2 · Cited by 132 · see citing works
Lower Mantle Mineral Associations Preserved in Diamonds
Harte, B. (1994) · Mineralogical Magazine · doi:10.1180/minmag.1994.58a.1.201 · Cited by 131 · see citing works
Structural refinements of magnesite at very high pressure
Fiquet, G., Guyot, F., Kunz, M., Matas, J., Andrault, D., & Hanfland, M. (2002) · American Mineralogist · doi:10.2138/am-2002-8-927 · Cited by 120 · see citing works
Evidence from ultra-high-pressure marbles for recycling of sediments into the mantle
Becker, H., & Altherr, R. (1992) · Nature · doi:10.1038/358745a0 · Cited by 105 · see citing works
Stability and equation of state of Fe3C to 73 GPa: Implications for carbon in the Earth's core
Scott, H. P., Williams, Q., & Knittle, E. (2001) · Geophysical Research Letters · doi:10.1029/2000gl012606 · Cited by 102 · see citing works
Watanuki, T., Shimomura, O., Yagi, T., Kondo, T., & Isshiki, M. (2001) · Review of Scientific Instruments · doi:10.1063/1.1343869 · Cited by 91 · see citing works
Self-citationLIN, C.-C., & LIU, L.-G. (1997) · Journal of Physics and Chemistry of Solids · doi:10.1016/s0022-3697(96)00201-6 · Cited by 70 · see citing works
Domanik, K. J., & Holloway, J. (2000) · Lithos · doi:10.1016/s0024-4937(99)00084-5 · Cited by 69 · see citing works
Gillet, P. (1993) · Infoscience (Ecole Polytechnique Fédérale de Lausanne) · Cited by 59 · see citing works
High pressure phase transformations in aragonite-type carbonates
Lin, C.-C., & Liu, L.-G. (1997) · Physics and Chemistry of Minerals · doi:10.1007/s002690050028 · Cited by 45 · see citing works
Stability of Magnesite under the Lower Mantle Conditions.
Katsura, T., TSUCHIDA, Y., Ito, E., Yagi, T., Utsumi, W., & Akimoto, S. (1991) · Proceedings of the Japan Academy Series B · doi:10.2183/pjab.67.57 · Cited by 30 · see citing works
Genesis of diamonds in the lower mantle
Liu, L.-G. (1999) · Contributions to Mineralogy and Petrology · doi:10.1007/s004100050476 · Cited by 11 · see citing works
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The deep carbon cycle and melting in Earth's interior
Dasgupta, R., & Hirschmann, M. M. (2010) · Earth and Planetary Science Letters · doi:10.1016/j.epsl.2010.06.039 · Cited by 1,027 · see citing works
High-pressure phases of CaCO3: Crystal structure prediction and experiment
Оганов, А. Р., Glass, C. W., & Ono, S. (2005) · Earth and Planetary Science Letters · doi:10.1016/j.epsl.2005.10.014 · Cited by 345 · see citing works
Self-citationSource of parental melts to carbonatites–critical isotopic constraints
Bell, K., & Simonetti, A. (2009) · Mineralogy and Petrology · doi:10.1007/s00710-009-0059-0 · Cited by 282 · see citing works
Novel high-pressure structures of MgCO3, CaCO3 and CO2 and their role in Earth's lower mantle
Оганов, А. Р., Ono, S., Ma, Y., Glass, C. W., & Garcı́a, A. (2008) · Earth and Planetary Science Letters · doi:10.1016/j.epsl.2008.06.005 · Cited by 231 · see citing works
Self-citationCarbon solubility in mantle minerals
Shcheka, S. S., Wiedenbeck, M., Frost, D. J., & Keppler, H. (2006) · Earth and Planetary Science Letters · doi:10.1016/j.epsl.2006.03.036 · Cited by 197 · see citing works
Spandler, C. J., Hermann, J., Faure, K., Mavrogenes, J., & Arculus, R. (2007) · Contributions to Mineralogy and Petrology · doi:10.1007/s00410-007-0236-2 · Cited by 182 · see citing works
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Hayman, P. C., Kopylova, M., & Kaminsky, F. V. (2005) · Contributions to Mineralogy and Petrology · doi:10.1007/s00410-005-0657-8 · Cited by 181 · see citing works
Kiseeva, E. S., Litasov, K. D., Yaxley, G. M., Ohtani, E., & Kamenetsky, V. S. (2013) · Journal of Petrology · doi:10.1093/petrology/egt023 · Cited by 166 · see citing works
Ghosh, S., Ohtani, E., Litasov, K. D., & Terasaki, H. (2009) · Chemical Geology · doi:10.1016/j.chemgeo.2008.12.030 · Cited by 165 · see citing works
Post-aragonite phase transformation in CaCO3 at 40 GPa
Ono, S. (2005) · American Mineralogist · doi:10.2138/am.2005.1610 · Cited by 150 · see citing works
Self-citationNew host for carbon in the deep Earth
Boulard, E., Gloter, A., Corgne, A., Antonangeli, D., Auzende, A., Perrillat, J., Guyot, F., & Fiquet, G. (2011) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1016934108 · Cited by 140 · see citing works
Structure, Bonding, and Mineralogy of Carbon at Extreme Conditions
Оганов, А. Р., Hemley, R. J., Hazen, R. M., & Jones, A. (2013) · Reviews in Mineralogy and Geochemistry · doi:10.2138/rmg.2013.75.3 · Cited by 131 · see citing works
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Wang, Y., Liu, B., Zhao, X., Zhang, X., Miao, Y., Yang, N., Yang, B. L., Zhang, L., Kuang, W., Li, J., et al. (2018) · Nature Communications · doi:10.1038/s41467-018-06433-5 · Cited by 128 · see citing works
Tao, R., Zhang, L., Tian, M., Zhu, J., Liu, X., Liu, J., Höfer, H. E., Stagno, V., & Fei, Y. (2018) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2018.08.008 · Cited by 123 · see citing works
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Cerantola, V., Bykova, E., Kupenko, I., Merlini, M., Ismailova, L., McCammon, C., Bykov, M., Chumakov, A. I., Petitgirard, S., Kantor, I., et al. (2017) · Nature Communications · doi:10.1038/ncomms15960 · Cited by 120 · see citing works
Seto, Y., Hamane, D., Nagai, T., & Fujino, K. (2008) · Physics and Chemistry of Minerals · doi:10.1007/s00269-008-0215-9 · Cited by 117 · see citing works
High-pressure polymeric phases of carbon dioxide
Sun, J., Klug, D. D., Martoňák, R., Montoya, J. A., Lee, M., Scandolo, S., & Tosatti, E. (2009) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.0812624106 · Cited by 117 · see citing works
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Ono, S., Kikegawa, T., & Ohishi, Y. (2007) · American Mineralogist · doi:10.2138/am.2007.2649 · Cited by 117 · see citing works
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Wu, Z., Wentzcovitch, R. M. M., Umemoto, K., Li, B., Hirose, K., & Zheng, J. (2008) · Journal of Geophysical Research Atmospheres · doi:10.1029/2007jb005275 · Cited by 112 · see citing works
Self-citationStructures of dolomite at ultrahigh pressure and their influence on the deep carbon cycle
Merlini, M., Crichton, W. A., Hanfland, M., Gemmi, M., Müller, H., Kupenko, I., & Dubrovinsky, L. (2012) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1201336109 · Cited by 103 · see citing works
Structure of siderite FeCO3 to 56 GPa and hysteresis of its spin-pairing transition
Lavina, B., Dera, P., Downs, R. T., Yang, W., Sinogeikin, S. V., Meng, Y., Shen, G., & Schiferl, D. (2010) · Physical Review B · doi:10.1103/physrevb.82.064110 · Cited by 103 · see citing works
Single-crystal diffraction at megabar conditions by synchrotron radiation
Merlini, M., & Hanfland, M. (2013) · High Pressure Research · doi:10.1080/08957959.2013.831088 · Cited by 99 · see citing works
Collerson, K. D., Williams, Q., Ewart, A., & Murphy, D. T. (2010) · Physics of The Earth and Planetary Interiors · doi:10.1016/j.pepi.2010.05.008 · Cited by 99 · see citing works
Siderite at lower mantle conditions and the effects of the pressure‐induced spin‐pairing transition
Lavina, B., Dera, P., Downs, R. T., Prakapenka, V. B., Rivers, M. L., Sutton, S. R., & Nicol, M. (2009) · Geophysical Research Letters · doi:10.1029/2009gl039652 · Cited by 98 · see citing works
Kaminsky, F. V., Wirth, R., & Schreiber, A. (2013) · The Canadian Mineralogist · doi:10.3749/canmin.51.5.669 · Cited by 98 · see citing works
Structures and stability of calcium and magnesium carbonates at mantle pressures
Pickard, C. J., & Needs, R. J. (2015) · Physical Review B · doi:10.1103/physrevb.91.104101 · Cited by 94 · see citing works
Unraveling the complexity of iron oxides at high pressure and temperature: Synthesis of Fe 5 O 6
Lavina, B., & Meng, Y. (2015) · Science Advances · doi:10.1126/sciadv.1400260 · Cited by 94 · see citing works
Franzolin, E., Schmidt, M. W., & Poli, S. (2010) · Contributions to Mineralogy and Petrology · doi:10.1007/s00410-010-0527-x · Cited by 89 · see citing works
Experimental investigation of the stability of Fe‐rich carbonates in the lower mantle
Boulard, E., Menguy, N., Auzende, A., Benzerara, K., Bureau, H., Antonangeli, D., Corgne, A., Morard, G., Siebert, J., Perrillat, J., et al. (2011) · Journal of Geophysical Research Atmospheres · doi:10.1029/2011jb008733 · Cited by 88 · see citing works
Cheng, Z., Zhang, Z., Hou, T., Santosh, M., Chen, L., Ke, S., & Xu, L. (2017) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2016.12.036 · Cited by 83 · see citing works
Mineralogy of the Earth – Phase Transitions and Mineralogy of the Lower Mantle
Irifune, T., & Tsuchiya, T. (2007) · Elsevier eBooks · doi:10.1016/b978-044452748-6.00030-4 · Cited by 83 · see citing works
Self-citationStagno, V., Tange, Y., Miyajima, N., McCammon, C. A., Irifune, T., & Frost, D. J. (2011) · Geophysical Research Letters · doi:10.1029/2011gl049560 · Cited by 83 · see citing works
Self-citationDiamond formation in the deep lower mantle: a high-pressure reaction of MgCO3 and SiO2
Maeda, F., Ohtani, E., Kamada, S., Sakamaki, T., Hirao, N., & Ohishi, Y. (2017) · Scientific Reports · doi:10.1038/srep40602 · Cited by 80 · see citing works
Self-citationIron oxidation state in lower mantle mineral assemblages
McCammon, C. A., Lauterbach, S., Seifert, F., Langenhorst, F., & van Aken, P. A. (2004) · Earth and Planetary Science Letters · doi:10.1016/j.epsl.2004.03.018 · Cited by 76 · see citing works
Brik, M. G. (2011) · Physica B Condensed Matter · doi:10.1016/j.physb.2010.12.049 · Cited by 74 · see citing works
Carbonate stability in the reduced lower mantle
Dorfman, S. M., Badro, J., Nabiei, F., Prakapenka, V. B., Cantoni, M., & Gillet, P. (2018) · Earth and Planetary Science Letters · doi:10.1016/j.epsl.2018.02.035 · Cited by 74 · see citing works
Thermal equation of state of magnesite to 32GPa and 2073K
Litasov, K. D., Fei, Y., Ohtani, E., Kuribayashi, T., & Funakoshi, K. (2008) · Physics of The Earth and Planetary Interiors · doi:10.1016/j.pepi.2008.06.018 · Cited by 72 · see citing works
Lin, J., Liu, J., Jacobs, C., & Prakapenka, V. (2012) · American Mineralogist · doi:10.2138/am.2012.3961 · Cited by 71 · see citing works
High-pressure spectroscopic study of siderite (FeCO 3 ) with a focus on spin crossover
Cerantola, V., McCammon, C. A., Kupenko, I., Kantor, I. Y., Marini, C., Wilke, M., Ismailova, L., Solopova, N., Chumakov, A. I., Pascarelli, S., et al. (2015) · American Mineralogist · doi:10.2138/am-2015-5319 · Cited by 70 · see citing works
Deep-seated abiogenic origin of petroleum: From geological assessment to physical theory
Kutcherov, V. G., & Krayushkin, V. A. (2010) · Reviews of Geophysics · doi:10.1029/2008rg000270 · Cited by 69 · see citing works
Tetrahedrally coordinated carbonates in Earth’s lower mantle
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High-Pressure Orthorhombic Ferromagnesite as a Potential Deep-Mantle Carbon Carrier
Liu, J., Lin, J.-F., & Prakapenka, V. B. (2015) · Scientific Reports · doi:10.1038/srep07640 · Cited by 64 · see citing works
Cheng, C., Li, X., Le, Q., Guo, R., Lan, Q., & Cui, J. (2020) · Journal of Magnesium and Alloys · doi:10.1016/j.jma.2019.09.013 · Cited by 62 · see citing works
A primary natrocarbonatitic association in the Deep Earth
Kaminsky, F. V., Ryabchikov, I. D., & Wirth, R. (2015) · Mineralogy and Petrology · doi:10.1007/s00710-015-0368-4 · Cited by 62 · see citing works
Finite element simulations of the laser-heated diamond-anvil cell
Kiefer, B., & Duffy, T. S. (2005) · Journal of Applied Physics · doi:10.1063/1.1906292 · Cited by 60 · see citing works
Dolomite III: A new candidate lower mantle carbonate
Mao, Z., Armentrout, M. M., Rainey, E. S. G., Manning, C. E., Dera, P., Prakapenka, V. B., & Kavner, A. (2011) · Geophysical Research Letters · doi:10.1029/2011gl049519 · Cited by 59 · see citing works
Merlini, M., Hanfland, M., Salamat, A., Petitgirard, S., & Müller, H. (2015) · American Mineralogist · doi:10.2138/am-2015-5369 · Cited by 59 · see citing works
Shatskiy, A. F., Litasov, K. D., & Palyanov, Y. N. (2015) · Russian Geology and Geophysics · doi:10.1016/j.rgg.2015.01.007 · Cited by 58 · see citing works
Wang, X., Xu, X., Ye, Y., Wang, C., Liu, D., Shi, X., Wang, S., & Zhu, X. P. (2019) · Journal of Earth Science · doi:10.1007/s12583-019-1236-7 · Cited by 57 · see citing works
Mata, J., Moreira, M., Doucelance, R., Ader, M., & Silva, L. C. (2010) · Earth and Planetary Science Letters · doi:10.1016/j.epsl.2009.12.052 · Cited by 57 · see citing works
THE ROLE OF CARBON IN EXTRASOLAR PLANETARY GEODYNAMICS AND HABITABILITY
Unterborn, C. T., Kabbes, J. E., Pigott, J. S., Reaman, D. M., & Panero, W. R. (2014) · The Astrophysical Journal · doi:10.1088/0004-637x/793/2/124 · Cited by 57 · see citing works
Thermal equation of state and spin transition of magnesiosiderite at high pressure and temperature
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Experimental determination of siderite stability at high pressure
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Chandra, J., Paul, D., Viladkar, S. G., & Sensarma, S. (2017) · Geological Society London Special Publications · doi:10.1144/sp463.3 · Cited by 55 · see citing works
Sanchez‐Valle, C., Ghosh, S., & Rosa, A. D. (2011) · Geophysical Research Letters · doi:10.1029/2011gl049981 · Cited by 54 · see citing works
Santillán, J. D., & Williams, Q. (2004) · American Mineralogist · doi:10.2138/am-2004-8-925 · Cited by 54 · see citing works
Carbon, carbides, carbonates and carbonatitic melts in the Earth's interior
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Melting and decomposition of MgCO3 at pressures up to 84 GPa
Solopova, N., Dubrovinsky, L., Spivak, A. V., Litvin, Y. А., & Dubrovinskaia, N. (2014) · Physics and Chemistry of Minerals · doi:10.1007/s00269-014-0701-1 · Cited by 53 · see citing works
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Iron oxidation state in lower mantle mineral assemblages
McCammon, C. A., Stachel, T., & Harris, J. W. (2004) · Earth and Planetary Science Letters · doi:10.1016/j.epsl.2004.03.019 · Cited by 53 · see citing works
Bonding and structural changes in siderite at high pressure
Farfán, G., Wang, S., Ma, H., Caracas, R., & Mao, W. L. (2012) · American Mineralogist · doi:10.2138/am.2012.4001 · Cited by 51 · see citing works
Binck, J., Bayarjargal, L., Lobanov, S. S., Morgenroth, W., Luchitskaia, R., Pickard, C. J., Milman, V., Refson, K., Jochym, D. B., Byrne, P. J., et al. (2020) · Physical Review Materials · doi:10.1103/physrevmaterials.4.055001 · Cited by 51 · see citing works
Clumped-isotope thermometry of magnesium carbonates in ultramafic rocks
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Lobanov, S. S., Goncharov, A. F., & Litasov, K. D. (2015) · American Mineralogist · doi:10.2138/am-2015-5053 · Cited by 50 · see citing works
Stability of the MgCO3 structures under lower mantle conditions
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Terasaki, H., Nishida, K., Shibazaki, Y., Sakamaki, T., SUZUKI, A. S., Ohtani, E., & Kikegawa, T. (2010) · Journal of Geophysical Research Atmospheres · doi:10.1029/2009jb006905 · Cited by 49 · see citing works
Raman study of MgCO3–FeCO3 carbonate solid solution at high pressures up to 55 GPa
Spivak, A., Solopova, N., Cerantola, V., Bykova, E., Zakharchenko, E., Dubrovinsky, L., & Litvin, Y. (2014) · Physics and Chemistry of Minerals · doi:10.1007/s00269-014-0676-y · Cited by 48 · see citing works
Phase Transitions and Mineralogy of the Lower Mantle
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Scheller, E. L., Swindle, C., Grotzinger, J. P., Barnhart, H. A., Bhattacharjee, S., Ehlmann, B. L., Farley, K. A., Fischer, W. W., Greenberger, R. N., Ingalls, M., et al. (2021) · Journal of Geophysical Research Planets · doi:10.1029/2021je006828 · Cited by 47 · see citing works
Single-crystal elasticity of the deep-mantle magnesite at high pressure and temperature
Yang, J., Mao, Z., Lin, J., & Prakapenka, V. B. (2014) · Earth and Planetary Science Letters · doi:10.1016/j.epsl.2014.01.027 · Cited by 47 · see citing works
Thermodynamic constraints on carbonate stability and carbon volatility during subduction
Gorce, J. S., Caddick, M. J., & Bodnar, R. J. (2019) · Earth and Planetary Science Letters · doi:10.1016/j.epsl.2019.04.047 · Cited by 47 · see citing works
Stability of dense liquid carbon dioxide
Boates, B., Teweldeberhan, A. M., & Bonev, S. (2012) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1120243109 · Cited by 47 · see citing works
Beyond the Principle of Plentitude: A Review of Terrestrial Planet Habitability
Gaidos, E. J., Deschenes, B., Dundon, L., Fagan, K., Menviel, L., Moskovitz, N., & Workman, M. (2005) · Astrobiology · doi:10.1089/ast.2005.5.100 · Cited by 46 · see citing works
Ray, J. S., Pande, K., Bhutani, R., Shukla, A. D., Vinai, K., Rai, A. K., Awasthi, N., Smitha, R. S., & Panda, D. K. (2013) · Contributions to Mineralogy and Petrology · doi:10.1007/s00410-013-0945-7 · Cited by 45 · see citing works
Liang, W. Y., Yin, Y. Q., Wang, L., Lin, C., & Li, H. (2017) · Journal of Alloys and Compounds · doi:10.1016/j.jallcom.2017.01.258 · Cited by 45 · see citing works
Crystalline polymeric carbon dioxide stable at megabar pressures
Dziubek, K. F., Ende, M., Scelta, D., Bini, R., Mézouar, M., Leonel, G. G., & Miletich, R. (2018) · Nature Communications · doi:10.1038/s41467-018-05593-8 · Cited by 45 · see citing works
Tao, R., Zhang, L., Fei, Y., & Liu, Q. (2014) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2014.02.031 · Cited by 44 · see citing works
Mantle oxidation state and oxygen fugacity: Constraints on mantle chemistry, structure, and dynamics
McCammon, C. A. (2005) · Geophysical monograph · doi:10.1029/160gm14 · Cited by 44 · see citing works
Electronic, optical and bonding properties of MgCO3
Hossain, F. M., Dlugogorski, B. Z., Kennedy, E. M., Belova, I. V., & Murch, G. E. (2010) · Solid State Communications · doi:10.1016/j.ssc.2010.02.008 · Cited by 43 · see citing works
The CaCO3–Fe interaction: Kinetic approach for carbonate subduction to the deep Earth’s mantle
Martirosyan, N. S., Yoshino, T., Shatskiy, A. F., Chanyshev, A., & Litasov, K. D. (2016) · Physics of The Earth and Planetary Interiors · doi:10.1016/j.pepi.2016.08.008 · Cited by 42 · see citing works
Fu, S., Yang, J., & Lin, J. (2017) · Physical Review Letters · doi:10.1103/physrevlett.118.036402 · Cited by 41 · see citing works
Shantanu Keshav, A., & Guðfinnsson, G. H. (2010) · Journal of Geophysical Research Atmospheres · doi:10.1029/2009jb006457 · Cited by 41 · see citing works
Koch‐Müller, M., Jahn, S., Birkholz, N., Ritter, E., & Schade, U. (2016) · Physics and Chemistry of Minerals · doi:10.1007/s00269-016-0815-8 · Cited by 40 · see citing works
Yoshino, T., Gruber, B., & Reinier, C. (2018) · Physics of The Earth and Planetary Interiors · doi:10.1016/j.pepi.2018.05.003 · Cited by 40 · see citing works
Recycled calcium carbonate is an efficient oxidation agent under deep upper mantle conditions
Tao, R., & Fei, Y. (2021) · Communications Earth & Environment · doi:10.1038/s43247-021-00116-8 · Cited by 40 · see citing works
Sablikov, V. A., & Tkach, Y. Y. (2007) · Physical Review B · doi:10.1103/physrevb.76.245321 · Cited by 40 · see citing works
High-pressure phase transformations in carbonates
Arapan, S., & Ahuja, R. (2010) · Physical Review B · doi:10.1103/physrevb.82.184115 · Cited by 39 · see citing works
High-pressure compressibility and vibrational properties of (Ca,Mn)CO <sub>3</sub>
Liu, J., Caracas, R., Fan, D., Bobocioiu, E., Zhang, D., & Mao, W. L. (2016) · American Mineralogist · doi:10.2138/am-2016-5742 · Cited by 38 · see citing works
New high-pressure phases in BaCO3
Ono, S. (2007) · Physics and Chemistry of Minerals · doi:10.1007/s00269-006-0140-8 · Cited by 38 · see citing works
Self-citationThe mineralogy and the origin of deep geospheres: A review
Pushcharovsky, D. Y., & Pushcharovsky, Y. M. (2012) · Earth-Science Reviews · doi:10.1016/j.earscirev.2012.03.004 · Cited by 38 · see citing works
Irifune, T., Isshiki, M., & Sakamoto, S. (2005) · Earth and Planetary Science Letters · doi:10.1016/j.epsl.2005.05.043 · Cited by 38 · see citing works
Self-citationMantle‐wide sequestration of carbon in silicates and the structure of magnesite II
Panero, W. R., & Kabbes, J. E. (2008) · Geophysical Research Letters · doi:10.1029/2008gl034442 · Cited by 37 · see citing works
(2007) · doi:10.1103/physrevlett.98.268501 · Cited by 37 · see citing works
Nanocrystalline Cubic Silicon Carbide: A Route to Superhardness
Sun, R., Wei, X., Hu, W., Ying, P., Wu, Y., Wang, L., Chen, S., Zhang, X., Ma, M., Yu, D., et al. (2022) · Small · doi:10.1002/smll.202201212 · Cited by 36 · see citing works
Redox evolution of western Tianshan subduction zone and its effect on deep carbon cycle
Tao, R., Zhang, L., & Zhang, L. (2019) · Geoscience Frontiers · doi:10.1016/j.gsf.2019.09.007 · Cited by 36 · see citing works
Raman spectroscopic study of PbCO3 at high pressures and temperatures
Minch, R., Dubrovinsky, L., Kurnosov, A., Ehm, L., Knorr, K., & Depmeier, W. (2009) · Physics and Chemistry of Minerals · doi:10.1007/s00269-009-0308-0 · Cited by 36 · see citing works
The fate of carbonate in oceanic crust subducted into earth's lower mantle
Drewitt, J. W. E., Walter, M. J., Zhang, H. L., McMahon, S. C., Edwards, D., Heinen, B. J., Lord, O. T., Anzellini, S., & Kleppe, A. (2019) · Earth and Planetary Science Letters · doi:10.1016/j.epsl.2019.01.041 · Cited by 35 · see citing works
Stagno, V., Kono, Y., Stopponi, V., Masotta, M., Scarlato, P., & Manning, C. E. (2020) · Geophysical monograph · doi:10.1002/9781119508229 · Cited by 35 · see citing works
Proterozoic Alkaline rocks and Carbonatites of Peninsular India: A review
Paul, D., Chandra, J., & Halder, M. (2020) · Episodes · doi:10.18814/epiiugs/2020/020015 · Cited by 34 · see citing works
- Authors
- Isshiki, M., Irifune, T., Hirose, K., Ono, S., Ohishi, Y., Watanuki, T., Nishibori, E., Takata, M., & Sakata, M.
- Affiliations
- Ehime University (JP)
- Tokyo Institute of Technology (JP)
- Japan Agency for Marine-Earth Science and Technology (JP)
- Japan Synchrotron Radiation Research Institute (JP)
- SPring-8 (JP)
- Nagoya University (JP)
- Corresponding author
- Isshiki, Maiko
- Irifune, Tetsuo
- Venue
- Nature
- Published
- 2004-01
- Volume
- 427
- Issue
- 6969
- Pages
- 60-63
- ISSN
- 0028-0836 (ISSN-L)
- 1476-4687
- OpenAlex
- W1984885274
- Cited by
- 279
- References
- 26
- Citations by year
- 2026: 14 · 2025: 11 · 2024: 11 · 2023: 3 · 2022: 15 · 2021: 16 · 2020: 24 · 2019: 15 · 2018: 12 · 2017: 23 · 2016: 13 · 2015: 16 · 2014: 12 · 2013: 13 · 2012: 8
- FWCI
- 6.85
- Type
- journal article
- Language
- en
- Open access
- closed
- Licence
- www.springer.com/tdm (tdm)
- Locations
- Nature (publishedVersion)
- PubMed (publishedVersion)
- RePEc: Research Papers in Economics (submittedVersion)
- Topics
- Physical Sciences › Earth and Planetary Sciences › Geophysics › High-pressure geophysics and materials
- Physical Sciences › Earth and Planetary Sciences › Geophysics › Geological and Geochemical Analysis
- Physical Sciences › Materials Science › Materials Chemistry › Boron and Carbon Nanomaterials Research
- Keywords
- magnesite, high-pressure phase transformation, lower mantle, carbonate stability, subducted carbonates, carbon cycle, core-mantle boundary, in situ X-ray diffraction
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