The DOI matches its Crossref record; 11 of the 11 references it cites were found in a registry or an index.
Amorphous nickel-cobalt complexes hybridized with 1T-phase molybdenum disulfide via hydrazine-induced phase transformation for water splitting
Open accessAbstract
Highly active and robust eletcrocatalysts based on earth-abundant elements are desirable to generate hydrogen and oxygen as fuels from water sustainably to replace noble metal materials. Here we report an approach to synthesize porous hybrid nanostructures combining amorphous nickel-cobalt complexes with 1T phase molybdenum disulfide (MoS 2) via hydrazine-induced phase transformation for water splitting. The hybrid nanostructures exhibit overpotentials of 70 mV for hydrogen evolution and 235 mV for oxygen evolution at 10 mA cm−2 with long-term stability, which have superior kinetics for hydrogen- and oxygen-evolution with Tafel slope values of 38.1 and 45.7 mV dec−1. Moreover, we achieve 10 mA cm−2 at a low voltage of 1.44 V for 48 h in basic media for overall water splitting. We propose that such performance is likely due to the complete transformation of MoS 2 to metallic 1T phase, high porosity and stabilization effect of nickel-cobalt complexes on 1T phase MoS 2.
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Cites
Opportunities and challenges for a sustainable energy future
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Identification of Active Edge Sites for Electrochemical H 2 Evolution from MoS 2 Nanocatalysts
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Design of electrocatalysts for oxygen- and hydrogen-involving energy conversion reactions
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Computational high-throughput screening of electrocatalytic materials for hydrogen evolution
Greeley, J., Jaramillo, T. F., Bonde, J., Chorkendorff, I., & Nørskov, J. K. (2006) · Nature Materials · doi:10.1038/nmat1752 · Cited by 4,097
Kibsgaard, J., Chen, Z., Reinecke, B. N., & Jaramillo, T. F. (2012) · Nature Materials · doi:10.1038/nmat3439 · Cited by 3,234
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Highly Active Electrocatalysis of the Hydrogen Evolution Reaction by Cobalt Phosphide Nanoparticles
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Low Overpotential in Vacancy-Rich Ultrathin CoSe2 Nanosheets for Water Oxidation
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Cited by
Recent Advances in Electrocatalytic Hydrogen Evolution Using Nanoparticles
Zhu, J., Hu, L., Zhao, P., Lee, L. Y. S., & Wong, K.-Y. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00248 · Cited by 3,133
Li, H., Chen, S., Zhang, Y., Zhang, Q., Jia, X., Zhang, Q., Gu, L., Sun, X., Song, L., & Wang, X. (2018) · Nature Communications · doi:10.1038/s41467-018-04888-0 · Cited by 613
Self-citationRecent Development of Metallic (1T) Phase of Molybdenum Disulfide for Energy Conversion and Storage
Lei, Z., Zhan, J., Tang, L., Zhang, Y., & Wang, Y. (2018) · Advanced Energy Materials · doi:10.1002/aenm.201703482 · Cited by 485
Ultrathinning Nickel Sulfide with Modulated Electron Density for Efficient Water Splitting
Fei, B., Chen, Z., Liu, J., Xu, H., Yan, X., Qing, H., Chen, M., & Wu, R. (2020) · Advanced Energy Materials · doi:10.1002/aenm.202001963 · Cited by 372
Zheng, J., Chen, X., Zhong, X., Li, S., Liu, T., Zhuang, G., Li, X., Deng, S., Mei, D., & Wang, J. (2017) · Advanced Functional Materials · doi:10.1002/adfm.201704169 · Cited by 357
Metadata
- Authors
- Li, H., Chen, S., Jia, X., Xu, B., Lin, H., Yang, H., Song, L., & Wang, X.
- Venue
- Nature Communications
- Published
- 2017-05-09
- Volume
- 8
- Issue
- 1
- Pages
- 15377-15377
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W2613038737
- Cited by
- 362
- References
- 11
- FWCI
- 12.45
- Type
- journal article
- Language
- en
- Open access
- gold
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- Li, H., Chen, S., Jia, X., Xu, B., Lin, H., Yang, H., Song, L., & Wang, X. (2017). Amorphous nickel-cobalt complexes hybridized with 1T-phase molybdenum disulfide via hydrazine-induced phase transformation for water splitting. Nature Communications. https://doi.org/10.1038/ncomms15377
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