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Cited by 281

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Photo-induced enhanced Raman spectroscopy for universal ultra-trace detection of explosives, pollutants and biomolecules

Open access
Ben-Jaber, Sultan, Peveler, William J., Quesada-Cabrera, Raul, Cortés, Emiliano, Sotelo-Vazquez, Carlos, Abdul-Karim, Nadia, Maier, Stefan A., Parkin, Ivan P.·2016·Nature Communications

Abstract

Surface-enhanced Raman spectroscopy is one of the most sensitive spectroscopic techniques available, with single-molecule detection possible on a range of noble-metal substrates. It is widely used to detect molecules that have a strong Raman response at very low concentrations. Here we present photo-induced-enhanced Raman spectroscopy, where the combination of plasmonic nanoparticles with a photo-activated substrate gives rise to large signal enhancement (an order of magnitude) for a wide range of small molecules, even those with a typically low Raman cross-section. We show that the induced chemical enhancement is due to increased electron density at the noble-metal nanoparticles, and demonstrate the universality of this system with explosives, biomolecules and organic dyes, at trace levels. Our substrates are also easy to fabricate, self-cleaning and reusable.

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Crossref · 10.1038/ncomms12189

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Metadata

Authors
Ben-Jaber, S., Peveler, W. J., Quesada-Cabrera, R., Cortés, E., Sotelo-Vazquez, C., Abdul-Karim, N., Maier, S. A., & Parkin, I. P.
Venue
Nature Communications
Published
2016-07-14
Volume
7
Issue
1
Pages
12189-12189
ISSN
2041-1723 (ISSN-L)
OpenAlex
W2472474602
Cited by
281
References
1
FWCI
7.49
Type
journal article
Language
en
Open access
gold

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