The DOI matches its Crossref record; 38 of the 38 references it cites were found in a registry or an index.
Efficient hole-blocking layer-free planar halide perovskite thin-film solar cells
Open accessAbstract
Efficient lead halide perovskite solar cells use hole-blocking layers to help collection of photogenerated electrons and to achieve high open-circuit voltages. Here, we report the realization of efficient perovskite solar cells grown directly on fluorine-doped tin oxide-coated substrates without using any hole-blocking layers. With ultraviolet–ozone treatment of the substrates, a planar Au/hole-transporting material/CH3NH3PbI3-xClx/substrate cell processed by a solution method has achieved a power conversion efficiency of over 14% and an open-circuit voltage of 1.06 V measured under reverse voltage scan. The open-circuit voltage is as high as that of our best reference cell with a TiO2 hole-blocking layer. Besides ultraviolet–ozone treatment, we find that involving Cl in the synthesis is another key for realizing high open-circuit voltage perovskite solar cells without hole-blocking layers. Our results suggest that TiO2 may not be the ultimate interfacial material for achieving high-performance perovskite solar cells. Lead halide perovskite solar cells use hole-blocking layers to allow a separate collection of positive and negative charge carriers and to achieve high-operation voltages. Here, the authors demonstrate efficient lead halide perovskite solar cells that avoid using this extra layer.
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Cites
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Cited by
Ke, W., Xiao, C., Wang, C., Saparov, B., Duan, H., Zhao, D., Xiao, Z., Schulz, P., Harvey, S. P., Liao, W., et al. (2016) · Advanced Materials · doi:10.1002/adma.201600594 · Cited by 579
Self-citation“Unleaded” Perovskites: Status Quo and Future Prospects of Tin‐Based Perovskite Solar Cells
Ke, W., Stoumpos, C. C., & Kanatzidis, M. G. (2019) · Advanced Materials · doi:10.1002/adma.201803230 · Cited by 533
Self-citationFlexible Perovskite Solar Cells
Jung, H. S., Han, G. S., Park, N.-G., & Ko, M. J. (2019) · Joule · doi:10.1016/j.joule.2019.07.023 · Cited by 449
Device stability of perovskite solar cells – A review
Asghar, M. I., Zhang, J., Wang, H., & Lund, P. D. (2017) · Renewable and Sustainable Energy Reviews · doi:10.1016/j.rser.2017.04.003 · Cited by 423
Huang, L., Sun, X., Li, C., Xu, R., Xu, J., Du, Y., Wu, Y., Ni, J., Cai, H., Li, J., et al. (2016) · Solar Energy Materials and Solar Cells · doi:10.1016/j.solmat.2016.08.025 · Cited by 267
Metadata
- Authors
- Ke, W., Fang, G., Wan, J., Tao, H., Liu, Q., Xiong, L., Qin, P., Wang, J., Lei, H., Yang, G., Qin, M., Zhao, X., & Yan, Y.
- Venue
- Nature Communications
- Published
- 2015-03-23
- Volume
- 6
- Issue
- 1
- Pages
- 6700-6700
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W2102140268
- Cited by
- 420
- References
- 38
- FWCI
- 34.00
- Type
- journal article
- Language
- en
- Open access
- gold
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- Ke, W., Fang, G., Wan, J., Tao, H., Liu, Q., Xiong, L., Qin, P., Wang, J., Lei, H., Yang, G., Qin, M., Zhao, X., & Yan, Y. (2015). Efficient hole-blocking layer-free planar halide perovskite thin-film solar cells. Nature Communications. https://doi.org/10.1038/ncomms7700
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