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Cited by 509

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Separating hydrogen and oxygen evolution in alkaline water electrolysis using nickel hydroxide

Open access
Chen, Long, Dong, Xiaoli, Wang, Yonggang, Xia, Yongyao·2016·Nature Communications

Abstract

Low-cost alkaline water electrolysis has been considered a sustainable approach to producing hydrogen using renewable energy inputs, but preventing hydrogen/oxygen mixing and efficiently using the instable renewable energy are challenging. Here, using nickel hydroxide as a redox mediator, we decouple the hydrogen and oxygen production in alkaline water electrolysis, which overcomes the gas-mixing issue and may increase the use of renewable energy. In this architecture, the hydrogen production occurs at the cathode by water reduction, and the anodic Ni(OH)2 is simultaneously oxidized into NiOOH. The subsequent oxygen production involves a cathodic NiOOH reduction (NiOOH→Ni(OH)2) and an anodic OH− oxidization. Alternatively, the NiOOH formed during hydrogen production can be coupled with a zinc anode to form a NiOOH-Zn battery, and its discharge product (that is, Ni(OH)2) can be used to produce hydrogen again. This architecture brings a potential solution to facilitate renewables-to-hydrogen conversion.

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Metadata

Authors
Chen, L., Dong, X., Wang, Y., & Xia, Y.
Venue
Nature Communications
Published
2016-05-20
Volume
7
Issue
1
Pages
11741-11741
ISSN
2041-1723 (ISSN-L)
OpenAlex
W2400492407
Cited by
509
References
6
FWCI
10.46
Type
journal article
Language
en
Open access
gold

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CoChat. (2026). Citation check: Separating hydrogen and oxygen evolution in alkaline water electrolysis using nickel hydroxide. https://app.cochat.ai/papers/10.1038/ncomms11741
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Chen, L., Dong, X., Wang, Y., & Xia, Y. (2016). Separating hydrogen and oxygen evolution in alkaline water electrolysis using nickel hydroxide. Nature Communications. https://doi.org/10.1038/ncomms11741

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