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Efficient electrical control of thin-film black phosphorus bandgap

Open access
Deng, Bingchen, Tran, Vy, Xie, Yujun, Jiang, Hao, Li, Cheng, Guo, Qiushi, Wang, Xiaomu, Tian, He, Koester, Steven J., Wang, Han, Cha, Judy J., Xia, Qiangfei, Yang, Li, Xia, Fengnian·2017·Nature Communications

Abstract

Recently rediscovered black phosphorus is a layered semiconductor with promising electronic and photonic properties. Dynamic control of its bandgap can allow for the exploration of new physical phenomena. However, theoretical investigations and photoemission spectroscopy experiments indicate that in its few-layer form, an exceedingly large electric field in the order of several volts per nanometre is required to effectively tune its bandgap, making the direct electrical control unfeasible. Here we reveal the unique thickness-dependent bandgap tuning properties in intrinsic black phosphorus, arising from the strong interlayer electronic-state coupling. Furthermore, leveraging a 10 nm-thick black phosphorus, we continuously tune its bandgap from ∼300 to below 50 meV, using a moderate displacement field up to 1.1 V nm−1. Such dynamic tuning of bandgap may not only extend the operational wavelength range of tunable black phosphorus photonic devices, but also pave the way for the investigation of electrically tunable topological insulators and semimetals.

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Crossref · 10.1038/ncomms14474

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Metadata

Authors
Deng, B., Tran, V., Xie, Y., Jiang, H., Li, C., Guo, Q., Wang, X., Tian, H., Koester, S. J., Wang, H., Cha, J. J., Xia, Q., Yang, L., & Xia, F.
Venue
Nature Communications
Published
2017-04-19
Volume
8
Issue
1
Pages
14474-14474
ISSN
2041-1723 (ISSN-L)
OpenAlex
W2590602300
Cited by
347
References
7
FWCI
16.03
Type
journal article
Language
en
Open access
gold

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CoChat. (2026). Citation check: Efficient electrical control of thin-film black phosphorus bandgap. https://app.cochat.ai/papers/10.1038/ncomms14474
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Deng, B., Tran, V., Xie, Y., Jiang, H., Li, C., Guo, Q., Wang, X., Tian, H., Koester, S. J., Wang, H., Cha, J. J., Xia, Q., Yang, L., & Xia, F. (2017). Efficient electrical control of thin-film black phosphorus bandgap. Nature Communications. https://doi.org/10.1038/ncomms14474

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