Cited by 2,000CO2 Reduction Techniques and CatalystsElectrocatalysts for Energy ConversionCatalysts for Methane Reforming

The DOI matches its Crossref record; 42 of the 42 references it cites were found in a registry or an index.

Enhanced electrocatalytic CO2 reduction via field-induced reagent concentration

Liu, Min, Pang, Yuanjie, Zhang, Bo, De Luna, Phil, Voznyy, Oleksandr, Xu, Jixian, Zheng, Xueli, Dinh, Cao Thang, Fan, Fengjia, Cao, Changhong, de Arquer, F. Pelayo García, Safaei, Tina Saberi, Mepham, Adam, Klinkova, Anna, Kumacheva, Eugenia, Filleter, Tobin, Sinton, David, Kelley, Shana O., Sargent, Edward H.·2016·Nature

DOI 10.1038/nature19060

Open this paper in CoChat — free account

Abstract

Electrochemical reduction of carbon dioxide (CO 2) to carbon monoxide (CO) is the first step in the synthesis of more complex carbon-based fuels and feedstocks using renewable electricity. Unfortunately, the reaction suffers from slow kinetics owing to the low local concentration of CO 2 surrounding typical CO 2 reduction reaction catalysts. Alkali metal cations are known to overcome this limitation through non-covalent interactions with adsorbed reagent species, but the effect is restricted by the solubility of relevant salts. Large applied electrode potentials can also enhance CO 2 adsorption, but this comes at the cost of increased hydrogen (H 2) evolution. Here we report that nanostructured electrodes produce, at low applied overpotentials, local high electric fields that concentrate electrolyte cations, which in turn leads to a high local concentration of CO 2 close to the active CO 2 reduction reaction surface. Simulations reveal tenfold higher electric fields associated with metallic nanometre-sized tips compared to quasi-planar electrode regions, and measurements using gold nanoneedles confirm a field-induced reagent concentration that enables the CO 2 reduction reaction to proceed with a geometric current density for CO of 22 milliamperes per square centimetre at -0.35 volts (overpotential of 0.24 volts). This performance surpasses by an order of magnitude the performance of the best gold nanorods, nanoparticles and oxide-derived noble metal catalysts. Similarly designed palladium nanoneedle electrocatalysts produce formate with a Faradaic efficiency of more than 90 per cent and an unprecedented geometric current density for formate of 10 milliamperes per square centimetre at -0.2 volts, demonstrating the wider applicability of the field-induced reagent concentration concept.

Integrity signals

Registry

Crossref · 10.1038/nature19060

Cites

42 of 42 references verified0 citation errors · 0 not checkable

Statistics

Recomputing p-values needs the paper’s full text.

Claims the paper makes

This paper’s full text isn’t openly available, so its claims and self-check weren’t run. The registry and citation checks still apply.

Claims other papers make about this one

Each is checked against this paper’s own text: does it say what the citing paper says it does?

Generalized Gradient Approximation Made Simple
Perdew, J. P., Burke, K., & Ernzerhof, M. (1996) · Physical Review Letters · doi:10.1103/physrevlett.77.3865 · Cited by 215,824
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set
Kresse, G., & Furthmüller, J. (1996) · Physical Review B · doi:10.1103/physrevb.54.11169 · Cited by 123,652
Projector augmented-wave method
Blöchl, P. E. (1994) · Physical Review B · doi:10.1103/physrevb.50.17953 · Cited by 92,732
From ultrasoft pseudopotentials to the projector augmented-wave method
Kresse, G., & Joubert, D. (1999) · Physical Review B · doi:10.1103/physrevb.59.1758 · Cited by 85,307
Special points for Brillouin-zone integrations
Monkhorst, H. J., & Pack, J. D. (1976) · Physical Review B · doi:10.1103/physrevb.13.5188 · Cited by 71,721
VMD: visual molecular dynamics
Humphrey, W., Dalke, A., & Schulten, K. (1996) · Journal of Molecular Graphics · doi:10.1016/0263-7855(96)00018-5 · Cited by 66,952
A grid-based Bader analysis algorithm without lattice bias
Tang, W., Sanville, E., & Henkelman, G. (2009) · Journal of Physics Condensed Matter · doi:10.1088/0953-8984/21/8/084204 · Cited by 7,595
Modern Aspects of Electrochemistry
Bockris, J. O., White, R. E., & Conway, B. E. (2002) · Kluwer Academic Publishers eBooks · doi:10.1007/b114168 · Cited by 5,954
How copper catalyzes the electroreduction of carbon dioxide into hydrocarbon fuels
Peterson, A. A., Abild-Pedersen, F., Studt, F., Rossmeisl, J., & Nørskov, J. K. (2010) · Energy & Environmental Science · doi:10.1039/c0ee00071j · Cited by 3,784
Recent advances in catalytic hydrogenation of carbon dioxide
Wang, W., Wang, S., Ma, X., & Gong, J. (2011) · Chemical Society Reviews · doi:10.1039/c1cs15008a · Cited by 3,316

Flagged first, then by citations

Show all 42 references

Research works printed but not linked: 2

Jackson, J. D. Classical Electrodynamics Vol. 3, 75–79 (Wiley, 1962)
Serway, R. A. & Jewett, J. W. Principles of Physics Vol. 1, 602 (Saunders College Pub., 1998)

Sorted by citations

Items 801–900 of 1,001

Regulating the reduction reaction pathways via manipulating the solvation shell and donor number of the solvent in Li-CO 2 chemistry
Zhang, W., Zhang, F., Liu, S., Pang, W. K., Lin, Z., Guo, Z., & Chai, L. (2023) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.2219692120 · Cited by 46
Gas penetrating hollow fiber Bi with contractive bond enables industry-level CO2 electroreduction
Chen, A., Dong, X., Mao, J., Chen, W., Zhu, C., Li, S., Wu, G., Wei, Y., Liu, X., Li, G., et al. (2023) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2023.122768 · Cited by 45
Direct Machine Learning Predictions of C3 Pathways
Sun, M., & Huang, B. (2024) · Advanced Energy Materials · doi:10.1002/aenm.202400152 · Cited by 47
Free-Standing Single-Atom Catalyst-Based Electrodes for CO2 Reduction
Hossain, M. N., Zhang, L., Neagu, R., & Rassachack, E. (2024) · Electrochemical Energy Reviews · doi:10.1007/s41918-023-00193-7 · Cited by 53
Hierarchically ordered meso-/macroporous MOF-based materials for catalysis and energy applications
Hu, A., Xie, Q., Chen, L., & Li, Y. (2024) · EnergyChem · doi:10.1016/j.enchem.2024.100137 · Cited by 47
Strong Electric Fields on Water Microdroplets Enable Near-Unity Selectivity in H 2 O 2 Photosynthesis
Li, K., You, W., Zhu, Y., Wang, W., Wang, L., Liu, Y., Ge, Q., Wang, T., Wang, R., Ruan, X., et al. (2025) · Journal of the American Chemical Society · doi:10.1021/jacs.5c06077 · Cited by 46
Morphology‐Controlled Bi2O3 Nanoparticles as Catalysts for Selective Electrochemical Reduction of CO2 to Formate
Miao, C., & Yuan, G. (2018) · ChemElectroChem · doi:10.1002/celc.201801036 · Cited by 46
Operando Raman probing of electrocatalytic biomass oxidation on gold nanoparticle surfaces
Heidary, N., & Kornienko, N. (2019) · Chemical Communications · doi:10.1039/c9cc06646b · Cited by 46
Electrolyzer and Catalysts Design from Carbon Dioxide to Carbon Monoxide Electrochemical Reduction
He, J., Li, Y., Huang, A., Liu, Q., & Li, C. (2021) · Electrochemical Energy Reviews · doi:10.1007/s41918-021-00100-y · Cited by 48
Effect of additives in aqueous electrolytes on CO2 electroreduction
Golru, S. S., & Biddinger, E. J. (2021) · Chemical Engineering Journal · doi:10.1016/j.cej.2021.131303 · Cited by 48
Metal chalcogenide-associated catalysts enabling CO 2 electroreduction to produce low-carbon fuels for energy storage and emission reduction: catalyst structure, morphology, performance, and mechanism
Shao, X., Zhang, X., Liu, Y., Qiao, J., Zhou, X., Xu, N., Malcombe, J. L., Jin, Y., & Zhang, J. (2020) · Journal of Materials Chemistry A · doi:10.1039/d0ta09232k · Cited by 46
Gold Adparticles on Silver Combine Low Overpotential and High Selectivity in Electrochemical CO2 Conversion
Ozden, A., Liu, Y., Dinh, C., Li, J., Ou, P., de Arquer, F. P. G., Sargent, E. H., & Sinton, D. A. (2021) · ACS Applied Energy Materials · doi:10.1021/acsaem.1c01577 · Cited by 47
Self-citation
Comparing interfacial cation hydration at catalytic active sites and spectator sites on gold electrodes: understanding structure sensitive CO 2 reduction kinetics
Rebstock, J. A., Zhu, Q., & Baker, L. R. (2022) · Chemical Science · doi:10.1039/d2sc01878k · Cited by 45
Isolated Cu-Sn diatomic sites for enhanced electroreduction of CO2 to CO
Liu, W., Li, H., Ou, P., Mao, J., Han, L., Song, J. J., Luo, J., & Xin, H. L. (2023) · Nano Research · doi:10.1007/s12274-023-5513-5 · Cited by 48
Tip and heterogeneous effects co-contribute to a boosted performance and stability in zinc air battery
Long, X., Xiong, T., Bao, H., Pan, S., Liu, Q., Luo, F., & Yang, Z. (2024) · Journal of Colloid and Interface Science · doi:10.1016/j.jcis.2024.02.120 · Cited by 45
Ethylene electrosynthesis from low-concentrated acetylene via concave-surface enriched reactant and improved mass transfer
Chen, F., Li, L., Cheng, C., Yu, Y., Zhao, B., & Zhang, B. (2024) · Nature Communications · doi:10.1038/s41467-024-50335-8 · Cited by 45
Self-citation
Iron group elements (Fe, Co, Ni) in Electrocatalytic applications: Evaluation, characterization and prospects
Wu, J., Liu, N., Li, F., Jia, B., & Zheng, J. (2024) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2024.216343 · Cited by 45
Enhanced CO2 reduction activity of polyethylene glycol-modified Au nanoparticles prepared via liquid medium sputtering
Chung, M. W., Cha, I. Y., Ha, M. G., Na, Y., Hwang, J., Ham, H. C., Kim, H., Henkensmeier, D., Yoo, S. J., Kim, J. Y., et al. (2018) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2018.06.022 · Cited by 45
Impacts on carbon dioxide electroreduction of cadmium sulfides via continuous surface sulfur vacancy engineering
Cheng, L., Li, Y., Chen, A., Zhu, Y., & Li, C. (2019) · Chemical Communications · doi:10.1039/c9cc08330h · Cited by 45
Ni and nitrogen-codoped ultrathin carbon nanosheets with strong bonding sites for efficient CO2 electrochemical reduction
Ma, Z., Zhang, X., Wu, D., Han, X., Zhang, L., Wang, H., Xu, F., Gao, Z., & Jiang, K. (2020) · Journal of Colloid and Interface Science · doi:10.1016/j.jcis.2020.02.050 · Cited by 45
Semi-sacrificial template synthesis of single-atom Ni sites supported on hollow carbon nanospheres for efficient and stable electrochemical CO 2 reduction
Yuan, C., Zhan, L., Liu, S., Chen, F., Lin, H., Wu, X., & Chen, J. (2020) · Inorganic Chemistry Frontiers · doi:10.1039/c9qi01688k · Cited by 45
Evidence of Local Corrosion of Bimetallic Cu–Sn Catalysts and Its Effects on the Selectivity of Electrochemical CO2 Reduction
Dong, W. J., Lim, J. W., Hong, D. M., Park, J.-Y., Cho, W. S., Baek, S., Yoo, C. J., Kim, W., & Lee, J. (2020) · ACS Applied Energy Materials · doi:10.1021/acsaem.0c01617 · Cited by 45
Operando evidence of Cu + stabilization via a single-atom modifier for CO 2 electroreduction
Zhang, W., He, P., Wang, C., Ding, T., Chen, T., Liu, X., Cao, L., Huang, T., Shen, X., Usoltsev, O., et al. (2020) · Journal of Materials Chemistry A · doi:10.1039/d0ta08369k · Cited by 45
Wet-chemical synthesis and applications of amorphous metal-containing nanomaterials
Liang, J., Ge, Y., He, Z., Yun, Q., Liu, G., Lu, S., Zhai, L., Huang, B., & Zhang, H. (2021) · Nano Research · doi:10.1007/s12274-021-4007-6 · Cited by 46
Total conversion of centimeter-scale nickel foam into single atom electrocatalysts with highly selective CO2 electrocatalytic reduction in neutral electrolyte
Fan, Q., Gao, P., Ren, S., Qu, Y., Kong, C., Yang, J., & Wu, Y. S. (2022) · Nano Research · doi:10.1007/s12274-022-4472-6 · Cited by 44
Tip-Intensified Interfacial Microenvironment Reconstruction Promotes an Electrocatalytic Chlorine Evolution Reaction
Chen, Y., Zhang, G., Liu, H., Wang, Y., Chen, Z., Ji, Q., Lan, H., Liu, R., & Qu, J. (2022) · ACS Catalysis · doi:10.1021/acscatal.2c03401 · Cited by 44
Ultrafine Fe 2 C Iron Carbide Nanoclusters Trapped in Topological Carbon Defects for Efficient Electroreduction of Carbon Dioxide
Su, J., Pan, D., Yan, D., Zhang, Y., Tang, Y., Sun, J. Q., Zhang, L., Tian, Z., & Chen, L. (2023) · Advanced Energy Materials · doi:10.1002/aenm.202204391 · Cited by 45
Enriching Metal–Oxygen Species and Phosphate Modulating of Active Sites for Robust Electrocatalytical CO 2 Reduction
Zhang, B., Chang, Y., Zhai, P., Wang, C., Gao, J., Sun, L., & Hou, J. (2023) · Advanced Materials · doi:10.1002/adma.202304379 · Cited by 44
Self-citation
Enhanced CO 2 Reactive Capture and Conversion Using Aminothiolate Ligand–Metal Interface
Wan, M., Yang, Z., Morgan, H., Shi, J., Shi, F., Liu, M., Wong, H., Gu, Z., & Che, F. (2023) · Journal of the American Chemical Society · doi:10.1021/jacs.3c06888 · Cited by 44
Self-citation
Alkynes Electrooxidation to α,α-Dichloroketones in Seawater with Natural Chlorine Participation via Competitive Reaction Inhibition and Tip-Enhanced Reagent Concentration
Yao, J., Yang, R., Liu, C., Zhao, B., Zhang, B., & Wu, Y. (2023) · ACS Central Science · doi:10.1021/acscentsci.3c01277 · Cited by 45
Self-citation
Recent advances in amino-functionalized metal–organic frameworks for sustainable photocatalytic carbon dioxide reduction
Liu, Y., Guo, H., Sun, Z., Li, T., Qian, J., Wang, L. F., Zhang, J., & Zhang, Z. (2024) · Separation and Purification Technology · doi:10.1016/j.seppur.2024.131023 · Cited by 44
Steric Hindrance in Sulfur Vacancy of Monolayer MoS2 Boosts Electrochemical Reduction of Carbon Monoxide to Methane
Chen, Z., Gao, W., Zheng, W., & Jiang, Q. (2018) · ChemSusChem · doi:10.1002/cssc.201702262 · Cited by 44
Nickel phthalocyanine integrated graphene architecture as bifunctional electrocatalyst for CO2 and O2 reductions
Sonkar, P. K., Ganesan, V., Gupta, R., Yadav, D. K., & Yadav, M. (2018) · Journal of Electroanalytical Chemistry · doi:10.1016/j.jelechem.2018.08.020 · Cited by 44
Two‐Dimensional Electrocatalysts for Efficient Reduction of Carbon Dioxide
Zhang, Y., Li, L., Guo, S., Zhang, X., Li, F., Bond, A. M., & Zhang, J. (2019) · ChemSusChem · doi:10.1002/cssc.201901794 · Cited by 44
On factors limiting the performance of photoelectrochemical CO2 reduction
Liu, Y., & Guo, L. (2020) · The Journal of Chemical Physics · doi:10.1063/1.5141390 · Cited by 44
Molecular Evidence for Metallic Cobalt Boosting CO2 Electroreduction on Pyridinic Nitrogen
He, C., Zhang, Y., Zhang, Y., Zhao, L., Yuan, L., Zhang, J., Ma, J., & Hu, J. (2020) · Angewandte Chemie · doi:10.1002/ange.201916520 · Cited by 44
Recent Advances in the Catalyst Design and Mass Transport Control for the Electrochemical Reduction of Carbon Dioxide to Formate
Alfath, M., & Lee, C. W. (2020) · Catalysts · doi:10.3390/catal10080859 · Cited by 46
Reordering d Orbital Energies of Single‐Site Catalysts for CO 2 Electroreduction
Han, J., An, P., Liu, S., Zhang, X., Wang, D., Yuan, Y. D., Guo, J. M., Qiu, X., Hou, K., Shi, L., et al. (2019) · Angewandte Chemie · doi:10.1002/ange.201907399 · Cited by 44
Single atomic Fe–N 4 active sites and neighboring graphitic nitrogen for efficient and stable electrochemical CO 2 reduction
Menisa, L. T., Cheng, P., Qiu, X., Zheng, Y., Huang, X., Gao, Y. P., & Tang, Z. (2022) · Nanoscale Horizons · doi:10.1039/d2nh00143h · Cited by 43
A Cosolvent Electrolyte Boosting Electrochemical Alkynol Semihydrogenation.
Zhao, Y., Wang, J., Zha, X., Sheng, X., Dong, L., Wu, X.-P., Liu, Z., Jiang, H.-L., & Li, C.-Z. (2025) · Journal of the American Chemical Society · doi:10.1021/jacs.4c14773 · Cited by 35
Electrochemical and FTIR spectroscopic study of CO 2 reduction at a nanostructured Cu/reduced graphene oxide thin film
Hossain, M. N., Wen, J., Konda, S. K., Maduraiveeran, G., & Chen, A. (2017) · Electrochemistry Communications · doi:10.1016/j.elecom.2017.07.006 · Cited by 43
Simple Cadmium Sulfide Compound with Stable 95 % Selectivity for Carbon Dioxide Electroreduction in Aqueous Medium
Li, Y., Cheng, L., Liu, P. F., Zhang, L., Zu, M. Y., Wang, C., Jin, Y. H., Cao, X., Yang, H. G., & Li, C. (2018) · ChemSusChem · doi:10.1002/cssc.201800372 · Cited by 43
Polymers with intrinsic microporosity (PIMs) for targeted CO2 reduction to ethylene
Perry, S. C., Gateman, S. M., Malpass‐Evans, R., McKeown, N. B., Wegener, M., Nazarovs, P., Mauzeroll, J., Wang, L., & de León, C. P. (2020) · Chemosphere · doi:10.1016/j.chemosphere.2020.125993 · Cited by 44
Photoanode driven photoelectrocatalytic system for CO2 reduction to formic acid by using CoOx cathode
Pan, D., Ye, X., Cao, Y., Zhu, S., Chen, X., Chen, M., Zhang, D., & Li, G. (2020) · Applied Surface Science · doi:10.1016/j.apsusc.2020.145497 · Cited by 43
Direct Observation of Carbon Dioxide Electroreduction on Gold: Site Blocking by the Stern Layer Controls CO2 Adsorption Kinetics
Wallentine, S. K., Bandaranayake, S., Biswas, S., & Baker, L. R. (2020) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.0c02628 · Cited by 43
Curvature‐induced Zn 3d Electron Return on Zn−N4 Single‐atom Carbon Nanofibers for Boosting Electroreduction of CO2
Fang, M., Wang, X., Li, X., Zhu, Y., Xiao, G., Feng, J., Jiang, X., Lv, K., Zhu, Y., & Lin, W. (2020) · ChemCatChem · doi:10.1002/cctc.202001667 · Cited by 43
Capture and electroreduction of CO 2 using highly efficient bimetallic Pd–Ag aerogels paired with carbon nanotubes
Abdinejad, M., Ferrag, C., Hossain, M. N., Noroozifar, M., Kerman, K., & Kraatz, H. (2021) · Journal of Materials Chemistry A · doi:10.1039/d1ta01834e · Cited by 45
The Role of Surface Curvature in Electrocatalysts
Wang, Y., Bao, Z., Shi, M., Liang, Z., Cao, R., & Zheng, H. (2021) · Chemistry - A European Journal · doi:10.1002/chem.202102915 · Cited by 42
Electrocatalytic Disproportionation of Nitric Oxide Toward Efficient Nitrogen Fixation
Wu, A., Lv, J., Xuan, X., Zhang, J., Cao, A., Wang, M., Wu, X., Liu, Q., Zhong, Y., Sun, W. B., et al. (2023) · Advanced Energy Materials · doi:10.1002/aenm.202204231 · Cited by 42
Metal‐Organic Frameworks‐Based Copper Catalysts for CO 2 Electroreduction Toward Multicarbon Products
Chen, Q. K., Li, X., Wang, T., Xu, Z. C., Chen, K., & Pan, F. (2025) · Exploration · doi:10.1002/exp.70011 · Cited by 42
Tuning the electrocatalytic properties of a Cu electrode with organic additives containing amine group for CO 2 reduction
Qiu, Y., Zhong, H., Xu, W., Zhang, T., Li, X., & Zhang, H. (2019) · Journal of Materials Chemistry A · doi:10.1039/c9ta00039a · Cited by 42
Active Sulfur Sites in Semimetallic Titanium Disulfide Enable CO 2 Electroreduction
Aljabour, A., Coskun, H., Zheng, X. R., Kibria, M. G., Strobel, M., Hild, S., Kehrer, M., Stifter, D., Sargent, E. H., & Stadler, P. (2019) · ACS Catalysis · doi:10.1021/acscatal.9b02872 · Cited by 42
Self-citation
Syngas Evolution from CO2 Electroreduction by Porous Au Nanostructures
Mascaretti, L., Niorettini, A., Bricchi, B. R., Ghidelli, M., Naldoni, A., Caramori, S., Bassi, A. L., & Berardi, S. (2020) · ACS Applied Energy Materials · doi:10.1021/acsaem.0c00301 · Cited by 43
Defect Engineering of Molybdenum-Based Materials for Electrocatalysis
Gao, X., Zhou, G., Wang, H., Yin, J., Zhang, L., Xiao, F., Siddharth, K., Zhu, S., & Shao, M. (2020) · Catalysts · doi:10.3390/catal10111301 · Cited by 42
Tunable Product Selectivity in Electrochemical CO 2 Reduction on Well-Mixed Ni–Cu Alloys
Song, H., Tan, Y. C., Kim, B., Ringe, S., & Oh, J. (2021) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.1c19224 · Cited by 43
NiSn Atomic Pair on an Integrated Electrode for Synergistic Electrocatalytic CO2 Reduction
Xie, W., Li, H., Cui, G., Li, J., Song, Y., Li, S., Zhang, X., Lee, J. Y., Shao, M., & Wei, M. (2020) · Angewandte Chemie · doi:10.1002/ange.202014655 · Cited by 43
Tuning Gold Nanoparticles with Chelating Ligands for Highly Efficient Electrocatalytic CO2 Reduction
Cao, Z. M., Zacate, S. B., Sun, X., Liu, J., Hale, E. M., Carson, W., Tyndall, S. B., Xu, J., Liu, X., Liu, X., et al. (2018) · Angewandte Chemie · doi:10.1002/ange.201805696 · Cited by 42
Self-citation
CO2 electroreduction on single atom catalysts: Is water just a solvent?
Misra, D., Liberto, G. D., & Pacchioni, G. (2023) · Journal of Catalysis · doi:10.1016/j.jcat.2023.04.002 · Cited by 43
Vapor‐Fed Electrolyzers for Carbon Dioxide Reduction Using Tandem Electrocatalysts: Cuprous Oxide Coupled with Nickel‐Coordinated Nitrogen‐Doped Carbon
Lin, Y., Lee, D. U., Tan, S., Koshy, D. M., Lin, T. Y., Wang, L., Corral, D., Acosta, J. E. A., Zeledon, J. A. Z., Beck, V. A., et al. (2022) · Advanced Functional Materials · doi:10.1002/adfm.202113252 · Cited by 41
A review on electrochemical conversion of CO2 to CO: Ag-based electrocatalyst and cell configuration for industrial application
Iqbal, M. Z., Imteyaz, S., Ghanty, C., & Sarkar, S. (2022) · Journal of Industrial and Engineering Chemistry · doi:10.1016/j.jiec.2022.05.041 · Cited by 42
Microenvironment Engineering for the Electrocatalytic CO2 Reduction Reaction
Lv, J., Yin, R., Zhou, L., Li, J., Kikas, R., Xu, T., Wang, Z., Jin, H., Wang, X., & Wang, S. (2022) · Angewandte Chemie · doi:10.1002/ange.202207252 · Cited by 41
Molecular Assembled Electrocatalyst for Highly Selective CO2 Fixation to C2+ Products
Wang, P., Li, T., Wu, Q., Du, R., Zhang, Q., Huang, W., Chen, C., Fan, Y., Chen, H., Jia, Y., et al. (2022) · ACS Nano · doi:10.1021/acsnano.2c07138 · Cited by 41
Electric Double Layer Structure in Electrocatalytic Carbon Dioxide Reduction
Luo, T., Liu, K., Fu, J., Chen, S., Li, H., Pan, H., & Liu, M. (2022) · Advanced Energy and Sustainability Research · doi:10.1002/aesr.202200148 · Cited by 44
Self-citation
Photoelectrochemical Urea Synthesis from Nitrate and Carbon Dioxide on GaN Nanowires
Dong, W. J., Menzel, J. P., Ye, Z., Navid, I. A., Zhou, P. C., Yang, K., Batista, V. S., & Mi, Z. (2024) · ACS Catalysis · doi:10.1021/acscatal.3c04264 · Cited by 41
Temperature-dependent pathways in carbon dioxide electroreduction
Liu, S., Yin, Y., Yang, J., Zhao, W., Zhou, M. R., Qin, H., Jiao, J., Wang, Y., Wang, H., Tong, X., et al. (2025) · 中国科学通报：英文版 · doi:10.1016/j.scib.2024.12.052 · Cited by 42
Understanding the Effects of Au Morphology on CO 2 Electrocatalysis
Back, S., Yeom, M. S., & Jung, Y. (2018) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.7b10439 · Cited by 42
Fabrication and Applications of 3D Nanoarchitectures for Advanced Electrocatalysts and Sensors
Kim, Y. J., Lee, G. R., Cho, E. N., & Jung, Y. S. (2020) · Advanced Materials · doi:10.1002/adma.201907500 · Cited by 41
Electric-field-driven electrochemical CO2 reduction of sharpened Sn/Cu catalysts
Dong, W. J., Lim, J. W., Park, J.-Y., Yoo, C. J., Baek, S., Cho, W. S., Kim, W., & Lee, J. (2021) · Applied Surface Science · doi:10.1016/j.apsusc.2021.150460 · Cited by 41
CO2 reduction mechanism on the Nb2CO2 MXene surface: Effect of nonmetal and metal modification
Cheng, Y., Xu, X., Li, Y., Zhang, Y., & Song, Y. L. (2021) · Computational Materials Science · doi:10.1016/j.commatsci.2021.110971 · Cited by 41
Bimetallic MOF derived nickel nanoclusters supported by nitrogen-doped carbon for efficient electrocatalytic CO2 reduction
Wang, H., Wu, X., Liu, G., Wu, S., & Xu, R. Q. (2022) · Nano Research · doi:10.1007/s12274-022-4199-4 · Cited by 42
Facet engineering in Au nanoparticles buried in p-Si photocathodes for enhanced photoelectrochemical CO2 reduction
Hu, J., Fan, N., Chen, C., Wu, Y., Wei, Z., Xu, B., Peng, Y., Shen, M., & Fan, R. (2023) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2023.122438 · Cited by 41
Interfacial microenvironments for carbon dioxide electro-upgrading to multicarbon products
Kuang, M., & Zheng, G. (2023) · Chem Catalysis · doi:10.1016/j.checat.2023.100565 · Cited by 41
Highly Efficient CO 2 Reduction at Steady 2 A cm −2 by Surface Reconstruction of Silver Penetration Electrode
Li, S., Dong, X., Mao, J., Chen, W., Chen, A., Wu, G., Zhu, C., Li, G., Wei, Y., Liu, X., et al. (2023) · Small · doi:10.1002/smll.202301338 · Cited by 41
Highly efficient electrocatalytic CO2 reduction over pyrolysis–free conjugated metallophthalocyanine networks in full pH range
Wu, Q., Si, D., Liang, J., Huang, Y., & Cao, R. (2023) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2023.122803 · Cited by 40
Wettability control in electrocatalytic CO2 reduction: Effects, modulations and mechanisms
Lu, R., Zhang, X., Shi, H., Zhao, Z., Li, M., & Zhang, X. (2023) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2023.123293 · Cited by 40
Revealing the CO2 Conversion at Electrode/Electrolyte Interfaces in Li–CO2 Batteries via Nanoscale Visualization Methods
Shen, Z., Lang, S., Liu, R., Zhou, C., Zhang, Y., Liu, B., & Wen, R. (2023) · Angewandte Chemie International Edition · doi:10.1002/anie.202316781 · Cited by 40
Sequentially Regulating Potential‐Determining Step for Lowering CO2 Electroreduction Overpotential over Te‐Doped Bi Nanotips
Li, Y., Li, J., Ai, W., Chen, J., Lu, T., Liao, X., Wang, W., Huang, R., Chen, Z., Wu, J., et al. (2024) · Angewandte Chemie International Edition · doi:10.1002/anie.202407772 · Cited by 40
An Anti-Scaling Strategy for Electrochemical Wastewater Treatment: Leveraging Tip-Enhanced Electric Fields
Zhu, Y., Duan, W., Huang, Z., Li, T., Wu, W., Dang, Z., & Feng, C. (2024) · Environmental Science & Technology · doi:10.1021/acs.est.4c03572 · Cited by 40
Metal-support interaction and tip-enhanced electric field effect co-enhancing oxygen species adsorption/enrichment for efficient electrooxidation of plastic waste derived alcohol into glycolic acid
Li, W., Bao, Q., Ma, F., Xie, W., Song, J., Xu, X., Liu, Z., Wang, Z., Wang, P., Cheng, H., et al. (2025) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2025.125375 · Cited by 40
From low to high-index facets of noble metal nanocrystals: a way forward to enhance the performance of electrochemical CO 2 reduction
Woldu, A. R. (2020) · Nanoscale · doi:10.1039/d0nr01412e · Cited by 41
Discrete Helmholtz model: a single layer of correlated counter-ions. Metal oxides and silica interfaces, ion-exchange and biological membranes
Gschwend, G. C., & Girault, H. H. (2020) · Chemical Science · doi:10.1039/d0sc03748f · Cited by 40
Atomic-level-designed copper atoms on hierarchically porous gold architectures for high-efficiency electrochemical CO2 reduction
Zhao, Y., Liu, X., Chen, D., Liu, Z., Yang, Q., Lin, X., Peng, M., Liu, P., & Tan, Y. (2021) · Science China Materials · doi:10.1007/s40843-020-1583-4 · Cited by 40
Accelerating photoelectric CO2 conversion with a photothermal wavelength-dependent plasmonic local field
Xu, C., Zhang, X., Zhu, M., Zhang, L., Sui, P., Feng, R., Zhang, Y., & Luo, J. (2021) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2021.120533 · Cited by 40
Low‐Coordinated Edge Sites on Ultrathin Palladium Nanosheets Boost Carbon Dioxide Electroreduction Performance
Zhu, W., Zhang, L., Yang, P., Hu, C., Luo, Z., Chang, X., Zhao, Z., & Gong, J. (2018) · Angewandte Chemie · doi:10.1002/ange.201806432 · Cited by 40
Axial coordination modification of M–N 4 single-atom catalysts to regulate the electrocatalytic CO 2 reduction reaction
Ma, M., & Tang, Q. H. (2022) · Journal of Materials Chemistry C · doi:10.1039/d2tc02467e · Cited by 40
Electric fields drive bond homolysis
Zhang, B., Schaack, C., Prindle, C. R., Vo, E., Aziz, M., Steigerwald, M. L., Berkelbach, T. C., Nuckolls, C. P., & Venkataraman, L. (2023) · Chemical Science · doi:10.1039/d2sc06411a · Cited by 40
Self-citation
Uncovering the key features of gold flows and stocks in China
Liu, S., Geng, Y., Gao, Z., Li, J., & Xiao, S. (2023) · Resources Policy · doi:10.1016/j.resourpol.2023.103584 · Cited by 40
Perspective of p-block single-atom catalysts for electrocatalysis
Wang, L., Zhang, L., Zhang, L., Liu, H., & Yang, J. (2022) · Trends in Chemistry · doi:10.1016/j.trechm.2022.09.010 · Cited by 39
Recent status and advanced progress of tip effect induced by micro-nanostructure
Li, J., Pan, J., Yin, W., Cai, Y., Huang, H., He, Y., Gong, G., Yuan, Y., Fan, C., Zhang, Q., et al. (2022) · Chinese Chemical Letters · doi:10.1016/j.cclet.2022.108049 · Cited by 39
Carbon‐Hybridized Hydroxides for Energy Conversion and Storage: Interface Chemistry and Manufacturing
Xie, Y., Yu, C., Ni, L., Yu, J., Zhang, Y., & Qiu, J. (2022) · Advanced Materials · doi:10.1002/adma.202209652 · Cited by 40
Liquid Nitrogen Sources Assisting Gram‐Scale Production of Single‐Atom Catalysts for Electrochemical Carbon Dioxide Reduction
An, B., Zhou, J., Duan, L., Liu, X., Yu, G., Ren, T., Guo, X., Li, Y., Ågren, H., Wang, L., et al. (2023) · Advanced Science · doi:10.1002/advs.202205639 · Cited by 39
Sequential *CO management via controlling in situ reconstruction for efficient industrial-current-density CO 2 -to-C 2+ electroreduction
Wu, M., Huang, D., Lai, F., Yang, R., Liu, Y., Fang, J., Zhai, T., & Liu, Y. (2023) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.2302851120 · Cited by 39
Local Geometric Distortion to Stimulate Oxygen Reduction Activity of Atomically Dispersed Zn‐N x Sites for Zn–Air Batteries
Tan, Y., Zhang, Z., Chen, S., Wu, W., Yu, L., Chen, R., Guo, F., Wang, Z., & Cheng, N. (2023) · Advanced Functional Materials · doi:10.1002/adfm.202311337 · Cited by 39
Scaling-Free Cathodes: Enabling Electrochemical Extraction of High-Purity Nano-CaCO 3 and -Mg(OH) 2 in Seawater
Kang, W., Meng, S., Zhao, Y., Xu, J., Wu, S., Zhao, K., Chen, S., Niu, J., Yu, H., & Quan, X. (2024) · Environmental Science & Technology · doi:10.1021/acs.est.4c04700 · Cited by 39
Self-citation
New Perspectives on Abiotic Organic Synthesis and Processing during Hydrothermal Alteration of the Oceanic Lithosphere
Andréani, M., & Ménèz, B. (2019) · Cambridge University Press eBooks · doi:10.1017/9781108677950.015 · Cited by 39
High-capacity thermochemical CO 2 dissociation using iron-poor ferrites
Zhai, S., Rojas, J. A., Ahlborg, N. L., Lim, K., Cheng, C. H. M., Xie, C., Toney, M. F., Jung, I., Chueh, W. C., & Majumdar, A. (2020) · Energy & Environmental Science · doi:10.1039/c9ee02795e · Cited by 39
Nanostructures for Electrocatalytic CO2 Reduction
Ouyang, T., Huang, S., Wang, X., & Liu, Z. (2020) · Chemistry - A European Journal · doi:10.1002/chem.202000692 · Cited by 41
Atomistic Insight into Cation Effects on Binding Energies in Cu-Catalyzed Carbon Dioxide Reduction
Ludwig, T., Gauthier, J. A., Dickens, C. F., Brown, K. S., Ringe, S., Chan, K., & Nørskov, J. K. (2020) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.0c07004 · Cited by 40
MOF-Templated Sulfurization of Atomically Dispersed Manganese Catalysts Facilitating Electroreduction of CO 2 to CO
Tan, H., Lin, S., Wang, J., Chang, C.-J., Haw, S., Lin, K., Tsai, L. D., Chen, H., & Chen, H. M. (2021) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.1c10059 · Cited by 39
Electrochemical CO2 conversion to fuels on metal-free N-doped carbon-based materials: functionalities, mechanistic, and technoeconomic aspects
Adegoke, K. A., & Maxakato, N. W. (2022) · Materials Today Chemistry · doi:10.1016/j.mtchem.2022.100838 · Cited by 39

Authors: Liu, M., Pang, Y., Zhang, B., De Luna, P., Voznyy, O., Xu, J., Zheng, X., Dinh, C. T., Fan, F., Cao, C., de Arquer, F. P. G., Safaei, T. S., Mepham, A., Klinkova, A., Kumacheva, E., Filleter, T., Sinton, D., Kelley, S. O., & Sargent, E. H.
Affiliations: University of Toronto (CA)
East China University of Science and Technology (CN)
Tianjin University (CN)
Corresponding author: Sargent, Edward H.
ORCID: Liu, Min
Pang, Yuanjie
Zhang, Bo
Voznyy, Oleksandr
Xu, Jixian
Zheng, Xueli
Dinh, Cao Thang
Fan, Fengjia
Cao, Changhong
Klinkova, Anna
Kumacheva, Eugenia
Filleter, Tobin
Sinton, David
Kelley, Shana O.
Sargent, Edward H.
Venue: Nature
Publisher: Springer Science and Business Media LLC
Published: 2016-08-03
Volume: 537
Issue: 7620
Pages: 382-386
ISSN: 0028-0836 (ISSN-L)
1476-4687
DOI: 10.1038/nature19060
OpenAlex: W2496132953
Cited by: 2,000
References: 42
Citations by year: 2026: 150 · 2025: 195 · 2024: 265 · 2023: 238 · 2022: 218 · 2021: 233 · 2020: 226 · 2019: 201 · 2018: 164 · 2017: 104 · 2016: 6
FWCI: 43.01
Type: journal article
Language: en
Open access: closed
Licence: www.springer.com/tdm (tdm)
Locations: Nature (publishedVersion)
PubMed (publishedVersion)
RePEc: Research Papers in Economics (submittedVersion)
King Abdullah University of Science and Technology Repository (King Abdullah University of Science and Technology) (submittedVersion)
Topics: Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
Physical Sciences › Chemical Engineering › Catalysis › Catalysts for Methane Reforming
Keywords: electrochemical CO2 reduction, local electric field, CO2 adsorption, carbon monoxide production, formate production, nanostructured electrodes, alkali metal cations, CO2 reduction kinetics, hydrogen evolution suppression, electrocatalyst design, CO2 selectivity

About these checks

Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.

Statistics and arithmetic are recomputed, not judged.

Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.

What counts as a claim ›How we measure confidence ›How we check this ›

Are you an author, or do you see a problem with this page? Request a review

Enhanced electrocatalytic CO2 reduction via field-induced reagent concentration

Abstract

Overview

Integrity signals

Verification

Claims the paper makes

Claims other papers make about this one

Citations

Cites

Cited by

Related

Metadata

Record

About these checks