The DOI matches its Crossref record; 30 of the 30 references it cites were found in a registry or an index.
Hydroxyl radical-induced formation of highly oxidized organic compounds
Open accessAbstract
Explaining the formation of secondary organic aerosol is an intriguing question in atmospheric sciences because of its importance for Earth’s radiation budget and the associated effects on health and ecosystems. A breakthrough was recently achieved in the understanding of secondary organic aerosol formation from ozone reactions of biogenic emissions by the rapid formation of highly oxidized multifunctional organic compounds via autoxidation. However, the important daytime hydroxyl radical reactions have been considered to be less important in this process. Here we report measurements on the reaction of hydroxyl radicals with α- and β-pinene applying improved mass spectrometric methods. Our laboratory results prove that the formation of highly oxidized products from hydroxyl radical reactions proceeds with considerably higher yields than previously reported. Field measurements support these findings. Our results allow for a better description of the diurnal behaviour of the highly oxidized product formation and subsequent secondary organic aerosol formation in the atmosphere.
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Cites
The formation, properties and impact of secondary organic aerosol: current and emerging issues
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Self-citationA large source of low-volatility secondary organic aerosol
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Self-citationFast solvent screening via quantum chemistry: COSMO‐RS approach
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Kulmala, M., Kontkanen, J., Junninen, H., Lehtipalo, K., Manninen, H. E., Nieminen, T., Petäjä, T., Sipilä, M., Schobesberger, S., Rantala, P., et al. (2013) · Science · doi:10.1126/science.1227385 · Cited by 1,197
Self-citationSecondary organic aerosol formation from anthropogenic air pollution: Rapid and higher than expected
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Global data set of biogenic VOC emissions calculated by the MEGAN model over the last 30 years
Sindelarova, K., Granier, C., Bouarar, I., Guenther, A., Tilmes, S., Stavrakou, T., Müller, J.-F., Kuhn, U., Stefani, P., & Knorr, W. (2014) · Atmospheric Chemistry and Physics · doi:10.5194/acp-14-9317-2014 · Cited by 1,147
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Autoxidation of Organic Compounds in the Atmosphere
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Self-citationOrganic peroxy radicals: Kinetics, spectroscopy and tropospheric chemistry
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Cited by
Bianchi, F., Kurtén, T., Riva, M., Mohr, C., Rissanen, M. P., Roldin, P., Berndt, T., Crounse, J. D., Wennberg, P. O., Mentel, T. F., et al. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00395 · Cited by 1,084
Self-citationWang, L., Li, B., Dionysiou, D. D., Chen, B., Yang, J., & Li, J. (2022) · Environmental Science & Technology · doi:10.1021/acs.est.1c03796 · Cited by 328
Schwantes, R. H., Emmons, L. K., Orlando, J. J., Barth, M. C., Tyndall, G. S., Hall, S. R., Ullmann, K., St. Clair, J. M., Blake, D. R., Wisthaler, A., et al. (2020) · Atmospheric Chemistry and Physics · doi:10.5194/acp-20-3739-2020 · Cited by 112
Metadata
- Authors
- Berndt, T., Richters, S., Jokinen, T., Hyttinen, N., Kurtén, T., Otkjær, R. V., Kjaergaard, H. G., Stratmann, F., Herrmann, H., Sipilä, M., Kulmala, M., & Ehn, M.
- Venue
- Nature Communications
- Published
- 2016-12-02
- Volume
- 7
- Issue
- 1
- Pages
- 13677-13677
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W2559481487
- Cited by
- 316
- References
- 30
- FWCI
- 13.28
- Type
- journal article
- Language
- en
- Open access
- gold
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- Berndt, T., Richters, S., Jokinen, T., Hyttinen, N., Kurtén, T., Otkjær, R. V., Kjaergaard, H. G., Stratmann, F., Herrmann, H., Sipilä, M., Kulmala, M., & Ehn, M. (2016). Hydroxyl radical-induced formation of highly oxidized organic compounds. Nature Communications. https://doi.org/10.1038/ncomms13677
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