The DOI matches its Crossref record; 47 of the 47 references it cites were found in a registry or an index.
Mesoporous metallic rhodium nanoparticles
Open accessAbstract
Mesoporous noble metals are an emerging class of cutting-edge nanostructured catalysts due to their abundant exposed active sites and highly accessible surfaces. Although various noble metal (e.g. Pt, Pd and Au) structures have been synthesized by hard- and soft-templating methods, mesoporous rhodium (Rh) nanoparticles have never been generated via chemical reduction, in part due to the relatively high surface energy of rhodium (Rh) metal. Here we describe a simple, scalable route to generate mesoporous Rh by chemical reduction on polymeric micelle templates [poly(ethylene oxide)-b-poly(methyl methacrylate) (PEO-b-PMMA)]. The mesoporous Rh nanoparticles exhibited a ∼2.6 times enhancement for the electrocatalytic oxidation of methanol compared to commercially available Rh catalyst. Surprisingly, the high surface area mesoporous structure of the Rh catalyst was thermally stable up to 400 °C. The combination of high surface area and thermal stability also enables superior catalytic activity for the remediation of nitric oxide (NO) in lean-burn exhaust containing high concentrations of O 2.
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Cites
Highly Crystalline Multimetallic Nanoframes with Three-Dimensional Electrocatalytic Surfaces
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A facile soft-template synthesis of mesoporous polymeric and carbonaceous nanospheres
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Cited by
Zhang, H., An, P., Zhou, W., Guan, B. Y., Zhang, P., Dong, J., & Lou, X. W. (. (2018) · Science Advances · doi:10.1126/sciadv.aao6657 · Cited by 584
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Self-citationLi, C., Tan, H., Lin, J., Luo, X., Wang, S., You, J., Kang, Y.-M., Bando, Y., Yamauchi, Y., & Kim, J. (2018) · Nano Today · doi:10.1016/j.nantod.2018.06.005 · Cited by 336
Self-citationKang, Y., Tang, Y., Zhu, L., Jiang, B., Xu, X., Guselnikova, O., Li, H., Asahi, T., & Yamauchi, Y. (2022) · ACS Catalysis · doi:10.1021/acscatal.2c03480 · Cited by 107
Self-citationGold–Rhodium Nanoflowers for the Plasmon-Enhanced Hydrogen Evolution Reaction under Visible Light
Rodrigues, M. P. D. S., Dourado, A. H. B., Cutolo, L. D. O., Parreira, L. S., Alves, T. V., Slater, T. J. A., Haigh, S. J., Camargo, P. H. C., & Cordoba de Torresi, S. I. (2021) · ACS Catalysis · doi:10.1021/acscatal.1c02938 · Cited by 80
Metadata
- Authors
- Jiang, B., Li, C., Dag, Ö., Abe, H., Takei, T., Imai, T., Hossain, M. S. A., Islam, M. T., Wood, K., Henzie, J., & Yamauchi, Y.
- Venue
- Nature Communications
- Published
- 2017-05-19
- Volume
- 8
- Issue
- 1
- Pages
- 15581-15581
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W2616200183
- Cited by
- 257
- References
- 47
- FWCI
- 12.31
- Type
- journal article
- Language
- en
- Open access
- gold
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- Jiang, B., Li, C., Dag, Ö., Abe, H., Takei, T., Imai, T., Hossain, M. S. A., Islam, M. T., Wood, K., Henzie, J., & Yamauchi, Y. (2017). Mesoporous metallic rhodium nanoparticles. Nature Communications. https://doi.org/10.1038/ncomms15581
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