The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Chemically blockable transformation and ultraselective low-pressure gas adsorption in a non-porous metal organic framework
Open accessAbstract
Metal organic frameworks (MOFs) are among the most exciting materials discovered recently, attracting particular attention for their gas-adsorption and -storage properties. Certain MOFs show considerable structural flexibility in response to various stimuli. Although there are several examples of 'breathing' MOFs, in which structural changes occur without any bond breaking, examples of transformations in which several bonds are broken and made are much rarer. In this paper we demonstrate how a flexible MOF, Cu2(OH)(C8H3O7S)(H2O)2H2O, can be synthesized by careful choice of the organic linker ligand. The flexibility can be controlled by addition of a supplementary coordinating molecule, which increases the thermal stability of the solid sufficiently for direct imaging with electron microscopy to be possible. We also demonstrate that the MOF shows unprecedented low-pressure selectivity towards nitric oxide through a coordination-driven gating mechanism. The chemical control over these behaviours offers new possibilities for the synthesis of MOFs with unusual and potentially exploitable properties.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
NO-Releasing Zeolites and Their Antithrombotic Properties
Wheatley, P. S., Butler, A. R., Crane, M. S., Fox, S., Xiao, B., Rossi, A. G., Megson, I. L., & Morris, R. E. (2006) · Journal of the American Chemical Society · doi:10.1021/ja0503579 · Cited by 235
Self-citation
Cited by
Metal–Organic Frameworks for Separations
Li, J.-R., Sculley, J., & Zhou, H.-C. (2012) · Chemical Reviews · doi:10.1021/cr200190s · Cited by 6,323
BioMOFs: Metal–Organic Frameworks for Biological and Medical Applications
McKinlay, A. C., Morris, R. E., Horcajada, P., Férey, G., Gref, R., Couvreur, P., & Serre, C. (2010) · Angewandte Chemie International Edition · doi:10.1002/anie.201000048 · Cited by 1,256
Self-citationMetal–Organic Frameworks for Air Purification of Toxic Chemicals
DeCoste, J. B., & Peterson, G. W. (2014) · Chemical Reviews · doi:10.1021/cr4006473 · Cited by 958
Molecular decoding using luminescence from an entangled porous framework
Takashima, Y., Martínez, V. M., Furukawa, S., Kondo, M., Shimomura, S., Uehara, H., Nakahama, M., Sugimoto, K., & Kitagawa, S. (2011) · Nature Communications · doi:10.1038/ncomms1170 · Cited by 773
Porous materials with pre-designed single-molecule traps for CO2 selective adsorption
Li, J.-R., Yu, J., Lu, W., Sun, L.-B., Sculley, J., Balbuena, P. B., & Zhou, H.-C. (2013) · Nature Communications · doi:10.1038/ncomms2552 · Cited by 631
Metadata
- Authors
- Xiao, B., Byrne, P. J., Wheatley, P. S., Wragg, D. S., Zhao, X., Fletcher, A. J., Thomas, K. M., Peters, L., Evans, J. S. O., Warren, J. E., Zhou, W., & Morris, R. E.
- Venue
- Nature Chemistry
- Published
- 2009-06-22
- Volume
- 1
- Issue
- 4
- Pages
- 289-294
- ISSN
- 1755-4330 (ISSN-L)
- 1755-4349
- OpenAlex
- W2073172622
- Cited by
- 203
- References
- 1
- FWCI
- 14.58
- Type
- journal article
- Language
- en
- Open access
- green
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Chemically blockable transformation and ultraselective low-pressure gas adsorption in a non-porous metal organic framework. https://app.cochat.ai/papers/10.1038/nchem.254
- The paper
- Xiao, B., Byrne, P. J., Wheatley, P. S., Wragg, D. S., Zhao, X., Fletcher, A. J., Thomas, K. M., Peters, L., Evans, J. S. O., Warren, J. E., Zhou, W., & Morris, R. E. (2009). Chemically blockable transformation and ultraselective low-pressure gas adsorption in a non-porous metal organic framework. Nature Chemistry. https://doi.org/10.1038/nchem.254
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
