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A self-healable and highly stretchable supercapacitor based on a dual crosslinked polyelectrolyte

Open access
Huang, Yan, Zhong, Ming, Huang, Yang, Zhu, Minshen, Pei, Zengxia, Wang, Zifeng, Xue, Qi, Xie, Xuming, Zhi, Chunyi·2015·Nature Communications

Abstract

Superior self-healability and stretchability are critical elements for the practical wide-scale adoption of personalized electronics such as portable and wearable energy storage devices. However, the low healing efficiency of self-healable supercapacitors and the small strain of stretchable supercapacitors are fundamentally limited by conventional polyvinyl alcohol-based acidic electrolytes, which are intrinsically neither self-healable nor highly stretchable. Here we report an electrolyte comprising polyacrylic acid dual crosslinked by hydrogen bonding and vinyl hybrid silica nanoparticles, which displays all superior functions and provides a solution to the intrinsic self-healability and high stretchability problems of a supercapacitor. Supercapacitors with this electrolyte are non-autonomic self-healable, retaining the capacitance completely even after 20 cycles of breaking/healing. These supercapacitors are stretched up to 600% strain with enhanced performance using a designed facile electrode fabrication procedure.

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Crossref · 10.1038/ncomms10310

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Metadata

Authors
Huang, Y., Zhong, M., Huang, Y., Zhu, M., Pei, Z., Wang, Z., Xue, Q., Xie, X., & Zhi, C.
Venue
Nature Communications
Published
2015-12-22
Volume
6
Issue
1
Pages
10310-10310
ISSN
2041-1723 (ISSN-L)
OpenAlex
W2265740622
Cited by
742
References
1
FWCI
22.45
Type
journal article
Language
en
Open access
gold

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