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Two-dimensional gold nanostructures with high activity for selective oxidation of carbon–hydrogen bonds
Open accessAbstract
Efficient synthesis of stable two-dimensional (2D) noble metal catalysts is a challenging topic. Here we report the facile synthesis of 2D gold nanosheets via a wet chemistry method, by using layered double hydroxide as the template. Detailed characterization with electron microscopy and X-ray photoelectron spectroscopy demonstrates that the nanosheets are negatively charged and [001] oriented with thicknesses varying from single to a few atomic layers. X-ray absorption spectroscopy reveals unusually low gold–gold coordination numbers. These gold nanosheets exhibit high catalytic activity and stability in the solvent-free selective oxidation of carbon–hydrogen bonds with molecular oxygen.
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Cites
Identification of Active Edge Sites for Electrochemical H 2 Evolution from MoS 2 Nanocatalysts
Jaramillo, T. F., Jørgensen, K. P., Bonde, J., Nielsen, J. H., Horch, S., & Chorkendorff, I. (2007) · Science · doi:10.1126/science.1141483 · Cited by 6,100
MoS 2 Nanoparticles Grown on Graphene: An Advanced Catalyst for the Hydrogen Evolution Reaction
Li, Y., Wang, H., Xie, L., Liang, Y., Hong, G., & Dai, H. (2011) · Journal of the American Chemical Society · doi:10.1021/ja201269b · Cited by 5,001
Kibsgaard, J., Chen, Z., Reinecke, B. N., & Jaramillo, T. F. (2012) · Nature Materials · doi:10.1038/nmat3439 · Cited by 3,234
Xiang, Q., Yu, J., & Jaroniec, M. (2012) · Journal of the American Chemical Society · doi:10.1021/ja302846n · Cited by 2,360
Chen, Z., Cummins, D., Reinecke, B. N., Clark, E., Sunkara, M. K., & Jaramillo, T. F. (2011) · Nano Letters · doi:10.1021/nl2020476 · Cited by 1,153
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Tyagi, D., Wang, H., Huang, W., Hu, L., Tang, Y., Guo, Z., Ouyang, Z., & Zhang, H. (2020) · Nanoscale · doi:10.1039/c9nr10178k · Cited by 508
Metallenes as functional materials in electrocatalysis
Prabhu, P., & Lee, J.-M. (2021) · Chemical Society Reviews · doi:10.1039/d0cs01041c · Cited by 427
Single-Atom (Iron-Based) Catalysts: Synthesis and Applications
Singh, B., Gawande, M. B., Kute, A. D., Varma, R. S., Fornasiero, P., McNeice, P., Jagadeesh, R. V., Beller, M., & Zbořil, R. (2021) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00158 · Cited by 373
Hierarchical Core–Shell Al2O3@Pd-CoAlO Microspheres for Low-Temperature Toluene Combustion
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Metadata
- Authors
- Wang, L., Zhu, Y., Wang, J.-Q., Liu, F., Huang, J., Meng, X., Basset, J.-M., Han, Y., & Xiao, F.-S.
- Venue
- Nature Communications
- Published
- 2015-04-22
- Volume
- 6
- Issue
- 1
- Pages
- 6957-6957
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W2086037293
- Cited by
- 193
- References
- 5
- FWCI
- 5.86
- Type
- journal article
- Language
- en
- Open access
- gold
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