The DOI matches its Crossref record; 5 of the 5 references it cites were found in a registry or an index.
Metallic tin quantum sheets confined in graphene toward high-efficiency carbon dioxide electroreduction
Open accessAbstract
Ultrathin metal layers can be highly active carbon dioxide electroreduction catalysts, but may also be prone to oxidation. Here we construct a model of graphene confined ultrathin layers of highly reactive metals, taking the synthetic highly reactive tin quantum sheets confined in graphene as an example. The higher electrochemical active area ensures 9 times larger carbon dioxide adsorption capacity relative to bulk tin, while the highly-conductive graphene favours rate-determining electron transfer from carbon dioxide to its radical anion. The lowered tin–tin coordination numbers, revealed by X-ray absorption fine structure spectroscopy, enable tin quantum sheets confined in graphene to efficiently stabilize the carbon dioxide radical anion, verified by 0.13 volts lowered potential of hydroxyl ion adsorption compared with bulk tin. Hence, the tin quantum sheets confined in graphene show enhanced electrocatalytic activity and stability. This work may provide a promising lead for designing efficient and robust catalysts for electrolytic fuel synthesis.
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Li, C. W., & Kanan, M. W. (2012) · Journal of the American Chemical Society · doi:10.1021/ja3010978 · Cited by 2,000
Partially oxidized atomic cobalt layers for carbon dioxide electroreduction to liquid fuel
Gao, S., Lin, Y., Jiao, X., Sun, Y., Luo, Q., Zhang, W., Li, D., Yang, J., & Xie, Y. (2016) · Nature · doi:10.1038/nature16455 · Cited by 1,865
Self-citationElectroreduction of carbon monoxide to liquid fuel on oxide-derived nanocrystalline copper
Li, C. W., Ciston, J., & Kanan, M. W. (2014) · Nature · doi:10.1038/nature13249 · Cited by 1,728
Ionic Liquid–Mediated Selective Conversion of CO 2 to CO at Low Overpotentials
Rosen, B. A., Salehi-Khojin, A., Thorson, M. R., Zhu, W., Whipple, D. T., Kenis, P. J. A., & Masel, R. I. (2011) · Science · doi:10.1126/science.1209786 · Cited by 1,558
Deng, J., Ren, P., Deng, D., & Bao, X. (2015) · Angewandte Chemie International Edition · doi:10.1002/anie.201409524 · Cited by 1,314
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Electrocatalysis for CO 2 conversion: from fundamentals to value-added products
Wang, G., Chen, J., Ding, Y., Cai, P., Yi, L., Li, Y., Tu, C., Hou, Y., Wen, Z., & Dai, L. (2021) · Chemical Society Reviews · doi:10.1039/d0cs00071j · Cited by 1,295
Fundamentals and challenges of electrochemical CO2 reduction using two-dimensional materials
Sun, Z., Ma, T., Tao, H., Fan, Q., & Han, B. (2017) · Chem · doi:10.1016/j.chempr.2017.09.009 · Cited by 1,224
Wang, X., Chen, Z., Zhao, X., Yao, T., Chen, W., You, R., Zhao, C., Wu, G., Wang, J., Huang, W., et al. (2018) · Angewandte Chemie International Edition · doi:10.1002/anie.201712451 · Cited by 1,120
Self-citationCO2 Reduction: From the Electrochemical to Photochemical Approach
Wu, J., Huang, Y., Ye, W., & Li, Y. (2017) · Advanced Science · doi:10.1002/advs.201700194 · Cited by 937
Han, N., Wang, Y., Yang, H., Deng, J., Wu, J., Li, Y., & Li, Y. (2018) · Nature Communications · doi:10.1038/s41467-018-03712-z · Cited by 914
Metadata
- Authors
- Lei, F., Liu, W., Sun, Y., Xu, J., Liu, K., Liang, L., Yao, T., Pan, B., Wei, S., & Xie, Y.
- Venue
- Nature Communications
- Published
- 2016-09-02
- Volume
- 7
- Issue
- 1
- Pages
- 12697-12697
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W2507854244
- Cited by
- 675
- References
- 5
- FWCI
- 16.81
- Type
- journal article
- Language
- en
- Open access
- gold
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