The DOI matches its Crossref record; 29 of the 29 references it cites were found in a registry or an index.
Efficient and tunable white-light emission of metal–organic frameworks by iridium-complex encapsulation
Open accessAbstract
Metal–organic frameworks (MOFs) are well known for their tunable structure and porosity. Many studies have shown they are promising for various important applications, for which their performance can be further enhanced by encapsulating functional species, such as luminescent guest molecules, within the frameworks. Although numerous MOFs are luminescent, very few emit white light and their quantum yield is usually low. Here we report a strategy to achieve efficient white-light emission by encapsulating an iridium complex in the MOF cavity. A mesoporous blue-emitting MOF is prepared as host to encapsulate a yellow-emitting iridium complex, [Ir(ppy)2(bpy)]+. The resultant composites emit bright white light with good colour quality (for example, Commission International de I’Eclairage coordinates, colour-rendering index and correlated colour temperature of (0.31, 0.33), 84.5 and 5409 K, respectively), and high quantum yield up to 115 °C. This strategy may open new perspectives for developing high-performance energy-saving solid-state lighting materials. Although many metal–organic frameworks are luminescent, few are capable of white-light emission. Here, the authors incorporate a yellow-emitting guest molecule into the cavities of a blue-emitting metal–organic framework, and tune the composition to emit white light with relatively high quantum yield.
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Cites
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Cited by
Metal–organic frameworks based on flexible ligands (FL-MOFs): structures and applications
Lin, Z.-J., Lü, J., Hong, M., & Cao, R. (2014) · Chem. Soc. Rev. · doi:10.1039/c3cs60483g · Cited by 874
MOF positioning technology and device fabrication
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Mercury nano-trap for effective and efficient removal of mercury(II) from aqueous solution
Li, B., Zhang, Y., Ma, D., Shi, Z., & Ma, S. (2014) · Nature Communications · doi:10.1038/ncomms6537 · Cited by 587
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Metadata
- Authors
- Sun, C.-Y., Wang, X.-L., Zhang, X., Qin, C., Li, P., Su, Z.-M., Zhu, D.-X., Shan, G.-G., Shao, K.-Z., Wu, H., & Li, J.
- Venue
- Nature Communications
- Published
- 2013-11-11
- Volume
- 4
- Issue
- 1
- Pages
- 2717-2717
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W2027133178
- Cited by
- 573
- References
- 29
- FWCI
- 26.87
- Type
- journal article
- Language
- en
- Open access
- hybrid
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