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Unravelling exceptional acetylene and carbon dioxide adsorption within a tetra-amide functionalized metal-organic framework
Open accessAbstract
Understanding the mechanism of gas-sorbent interactions is of fundamental importance for the design of improved gas storage materials. Here we report the binding domains of carbon dioxide and acetylene in a tetra-amide functionalized metal-organic framework, MFM-188, at crystallographic resolution. Although exhibiting moderate porosity, desolvated MFM-188a exhibits exceptionally high carbon dioxide and acetylene adsorption uptakes with the latter (232 cm 3 g−1 at 295 K and 1 bar) being the highest value observed for porous solids under these conditions to the best of our knowledge. Neutron diffraction and inelastic neutron scattering studies enable the direct observation of the role of amide groups in substrate binding, representing an example of probing gas-amide binding interactions by such experiments. This study reveals that the combination of polyamide groups, open metal sites, appropriate pore geometry and cooperative binding between guest molecules is responsible for the high uptakes of acetylene and carbon dioxide in MFM-188a.
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Cites
Crystal structure refinement with SHELXL
Sheldrick, G. M. (2015) · Acta Crystallographica Section C Structural Chemistry · doi:10.1107/s2053229614024218 · Cited by 43,982
He, Y., Krishna, R., & Chen, B. (2012) · Energy & Environmental Science · doi:10.1039/c2ee22858k · Cited by 674
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Li, H., Li, L., Lin, R.-B., Zhou, W., Zhang, Z., Xiang, S., & Chen, B. (2019) · EnergyChem · doi:10.1016/j.enchem.2019.100006 · Cited by 891
Optimized Separation of Acetylene from Carbon Dioxide and Ethylene in a Microporous Material
Lin, R.-B., Li, L., Wu, H., Arman, H., Li, B., Lin, R.-G., Zhou, W., & Chen, B. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b03850 · Cited by 559
Ye, Y., Xian, S., Cui, H., Tan, K., Gong, L., Liang, B., Pham, T., Pandey, H., Krishna, R., Lan, P. C., et al. (2022) · Journal of the American Chemical Society · doi:10.1021/jacs.1c10620 · Cited by 359
Linker functionalized metal-organic frameworks
Ali Akbar Razavi, S., & Morsali, A. (2019) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2019.213023 · Cited by 341
Recent advances in understanding Li–CO2 electrochemistry
Liu, B., Sun, Y., Liu, L., Chen, J., Yang, B., Xu, S., & Yan, X. (2019) · Energy & Environmental Science · doi:10.1039/c8ee03417f · Cited by 317
Metadata
- Authors
- Moreau, F., da Silva, I., Al Smail, N. H., Easun, T. L., Savage, M., Godfrey, H. G. W., Parker, S. F., Manuel, P., Yang, S., & Schröder, M.
- Venue
- Nature Communications
- Published
- 2017-02-08
- Volume
- 8
- Issue
- 1
- Pages
- 14085-14085
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W2562779550
- Cited by
- 235
- References
- 2
- FWCI
- 10.65
- Type
- journal article
- Language
- en
- Open access
- gold
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- Moreau, F., da Silva, I., Al Smail, N. H., Easun, T. L., Savage, M., Godfrey, H. G. W., Parker, S. F., Manuel, P., Yang, S., & Schröder, M. (2017). Unravelling exceptional acetylene and carbon dioxide adsorption within a tetra-amide functionalized metal-organic framework. Nature Communications. https://doi.org/10.1038/ncomms14085
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