The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Pure and stable metallic phase molybdenum disulfide nanosheets for hydrogen evolution reaction
Open accessAbstract
Metallic-phase MoS 2 (M-MoS 2) is metastable and does not exist in nature. Pure and stable M-MoS 2 has not been previously prepared by chemical synthesis, to the best of our knowledge. Here we report a hydrothermal process for synthesizing stable two-dimensional M-MoS 2 nanosheets in water. The metal–metal Raman stretching mode at 146 cm−1 in the M-MoS 2 structure, as predicted by theoretical calculations, is experimentally observed. The stability of the M-MoS 2 is associated with the adsorption of a monolayer of water molecules on both sides of the nanosheets, which reduce restacking and prevent aggregation in water. The obtained M-MoS 2 exhibits excellent stability in water and superior activity for the hydrogen evolution reaction, with a current density of 10 mA cm−2 at a low potential of −175 mV and a Tafel slope of 41 mV per decade.
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Cites
High yield exfoliation of two-dimensional chalcogenides using sodium naphthalenide
Zheng, J., Zhang, H., Dong, S., Liu, Y., Tai Nai, C., Suk Shin, H., Young Jeong, H., Liu, B., & Ping Loh, K. (2014) · Nature Communications · doi:10.1038/ncomms3995 · Cited by 787
Cited by
Multicomponent electrocatalyst with ultralow Pt loading and high hydrogen evolution activity
Tiwari, J. N., Sultan, S., Myung, C. W., Yoon, T., Li, N., Ha, M., Harzandi, A. M., Park, H. J., Kim, D. Y., Chandrasekaran, S. S., et al. (2018) · Nature Energy · doi:10.1038/s41560-018-0209-x · Cited by 722
2D Transition Metal Dichalcogenides: Design, Modulation, and Challenges in Electrocatalysis
Fu, Q., Han, J., Wang, X., Xu, P., Yao, T., Zhong, J., Zhong, W., Liu, S., Gao, T., Zhang, Z., et al. (2021) · Advanced Materials · doi:10.1002/adma.201907818 · Cited by 697
Preparation of 2D material dispersions and their applications
Cai, X., Luo, Y., Liu, B., & Cheng, H.-M. (2018) · Chemical Society Reviews · doi:10.1039/c8cs00254a · Cited by 665
Wang, M., Zhang, L., He, Y., & Zhu, H. (2021) · Journal of Materials Chemistry A · doi:10.1039/d0ta12152e · Cited by 648
Self-citationQi, K., Cui, X., Gu, L., Yu, S., Fan, X., Luo, M., Xu, S., Li, N., Zheng, L., Zhang, Q., et al. (2019) · Nature Communications · doi:10.1038/s41467-019-12997-7 · Cited by 554
Metadata
- Authors
- Geng, X., Sun, W., Wu, W., Chen, B., Al-Hilo, A., Benamara, M., Zhu, H., Watanabe, F., Cui, J., & Chen, T.-P.
- Venue
- Nature Communications
- Published
- 2016-02-10
- Volume
- 7
- Issue
- 1
- Pages
- 10672-10672
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W2342787304
- Cited by
- 917
- References
- 1
- FWCI
- 26.64
- Type
- journal article
- Language
- en
- Open access
- gold
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