The DOI matches its Crossref record; 33 of the 33 references it cites were found in a registry or an index.
Catalytic transformation of dinitrogen into ammonia and hydrazine by iron-dinitrogen complexes bearing pincer ligand
Open accessAbstract
Synthesis and reactivity of iron-dinitrogen complexes have been extensively studied, because the iron atom plays an important role in the industrial and biological nitrogen fixation. As a result, iron-catalyzed reduction of molecular dinitrogen into ammonia has recently been achieved. Here we show that an iron-dinitrogen complex bearing an anionic PNP-pincer ligand works as an effective catalyst towards the catalytic nitrogen fixation, where a mixture of ammonia and hydrazine is produced. In the present reaction system, molecular dinitrogen is catalytically and directly converted into hydrazine by using transition metal-dinitrogen complexes as catalysts. Because hydrazine is considered as a key intermediate in the nitrogen fixation in nitrogenase, the findings described in this paper provide an opportunity to elucidate the reaction mechanism in nitrogenase.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Grimme, S., Antony, J., Ehrlich, S., & Krieg, H. (2010) · The Journal of Chemical Physics · doi:10.1063/1.3382344 · Cited by 59,686
Phenol-hypochlorite reaction for determination of ammonia
Weatherburn, M. W. (1967) · Analytical Chemistry · doi:10.1021/ac60252a045 · Cited by 4,099
Yang, L., Powell, D. R., & Houser, R. P. (2007) · Dalton Trans. · doi:10.1039/b617136b · Cited by 3,477
Evans, D. F. (1959) · Journal of the Chemical Society (Resumed) · doi:10.1039/jr9590002003 · Cited by 2,777
Mechanism of Nitrogen Fixation by Nitrogenase: The Next Stage
Hoffman, B. M., Lukoyanov, D., Yang, Z.-Y., Dean, D. R., & Seefeldt, L. C. (2014) · Chemical Reviews · doi:10.1021/cr400641x · Cited by 1,766
Catalytic Reduction of Dinitrogen to Ammonia at a Single Molybdenum Center
Yandulov, D. V., & Schrock, R. R. (2003) · Science · doi:10.1126/science.1085326 · Cited by 1,433
Catalytic conversion of nitrogen to ammonia by an iron model complex
Anderson, J. S., Rittle, J., & Peters, J. C. (2013) · Nature · doi:10.1038/nature12435 · Cited by 1,003
Spectrophotometric Method for Determination of Hydrazine
Watt, G. W., & Chrisp, J. D. (1952) · Analytical Chemistry · doi:10.1021/ac60072a044 · Cited by 945
Recent advances in the chemistry of nitrogen fixation
Chatt, J., Dilworth, J. R., & Richards, R. L. (1978) · Chemical Reviews · doi:10.1021/cr60316a001 · Cited by 759
Arashiba, K., Miyake, Y., & Nishibayashi, Y. (2011) · Nature Chemistry · doi:10.1038/nchem.906 · Cited by 745
Self-citation
Cited by
Catalysts for nitrogen reduction to ammonia
Foster, S. L., Bakovic, S. I. P., Duda, R. D., Maheshwari, S., Milton, R. D., Minteer, S. D., Janik, M. J., Renner, J. N., & Greenlee, L. F. (2018) · Nature Catalysis · doi:10.1038/s41929-018-0092-7 · Cited by 1,633
Zhao, J., & Chen, Z. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b05213 · Cited by 1,249
Electro- and Solar-Driven Fuel Synthesis with First Row Transition Metal Complexes
Dalle, K. E., Warnan, J., Leung, J. J., Reuillard, B., Karmel, I. S., & Reisner, E. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00392 · Cited by 912
Liu, H.-M., Han, S.-H., Zhao, Y., Zhu, Y.-Y., Tian, X.-L., Zeng, J.-H., Jiang, J.-X., Xia, B. Y., & Chen, Y. (2018) · Journal of Materials Chemistry A · doi:10.1039/c7ta10866d · Cited by 409
Eizawa, A., Arashiba, K., Tanaka, H., Kuriyama, S., Matsuo, Y., Nakajima, K., Yoshizawa, K., & Nishibayashi, Y. (2017) · Nature Communications · doi:10.1038/ncomms14874 · Cited by 257
Self-citation
Metadata
- Authors
- Kuriyama, S., Arashiba, K., Nakajima, K., Matsuo, Y., Tanaka, H., Ishii, K., Yoshizawa, K., & Nishibayashi, Y.
- Venue
- Nature Communications
- Published
- 2016-07-20
- Volume
- 7
- Issue
- 1
- Pages
- 12181-12181
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W2499262475
- Cited by
- 294
- References
- 33
- FWCI
- 19.60
- Type
- journal article
- Language
- en
- Open access
- gold
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Catalytic transformation of dinitrogen into ammonia and hydrazine by iron-dinitrogen complexes bearing pincer ligand. https://app.cochat.ai/papers/10.1038/ncomms12181
- The paper
- Kuriyama, S., Arashiba, K., Nakajima, K., Matsuo, Y., Tanaka, H., Ishii, K., Yoshizawa, K., & Nishibayashi, Y. (2016). Catalytic transformation of dinitrogen into ammonia and hydrazine by iron-dinitrogen complexes bearing pincer ligand. Nature Communications. https://doi.org/10.1038/ncomms12181
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
