Cited by 2,000CO2 Reduction Techniques and CatalystsElectrocatalysts for Energy ConversionCatalysts for Methane Reforming

The DOI matches its Crossref record; 42 of the 42 references it cites were found in a registry or an index.

Enhanced electrocatalytic CO2 reduction via field-induced reagent concentration

Liu, Min, Pang, Yuanjie, Zhang, Bo, De Luna, Phil, Voznyy, Oleksandr, Xu, Jixian, Zheng, Xueli, Dinh, Cao Thang, Fan, Fengjia, Cao, Changhong, de Arquer, F. Pelayo García, Safaei, Tina Saberi, Mepham, Adam, Klinkova, Anna, Kumacheva, Eugenia, Filleter, Tobin, Sinton, David, Kelley, Shana O., Sargent, Edward H.·2016·Nature

DOI 10.1038/nature19060

Open this paper in CoChat — free account

Abstract

Electrochemical reduction of carbon dioxide (CO 2) to carbon monoxide (CO) is the first step in the synthesis of more complex carbon-based fuels and feedstocks using renewable electricity. Unfortunately, the reaction suffers from slow kinetics owing to the low local concentration of CO 2 surrounding typical CO 2 reduction reaction catalysts. Alkali metal cations are known to overcome this limitation through non-covalent interactions with adsorbed reagent species, but the effect is restricted by the solubility of relevant salts. Large applied electrode potentials can also enhance CO 2 adsorption, but this comes at the cost of increased hydrogen (H 2) evolution. Here we report that nanostructured electrodes produce, at low applied overpotentials, local high electric fields that concentrate electrolyte cations, which in turn leads to a high local concentration of CO 2 close to the active CO 2 reduction reaction surface. Simulations reveal tenfold higher electric fields associated with metallic nanometre-sized tips compared to quasi-planar electrode regions, and measurements using gold nanoneedles confirm a field-induced reagent concentration that enables the CO 2 reduction reaction to proceed with a geometric current density for CO of 22 milliamperes per square centimetre at -0.35 volts (overpotential of 0.24 volts). This performance surpasses by an order of magnitude the performance of the best gold nanorods, nanoparticles and oxide-derived noble metal catalysts. Similarly designed palladium nanoneedle electrocatalysts produce formate with a Faradaic efficiency of more than 90 per cent and an unprecedented geometric current density for formate of 10 milliamperes per square centimetre at -0.2 volts, demonstrating the wider applicability of the field-induced reagent concentration concept.

Integrity signals

Registry

Crossref · 10.1038/nature19060

Cites

42 of 42 references verified0 citation errors · 0 not checkable

Statistics

Recomputing p-values needs the paper’s full text.

Claims the paper makes

This paper’s full text isn’t openly available, so its claims and self-check weren’t run. The registry and citation checks still apply.

Claims other papers make about this one

Each is checked against this paper’s own text: does it say what the citing paper says it does?

Generalized Gradient Approximation Made Simple
Perdew, J. P., Burke, K., & Ernzerhof, M. (1996) · Physical Review Letters · doi:10.1103/physrevlett.77.3865 · Cited by 215,824
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set
Kresse, G., & Furthmüller, J. (1996) · Physical Review B · doi:10.1103/physrevb.54.11169 · Cited by 123,652
Projector augmented-wave method
Blöchl, P. E. (1994) · Physical Review B · doi:10.1103/physrevb.50.17953 · Cited by 92,732
From ultrasoft pseudopotentials to the projector augmented-wave method
Kresse, G., & Joubert, D. (1999) · Physical Review B · doi:10.1103/physrevb.59.1758 · Cited by 85,307
Special points for Brillouin-zone integrations
Monkhorst, H. J., & Pack, J. D. (1976) · Physical Review B · doi:10.1103/physrevb.13.5188 · Cited by 71,721
VMD: visual molecular dynamics
Humphrey, W., Dalke, A., & Schulten, K. (1996) · Journal of Molecular Graphics · doi:10.1016/0263-7855(96)00018-5 · Cited by 66,952
A grid-based Bader analysis algorithm without lattice bias
Tang, W., Sanville, E., & Henkelman, G. (2009) · Journal of Physics Condensed Matter · doi:10.1088/0953-8984/21/8/084204 · Cited by 7,595
Modern Aspects of Electrochemistry
Bockris, J. O., White, R. E., & Conway, B. E. (2002) · Kluwer Academic Publishers eBooks · doi:10.1007/b114168 · Cited by 5,954
How copper catalyzes the electroreduction of carbon dioxide into hydrocarbon fuels
Peterson, A. A., Abild-Pedersen, F., Studt, F., Rossmeisl, J., & Nørskov, J. K. (2010) · Energy & Environmental Science · doi:10.1039/c0ee00071j · Cited by 3,784
Recent advances in catalytic hydrogenation of carbon dioxide
Wang, W., Wang, S., Ma, X., & Gong, J. (2011) · Chemical Society Reviews · doi:10.1039/c1cs15008a · Cited by 3,316

Flagged first, then by citations

Show all 42 references

Research works printed but not linked: 2

Jackson, J. D. Classical Electrodynamics Vol. 3, 75–79 (Wiley, 1962)
Serway, R. A. & Jewett, J. W. Principles of Physics Vol. 1, 602 (Saunders College Pub., 1998)

Sorted by citations

Items 401–500 of 1,001

Suppressing H2 Evolution and Promoting Selective CO2 Electroreduction to CO at Low Overpotentials by Alloying Au with Pd
Valenti, M., Prasad, N. P., Kaş, R., Bohra, D., Ma, M., Balasubramanian, V., Chu, L., Giménez, S., Bisquert, J., Dam, B., et al. (2019) · ACS Catalysis · doi:10.1021/acscatal.8b04604 · Cited by 116
Reaction intermediates during operando electrocatalysis identified from full solvent quantum mechanics molecular dynamics
Cheng, T., Fortunelli, A., & Goddard, W. A. (2019) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1821709116 · Cited by 116
Dramatic differences in carbon dioxide adsorption and initial steps of reduction between silver and copper
Ye, Y., Yang, H., Qian, J., Su, H., Lee, K. J., Cheng, T., Xiao, H. Y., Yano, J., Goddard, W. A., & Crumlin, E. J. (2019) · Nature Communications · doi:10.1038/s41467-019-09846-y · Cited by 116
Utilizing spatial confinement effect of N atoms in micropores of coal-based metal-free material for efficiently electrochemical reduction of carbon dioxide
Liu, W., Qi, J., Bai, P., Zhang, W., & Xu, L. (2020) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2020.118974 · Cited by 115
Interfacial electric field effect on electrochemical carbon dioxide reduction reaction
Yu, J., Yin, J., Li, R., Ma, Y., & Fan, Z. (2022) · Chem Catalysis · doi:10.1016/j.checat.2022.07.024 · Cited by 116
Partially Nitrided Ni Nanoclusters Achieve Energy‐Efficient Electrocatalytic CO 2 Reduction to CO at Ultralow Overpotential
Zhao, R., Wang, Y., Ji, G., Zhong, J., Zhang, F., Chen, M., Tong, S., Wang, P., Wu, Z., Han, B., et al. (2022) · Advanced Materials · doi:10.1002/adma.202205262 · Cited by 113
Nanostrukturierte Materialien für die elektrokatalytische CO2‐Reduktion und ihre Reaktionsmechanismen
Zhang, L., Zhao, Z., & Gong, J. (2017) · Angewandte Chemie · doi:10.1002/ange.201612214 · Cited by 114
Atomic nickel cluster decorated defect-rich copper for enhanced C2 product selectivity in electrocatalytic CO2 reduction
Zhang, X., Liu, C., Zhao, Y. S., Li, L., Chen, Y., Raziq, F., Qiao, L., Guo, S.-X., Wang, C., Wallace, G. G., et al. (2021) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2021.120030 · Cited by 113
Active-Site Tailoring of Gold Cluster Catalysts for Electrochemical CO 2 Reduction
Sun, Y.-N., Liu, X., Xiao, K., Zhu, Y., & Chen, M. (2021) · ACS Catalysis · doi:10.1021/acscatal.1c02193 · Cited by 112
Revealing the Predominant Surface Facets of Rough Cu Electrodes under Electrochemical Conditions
Gunathunge, C. M., Li, J., Li, X., Hong, J. J., & Waegele, M. M. (2020) · ACS Catalysis · doi:10.1021/acscatal.9b05532 · Cited by 111
Dual-Sites Tandem Catalysts for C–N Bond Formation via Electrocatalytic Coupling of CO 2 and Nitrogenous Small Molecules
Fu, J., Yang, Y., & Hu, J. (2021) · ACS Materials Letters · doi:10.1021/acsmaterialslett.1c00375 · Cited by 113
Role of the Adsorbed Oxygen Species in the Selective Electrochemical Reduction of CO 2 to Alcohols and Carbonyls on Copper Electrodes
Duff, C. S. L., Lawrence, M. J., & Rodríguez, P. (2017) · Angewandte Chemie International Edition · doi:10.1002/anie.201706463 · Cited by 111
Efficient nanomaterials for harvesting clean fuels from electrochemical and photoelectrochemical CO 2 reduction
Yang, Y., Ajmal, S., Zheng, X., & Zhang, L. (2017) · Sustainable Energy & Fuels · doi:10.1039/c7se00371d · Cited by 112
Self-citation
A bio-inspired O2-tolerant catalytic CO2 reduction electrode
Xu, L. X., Jiang, Z. S., Yuan, X., Wu, Y., Malpass‐Evans, R., Zhong, Y., Liang, Y., McKeown, N. B., & Wang, H. (2019) · 中国科学通报：英文版 · doi:10.1016/j.scib.2019.04.008 · Cited by 114
Integration of CO2 Capture and Electrochemical Conversion
Xia, Q., Zhang, K., Zheng, T., An, L., Xia, C., & Zhang, X. (2023) · ACS Energy Letters · doi:10.1021/acsenergylett.3c00738 · Cited by 116
Electrocatalytic CO 2 Reduction to Ethylene: From Advanced Catalyst Design to Industrial Applications
Lu, T., Xu, T., Zhu, S., Li, J., Wang, J., Jin, H., Wang, X., Lv, J., Wang, Z., & Wang, S. (2023) · Advanced Materials · doi:10.1002/adma.202310433 · Cited by 113
Innovations in catalysis towards efficient electrochemical reduction of CO2 to C1 chemicals
Ahmed, S., Hussain, M. S., Khan, M. K. I., & Kim, J. (2025) · Journal of Energy Chemistry · doi:10.1016/j.jechem.2025.03.055 · Cited by 113
Insight into the Microenvironments of the Metal–Ionic Liquid Interface during Electrochemical CO2 Reduction
Lim, H., Kwon, Y., Kim, H. S., Jeon, J., Lim, J.-A., Lim, J.-A., Kim, B.-S., Choi, J., & Kim, H. (2018) · ACS Catalysis · doi:10.1021/acscatal.7b03777 · Cited by 111
Vertex‐Type Engineering of Pt–Cu–Rh Heterogeneous Nanocages for Highly Efficient Ethanol Electrooxidation
Wang, K., Du, H., Sriphathoorat, R., & Shen, P. K. (2018) · Advanced Materials · doi:10.1002/adma.201804074 · Cited by 110
Durian-Inspired Design of Bismuth–Antimony Alloy Arrays for Robust Sodium Storage
Ni, J., Li, X., Sun, M., Yuan, Y., Liu, T., Li, L., & Lu, J. B. (2020) · ACS Nano · doi:10.1021/acsnano.0c04366 · Cited by 109
Recent Advances and Perspectives of Electrochemical CO2 Reduction Toward C2+ Products on Cu-Based Catalysts
Wang, X., Hu, Q. L., Li, G., Yang, H., & He, C. (2022) · Electrochemical Energy Reviews · doi:10.1007/s41918-022-00171-5 · Cited by 113
Unraveling the Mechanism for the Sharp‐Tip Enhanced Electrocatalytic Carbon Dioxide Reduction: The Kinetics Decide
Jiang, H., Hou, Z., & Luo, Y. (2017) · Angewandte Chemie International Edition · doi:10.1002/anie.201708825 · Cited by 108
A Universal Approach for Sustainable Urea Synthesis via Intermediate Assembly at the Electrode/Electrolyte Interface
Tu, X., Zhu, X., Bo, S., Zhang, X., Miao, R., Wen, G., Chen, C., Li, J., Zhou, Y., Liu, Q., et al. (2023) · Angewandte Chemie International Edition · doi:10.1002/anie.202317087 · Cited by 107
Transition Metal Chalcogenides as a Versatile and Tunable Platform for Catalytic CO 2 and N 2 Electroreduction
Giuffredi, G., Asset, T., Liu, Y., Atanassov, P. B., & Fonzo, F. D. (2021) · ACS Materials Au · doi:10.1021/acsmaterialsau.1c00006 · Cited by 109
Coupling CO2 reduction with CH3OH oxidation for efficient electrosynthesis of formate on hierarchical bifunctional CuSn alloy
Li, Y., Huo, C., Wang, H., Ye, Z.-X., Luo, P., Cao, X., & Lu, T. (2022) · Nano Energy · doi:10.1016/j.nanoen.2022.107277 · Cited by 106
Surface Atomic Arrangement Dependence of Electrochemical CO2 Reduction on Gold: Online Electrochemical Mass Spectrometric Study on Low-Index Au(hkl) Surfaces
Todoroki, N., Tei, H., Tsurumaki, H., Miyakawa, T., Inoue, T., & Wadayama, T. (2019) · ACS Catalysis · doi:10.1021/acscatal.8b04852 · Cited by 107
Separated growth of Bi-Cu bimetallic electrocatalysts on defective copper foam for highly converting CO2 to formate with alkaline anion-exchange membrane beyond KHCO3 electrolyte
Peng, L., Wang, Y., Wang, Y., Xu, N., Lou, W., Liu, P., Cai, D., Huang, H., & Qiao, J. (2021) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2021.120003 · Cited by 105
Transition metal-based single-atom catalysts (TM-SACs); rising materials for electrochemical CO2 reduction
Mohanty, B., Basu, S., & Jena, B. K. (2022) · Journal of Energy Chemistry · doi:10.1016/j.jechem.2022.02.045 · Cited by 107
Heteroatoms Induce Localization of the Electric Field and Promote a Wide Potential‐Window Selectivity Towards CO in the CO 2 Electroreduction
Cai, C., Liu, B., Liu, K., Li, P., Fu, J., Wang, Y., Li, W., Tian, C., Kang, Y., Ştefancu, A., et al. (2022) · Angewandte Chemie International Edition · doi:10.1002/anie.202212640 · Cited by 106
Self-citation
Boosting Hydrogen Peroxide Electrosynthesis via Modulating the Interfacial Hydrogen‐Bond Environment
Fang, Y., Yu, F., Xie, K., Ge, W., Zhu, Y., Qi, Z., Song, Z., Jiang, H., & Li, C. (2023) · Angewandte Chemie International Edition · doi:10.1002/anie.202304413 · Cited by 105
Electrocatalysis of gold-based nanoparticles and nanoclusters
Li, C., Chai, O. J. H., Yao, Q., Liu, Z., Wang, L., Wang, H., & Xie, J. (2021) · Materials Horizons · doi:10.1039/d0mh01947j · Cited by 104
Phase engineering of metal nanocatalysts for electrochemical CO2 reduction
Zhai, Y., Han, P., Yun, Q., Ge, Y., Zhang, X., Chen, Y., & Zhang, H. (2022) · eScience · doi:10.1016/j.esci.2022.09.002 · Cited by 104
Band alignment in Zn2SnO4/SnO2 heterostructure enabling efficient CO2 electrochemical reduction
Wang, K., Liu, D., Deng, P., Liu, L., Lu, S., Sun, Z., Ma, Y., Wang, Y., Li, M., Xia, B. Y., et al. (2019) · Nano Energy · doi:10.1016/j.nanoen.2019.103954 · Cited by 103
Toward Excellence of Transition Metal‐Based Catalysts for CO2 Electrochemical Reduction: An Overview of Strategies and Rationales
Li, M., Garg, S., Chang, X., Ge, L., Li, L., Targinovna, K. M., Rufford, T. E., Rudolph, V., & Wang, G. (2020) · Small Methods · doi:10.1002/smtd.202000033 · Cited by 104
Tracking structural evolution: operando regenerative CeOx/Bi interface structure for high-performance CO2 electroreduction
Pang, R., Tian, P., Jiang, H., Zhu, M., Su, X., Wang, Y., Yang, X., Zhu, Y., Song, L., & Li, C. (2020) · National Science Review · doi:10.1093/nsr/nwaa187 · Cited by 104
Local hydroxyl enhancement design of NiFe sulfide electrocatalyst toward efficient oxygen evolution reaction
Liu, X., Zhao, X., Cao, S., Xu, M., Wang, Y., Xue, W., & Li, J. (2023) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2023.122715 · Cited by 103
Computational Screening of Near-Surface Alloys for CO2 Electroreduction
Zhao, Z., & Lü, G. (2018) · ACS Catalysis · doi:10.1021/acscatal.7b03705 · Cited by 105
Defect‐Enhanced CO2 Reduction Catalytic Performance in O‐Terminated MXenes
Chen, H., Handoko, A. D., Wang, T., Qu, J., Xiao, J., Liu, X., Legut, D., Seh, Z. W., & Zhang, Q. (2020) · ChemSusChem · doi:10.1002/cssc.202001624 · Cited by 104
Electrochemical CO 2 Reduction at Silver from a Local Perspective
Zhu, X., Huang, J., & Eikerling, M. H. (2021) · ACS Catalysis · doi:10.1021/acscatal.1c04791 · Cited by 106
Regulating the Local Charge Distribution of Ni Active Sites for the Urea Oxidation Reaction
Wang, L., Zhu, Y., Wen, Y., Li, S., Cui, C., Ni, F., Liu, Y., Lin, H., Li, Y., Peng, H., et al. (2021) · Angewandte Chemie · doi:10.1002/ange.202100610 · Cited by 104
Self-citation
Recent Advances on Single‐Atom Catalysts for Photocatalytic CO 2 Reduction
Shang, Z., Feng, C., Chen, G., Qin, R., & Han, Y. (2023) · Small · doi:10.1002/smll.202304975 · Cited by 106
Low-Energy Electrocatalytic CO2 Reduction in Water over Mn-Complex Catalyst Electrode Aided by a Nanocarbon Support and K+ Cations
Sato, S., Saita, K., Sekizawa, K., Maeda, S., & Morikawa, T. (2018) · ACS Catalysis · doi:10.1021/acscatal.8b01068 · Cited by 101
Highly Efficient CO2 Electroreduction on ZnN4‐based Single‐Atom Catalyst
Fa, Y., Song, P., Liu, X., Mei, B., Xing, W., Jiang, Z. R., Gu, L., & Xu, W. (2018) · Angewandte Chemie · doi:10.1002/ange.201805871 · Cited by 101
High-Throughput Screening of Stable Single-Atom Catalysts in CO 2 Reduction Reactions
Qi, R., Zhu, B., Han, Z., & Gao, Y. (2022) · ACS Catalysis · doi:10.1021/acscatal.2c02149 · Cited by 105
Carbon Capture and Utilization by Algae with High Concentration CO2 or Bicarbonate as Carbon Source
Yang, Y., Tang, S., & Chen, J. P. (2024) · Science of The Total Environment · doi:10.1016/j.scitotenv.2024.170325 · Cited by 100
Controllable CO adsorption determines ethylene and methane productions from CO2 electroreduction
Bai, H., Cheng, T., Li, S., Zhou, Z., Yang, H., Li, J., Xie, M., Ye, J., Ji, Y., Li, Y., et al. (2020) · 中国科学通报：英文版 · doi:10.1016/j.scib.2020.06.023 · Cited by 104
Self-citation
Environment Matters: CO2RR Electrocatalyst Performance Testing in a Gas-Fed Zero-Gap Electrolyzer
Gálvez‐Vázquez, M. D. J., Moreno‐García, P., Xu, H., Hou, Y., Hu, H., Montiel, I. Z., Rudnev, A. V., Alinejad, S., Grozovski, V., Wiley, B. J., et al. (2020) · ACS Catalysis · doi:10.1021/acscatal.0c03609 · Cited by 103
Facile synthesis of porous Cu-Sn alloy electrode with prior selectivity of formate in a wide potential range for CO2 electrochemical reduction
Li, D., Huang, L., Tian, Y. E., Liu, T., Zhen, L., & Feng, Y. (2021) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2021.120119 · Cited by 100
Towards Higher Rate Electrochemical CO2 Conversion: From Liquid-Phase to Gas-Phase Systems
Song, J. T., Song, H., Kim, B.-I., & Oh, J. (2019) · Catalysts · doi:10.3390/catal9030224 · Cited by 106
Catalyst design strategies for stable electrochemical CO 2 reduction reaction
Choi, W. C., Won, D. H., & Hwang, Y. J. (2020) · Journal of Materials Chemistry A · doi:10.1039/d0ta02633f · Cited by 103
In Situ Chalcogen Leaching Manipulates Reactant Interface toward Efficient Amine Electrooxidation
Wen, Q., Lin, Y., Yang, Y., Gao, R., Ouyang, N., Ding, D., Liu, Y., & Zhai, T. (2022) · ACS Nano · doi:10.1021/acsnano.2c02838 · Cited by 99
A Cation Concentration Gradient Approach to Tune the Selectivity and Activity of CO2 Electroreduction
Ren, W., Xu, A., Chan, K., & Hu, X. (2022) · Angewandte Chemie International Edition · doi:10.1002/anie.202214173 · Cited by 101
Copper and Copper‐Based Bimetallic Catalysts for Carbon Dioxide Electroreduction
Birhanu, M. K., Tsai, M., Kahsay, A. W., Chen, C.-T., Zeleke, T. S., Ibrahim, K. B., Huang, C., Su, W.-N. J., & Hwang, B. (2018) · Advanced Materials Interfaces · doi:10.1002/admi.201800919 · Cited by 99
Design of doped cesium lead halide perovskite as a photo-catalytic CO 2 reduction catalyst
Tang, C. W., Chen, C., Xu, W., & Xu, L. (2019) · Journal of Materials Chemistry A · doi:10.1039/c9ta00550a · Cited by 98
Advanced Routes of Biological and Bio-electrocatalytic Carbon Dioxide (CO2) Mitigation Toward Carbon Neutrality
Kondaveeti, S., Abu-Reesh, I. M., Mohanakrishna, G., Bulut, M., & Pant, D. (2020) · Frontiers in Energy Research · doi:10.3389/fenrg.2020.00094 · Cited by 99
Advanced Materials for Energy-Water Systems: The Central Role of Water/Solid Interfaces in Adsorption, Reactivity, and Transport
Barry, E., Burns, R., Chen, W., Hoe, G. X. D., de, J. M. M., Pablo, J., Dombrowski, J. P., Elam, J. W., Felts, A. M., Galli, G., et al. (2021) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00069 · Cited by 98
Low-overpotential selective reduction of CO2 to ethanol on electrodeposited Cu Au nanowire arrays
Zhu, W., Zhao, K., Liu, S., Liu, M., Peng, F., An, P., Qin, B., Zhou, H., Li, H., & He, Z. (2019) · Journal of Energy Chemistry · doi:10.1016/j.jechem.2019.03.030 · Cited by 98
Self-citation
Recent Development of Electrocatalytic CO 2 Reduction Application to Energy Conversion
Liang, F., Zhang, K., Zhang, L., Zhang, Y., Lei, Y., & Sun, X. A. (2021) · Small · doi:10.1002/smll.202100323 · Cited by 100
Efficient Electrocatalytic Reduction of CO2 by Nitrogen‐Doped Nanoporous Carbon/Carbon Nanotube Membranes: A Step Towards the Electrochemical CO2 Refinery
Wang, H., Jia, J., Song, P., Wang, Q., Li, D., Min, S., Qian, C., Wang, L., Li, Y. F., Ma, C., et al. (2017) · Angewandte Chemie · doi:10.1002/ange.201703720 · Cited by 98
Porous Organic Polymers‐Based Single‐Atom Catalysts for Sustainable Energy‐Related Electrocatalysis
Li, H., Pan, F., Chen, Q. K., Wang, T., & Chen, K. (2023) · Advanced Energy Materials · doi:10.1002/aenm.202301378 · Cited by 98
Nanoscale Engineering of P‐Block Metal‐Based Catalysts Toward Industrial‐Scale Electrochemical Reduction of CO2
Li, P., Yang, F., Li, J., Zhu, Q., Xu, J. W., Loh, X. J., Huang, K., Hu, W., & Lu, J. (2023) · Advanced Energy Materials · doi:10.1002/aenm.202301597 · Cited by 97
Self-citation
Copper-modulated bismuth nanocrystals alter the formate formation pathway to achieve highly selective CO 2 electroreduction
Zu, M. Y., Zhang, L., Wang, C., Zheng, L., & Yang, H. G. (2018) · Journal of Materials Chemistry A · doi:10.1039/c8ta05355c · Cited by 96
Catalytic Principles from Natural Enzymes and Translational Design Strategies for Synthetic Catalysts
Li, W., & Head-Gordon, T. L. (2020) · ACS Central Science · doi:10.1021/acscentsci.0c01556 · Cited by 97
Atomic-level polarization in electric fields of defects for electrocatalysis
Xu, J., Xue, X., Shao, G., Jing, C., Dai, S., He, K., Jia, P., Wang, S., Yuan, Y., Luo, J., et al. (2023) · Nature Communications · doi:10.1038/s41467-023-43689-y · Cited by 96
Self-citation
Rational Design of Silver Sulfide Nanowires for Efficient CO2 Electroreduction in Ionic Liquid
Liu, S., Tao, H., Liu, Q., Xu, Z., Liu, Q., & Luo, J. (2018) · ACS Catalysis · doi:10.1021/acscatal.7b03619 · Cited by 97
Enhanced Electrochemical Reduction of CO2 Catalyzed by Cobalt and Iron Amino Porphyrin Complexes
Abdinejad, M., Seifitokaldani, A., Dao, C., Sargent, E. H., Zhang, X., & Kraatz, H. (2019) · ACS Applied Energy Materials · doi:10.1021/acsaem.8b01900 · Cited by 99
Self-citation
Electrochemical promotion of catalysis over Pd nanoparticles for CO 2 reduction
Cai, F., Gao, D., Zhou, H., Wang, G., He, T., Gong, H., Miao, S., Yang, F., Wang, J., & Bao, X. (2017) · Chemical Science · doi:10.1039/c6sc04966d · Cited by 94
Roadmap for optofluidics
Minzioni, P., Osellame, R., Sada, C., Zhao, S., Omenetto, F. G., Gylfason, K. B., Haraldsson, T., Zhang, Y., Özcan, A., Wax, A. P., et al. (2017) · Journal of Optics · doi:10.1088/2040-8986/aa783b · Cited by 96
Self-citation
The electrolyte matters: Stable systems for high rate electrochemical CO2 reduction
Vennekötter, J.-B., Scheuermann, T., Sengpiel, R., & Weßling, M. (2019) · Journal of CO2 Utilization · doi:10.1016/j.jcou.2019.04.007 · Cited by 98
Plasmon-Mediated Electrocatalysis for Sustainable Energy: From Electrochemical Conversion of Different Feedstocks to Fuel Cell Reactions
Choi, C. H., Chung, K., Nguyen, T. H. T., & Kim, D. H. (2018) · ACS Energy Letters · doi:10.1021/acsenergylett.8b00461 · Cited by 96
Electric Fields at Metal–Surfactant Interfaces: A Combined Vibrational Spectroscopy and Capacitance Study
Sarkar, S., Maitra, A., Banerjee, S., Thoi, V. S., & Dawlaty, J. M. (2020) · The Journal of Physical Chemistry B · doi:10.1021/acs.jpcb.0c00560 · Cited by 93
Biochar/Zinc Oxide Composites as Effective Catalysts for Electrochemical CO2Reduction
Lourenço, M. A. O., Zeng, J., Jagdale, P., Castellino, M., Sacco, A., Farkhondehfal, M. A., & Pirri, C. F. (2021) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.1c00837 · Cited by 96
Tuning the intermediate reaction barriers by a CuPd catalyst to improve the selectivity of CO2 electroreduction to C2 products
Zhu, L., Lin, Y., Liu, K., Cortés, E., Li, H., Hu, J., Yamaguchi, A., Liu, X., Miyauchi, M., Fu, J., et al. (2021) · CHINESE JOURNAL OF CATALYSIS (CHINESE VERSION) · doi:10.1016/s1872-2067(20)63754-8 · Cited by 94
Self-citation
(111) Facet‐oriented Cu2Mg Intermetallic Compound with Cu3‐Mg Sites for CO2 Electroreduction to Ethanol with Industrial Current Density
Chen, P., Ma, J., Luo, G., Yan, S., Zhang, J., Chen, Y., Chen, N., Wang, Z., Wei, W., Sham, T., et al. (2024) · Angewandte Chemie International Edition · doi:10.1002/anie.202316907 · Cited by 94
Mechanistic Insights into Cation Effects in Electrolytes for Electrocatalysis
Wu, Q., & Xu, Z. J. (2025) · Angewandte Chemie International Edition · doi:10.1002/anie.202505022 · Cited by 93
Selective electrochemical CO 2 reduction over highly porous gold films
Chen, C., Zhang, B., Zhong, J., & Cheng, Z. (2017) · Journal of Materials Chemistry A · doi:10.1039/c7ta04983h · Cited by 92
Self-citation
Bimetallic effects on Zn-Cu electrocatalysts enhance activity and selectivity for the conversion of CO2 to CO
Wang, L., Peng, H., Lamaison, S., Qi, Z., Koshy, D. M., Stevens, M. B., Wakerley, D., Zeledon, J. A. Z., King, L. A., Zhou, L., et al. (2021) · Chem Catalysis · doi:10.1016/j.checat.2021.05.006 · Cited by 94
Effects of Electrolyte Ionic Species on Electrocatalytic Reactions: Advances, Challenges, and Perspectives
Lu, X., Tu, W., Zhou, Y. L., & Zou, Z. (2023) · Advanced Energy Materials · doi:10.1002/aenm.202300628 · Cited by 95
Unique copper and reduced graphene oxide nanocomposite toward the efficient electrochemical reduction of carbon dioxide
Hossain, M. N., Wen, J., & Chen, A. (2017) · Scientific Reports · doi:10.1038/s41598-017-03601-3 · Cited by 91
Two-step electrochemical reduction of CO2 towards multi-carbon products at high current densities
Cuellar, N. S. R., Scherer, C., Kaçkar, B., Eisenreich, W., Huber, C., Wiesner‐Fleischer, K., Fleischer, M., & Hinrichsen, O. (2019) · Journal of CO2 Utilization · doi:10.1016/j.jcou.2019.10.016 · Cited by 93
Tuning the Microenvironment in Monolayer MgAl Layered Double Hydroxide for CO 2 ‐to‐Ethylene Electrocatalysis in Neutral Media
Xu, Y. N., Li, W., Fu, H. Q., Zhang, X. Y., Zhao, J. Y., Wu, X., Yuan, H., Zhu, M., Dai, S., Liu, P. F., et al. (2023) · Angewandte Chemie International Edition · doi:10.1002/anie.202217296 · Cited by 91
Rational design of Cu-based electrocatalysts for electrochemical reduction of carbon dioxide
Zhang, B., & Zhang, J. (2017) · Journal of Energy Chemistry · doi:10.1016/j.jechem.2017.10.011 · Cited by 91
Self-citation
Sharp Cu@Sn nanocones on Cu foam for highly selective and efficient electrochemical reduction of CO 2 to formate
Chen, C., Pang, Y., Zhang, F., Zhong, J., Zhang, B., & Cheng, Z. (2018) · Journal of Materials Chemistry A · doi:10.1039/c8ta06826g · Cited by 90
Self-citation
Ultra-fine surface solid-state electrolytes for long cycle life all-solid-state lithium–air batteries
Wang, S., Wang, J., Liu, J., Song, H., Liu, Y., Wang, P., He, P., Xu, J., & Zhou, H. S. (2018) · Journal of Materials Chemistry A · doi:10.1039/c8ta08095j · Cited by 90
Self-citation
Regulating electrochemical CO2RR selectivity at industrial current densities by structuring copper@poly(ionic liquid) interface
Li, X., Duan, G., Chen, J.-W., Han, L., Zhang, S., & Xu, B. (2021) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2021.120471 · Cited by 91
Engineering Electrochemical Surface for Efficient Carbon Dioxide Upgrade
Wen, G., Ren, B., Zheng, Y. H., Li, M., Silva, C. J., Song, S., Zhang, Z., Dou, H., Zhao, L., Luo, D., et al. (2021) · Advanced Energy Materials · doi:10.1002/aenm.202103289 · Cited by 90
Advanced Catalyst Design and Reactor Configuration Upgrade in Electrochemical Carbon Dioxide Conversion
Wang, Z., Zhou, Y., Qiu, P., Xia, C., Fang, W., Jin, J., Huang, L., Deng, P., Su, Y., Crespo‐Otero, R., et al. (2023) · Advanced Materials · doi:10.1002/adma.202303052 · Cited by 91
Self-citation
Effect of crystal facets in plasmonic catalysis
Kang, Y., João, S. M., Lin, R., Liu, K., Zhu, L., Fu, J., Cheong, W.-C. M., Lee, S., Frank, K., Nickel, B. A., et al. (2024) · Nature Communications · doi:10.1038/s41467-024-47994-y · Cited by 90
Self-citation
Unlocking Bifunctional Electrocatalytic Activity for CO 2 Reduction Reaction by Win-Win Metal–Oxide Cooperation
Cai, Z., Wu, Y., Wu, Z., Yin, L., Weng, Z., Zhong, Y., Xu, W., Sun, X., & Wang, H. (2018) · ACS Energy Letters · doi:10.1021/acsenergylett.8b01767 · Cited by 89
An Integrated CO2 Electrolyzer and Formate Fuel Cell Enabled by a Reversibly Restructuring Pb–Pd Bimetallic Catalyst
Xu, L. X., Wu, Y., Yuan, X., & Wang, H. (2019) · Angewandte Chemie International Edition · doi:10.1002/anie.201814257 · Cited by 89
Promotion of CO 2 Electrochemical Reduction via Cu Nanodendrites
Wu, M., Zhu, C., Wang, K., Li, G., Dong, X., Song, Y., Xue, J., Chen, W., Wei, W., & Sun, Y. (2020) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.9b21153 · Cited by 90
Surface Nitrogen-Injection Engineering for High Formation Rate of CO 2 Reduction to Formate
Han, C. L., Liu, S., Zhang, J., Zhou, T., Zhang, N., Zheng, X., Chu, W., Hu, Z., Wu, C., & Xie, Y. (2020) · Nano Letters · doi:10.1021/acs.nanolett.0c02144 · Cited by 89
Self-citation
Closing the Anthropogenic Chemical Carbon Cycle toward a Sustainable Future via CO2 Valorization
Zhang, J., Sewell, C. D., Huang, H., & Lin, Z. (2021) · Advanced Energy Materials · doi:10.1002/aenm.202102767 · Cited by 91
Metal-organic framework-derived diatomic catalysts for environmental remediation: Synthesis, applications and improvement strategies
Hu, T., Zhou, W., & Tang, W. (2024) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2024.216357 · Cited by 89
Installation of internal electric fields by non-redox active cations in transition metal complexes
Kang, K., Fuller, J. T., Reath, A. H., Ziller, J. W., Alexandrova, A. N., & Yang, J. Y. (2019) · Chemical Science · doi:10.1039/c9sc02870f · Cited by 90
Steering CO 2 electroreduction toward ethanol production by a surface-bound Ru polypyridyl carbene catalyst on N-doped porous carbon
Liu, Y., Fan, X., Nayak, A., Wang, Y., Shan, B., Quan, X., & Meyer, T. J. (2019) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1907740116 · Cited by 89
The atomic-level regulation of single-atom site catalysts for the electrochemical CO 2 reduction reaction
Qu, Q., Ji, S., Chen, Y., Wang, D. S., & Li, Y. (2021) · Chemical Science · doi:10.1039/d0sc07040h · Cited by 89
Chemical diversity in molecular orbital energy predictions with kernel ridge regression
Stuke, A., Todorović, M., Rupp, M., Künkel, C., Ghosh, K., Himanen, L., & Rinke, P. (2019) · The Journal of Chemical Physics · doi:10.1063/1.5086105 · Cited by 95
Electrode roughness dependent electrodeposition of sodium at the nanoscale
Zeng, Z., Barai, P., Lee, S., Yang, J., Zhang, X., Zheng, W., Liu, Y., Bustillo, K. C., Ercius, P. A., Guo, J., et al. (2020) · Nano Energy · doi:10.1016/j.nanoen.2020.104721 · Cited by 86
Bi nanodendrites for efficient electrocatalytic N 2 fixation to NH 3 under ambient conditions
Wang, F., Xu, L. S., Zhu, X., Du, J., Lu, S., Alshehri, A. A., Alzahrani, K. A., Zheng, B., & Sun, X. (2020) · Chemical Communications · doi:10.1039/c9cc09803h · Cited by 86

Authors: Liu, M., Pang, Y., Zhang, B., De Luna, P., Voznyy, O., Xu, J., Zheng, X., Dinh, C. T., Fan, F., Cao, C., de Arquer, F. P. G., Safaei, T. S., Mepham, A., Klinkova, A., Kumacheva, E., Filleter, T., Sinton, D., Kelley, S. O., & Sargent, E. H.
Affiliations: University of Toronto (CA)
East China University of Science and Technology (CN)
Tianjin University (CN)
Corresponding author: Sargent, Edward H.
ORCID: Liu, Min
Pang, Yuanjie
Zhang, Bo
Voznyy, Oleksandr
Xu, Jixian
Zheng, Xueli
Dinh, Cao Thang
Fan, Fengjia
Cao, Changhong
Klinkova, Anna
Kumacheva, Eugenia
Filleter, Tobin
Sinton, David
Kelley, Shana O.
Sargent, Edward H.
Venue: Nature
Publisher: Springer Science and Business Media LLC
Published: 2016-08-03
Volume: 537
Issue: 7620
Pages: 382-386
ISSN: 0028-0836 (ISSN-L)
1476-4687
DOI: 10.1038/nature19060
OpenAlex: W2496132953
Cited by: 2,000
References: 42
Citations by year: 2026: 150 · 2025: 195 · 2024: 265 · 2023: 238 · 2022: 218 · 2021: 233 · 2020: 226 · 2019: 201 · 2018: 164 · 2017: 104 · 2016: 6
FWCI: 43.01
Type: journal article
Language: en
Open access: closed
Licence: www.springer.com/tdm (tdm)
Locations: Nature (publishedVersion)
PubMed (publishedVersion)
RePEc: Research Papers in Economics (submittedVersion)
King Abdullah University of Science and Technology Repository (King Abdullah University of Science and Technology) (submittedVersion)
Topics: Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
Physical Sciences › Chemical Engineering › Catalysis › Catalysts for Methane Reforming
Keywords: electrochemical CO2 reduction, local electric field, CO2 adsorption, carbon monoxide production, formate production, nanostructured electrodes, alkali metal cations, CO2 reduction kinetics, hydrogen evolution suppression, electrocatalyst design, CO2 selectivity

About these checks

Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.

Statistics and arithmetic are recomputed, not judged.

Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.

What counts as a claim ›How we measure confidence ›How we check this ›

Are you an author, or do you see a problem with this page? Request a review

Enhanced electrocatalytic CO2 reduction via field-induced reagent concentration

Abstract

Overview

Integrity signals

Verification

Claims the paper makes

Claims other papers make about this one

Citations

Cites

Cited by

Related

Metadata

Record

About these checks