The DOI matches its Crossref record; 4 of the 4 references it cites were found in a registry or an index.
Phase and composition controllable synthesis of cobalt manganese spinel nanoparticles towards efficient oxygen electrocatalysis
Open accessAbstract
Spinel-type oxides are technologically important in many fields, including electronics, magnetism, catalysis and electrochemical energy storage and conversion. Typically, these materials are prepared by conventional ceramic routes that are energy consuming and offer limited control over shape and size. Moreover, for mixed-metal oxide spinels (for example, CoxMn 3−xO 4), the crystallographic phase sensitively correlates with the metal ratio, posing great challenges to synthesize active product with simultaneously tuned phase and composition. Here we report a general synthesis of ultrasmall cobalt manganese spinels with tailored structural symmetry and composition through facile solution-based oxidation–precipitation and insertion–crystallization process at modest condition. As an example application, the nanocrystalline spinels catalyse the oxygen reduction/evolution reactions, showing phase and composition co-dependent performance. Furthermore, the mild synthetic strategy allows the formation of homogeneous and strongly coupled spinel/carbon nanocomposites, which exhibit comparable activity but superior durability to Pt/C and serve as efficient catalysts to build rechargeable Zn–air and Li–air batteries.
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Cites
Li-O2 and Li-S batteries with high energy storage
Bruce, P. G., Freunberger, S. A., Hardwick, L. J., & Tarascon, J.-M. (2012) · Nature Materials · doi:10.1038/nmat3191 · Cited by 9,479
Electrocatalyst approaches and challenges for automotive fuel cells
Debe, M. K. (2012) · Nature · doi:10.1038/nature11115 · Cited by 5,885
Alloys of platinum and early transition metals as oxygen reduction electrocatalysts
Greeley, J., Stephens, I. E. L., Bondarenko, A. S., Johansson, T. P., Hansen, H. A., Jaramillo, T. F., Rossmeisl, J., Chorkendorff, I., & Nørskov, J. K. (2009) · Nature Chemistry · doi:10.1038/nchem.367 · Cited by 3,203
Highly Crystalline Multimetallic Nanoframes with Three-Dimensional Electrocatalytic Surfaces
Chen, C., Kang, Y., Huo, Z., Zhu, Z., Huang, W., Xin, H. L., Snyder, J. D., Li, D., Herron, J. A., Mavrikakis, M., et al. (2014) · Science · doi:10.1126/science.1249061 · Cited by 2,765
Self-citation
Cited by
Chatenet, M., Pollet, B. G., Dekel, D. R., Dionigi, F., Deseure, J., Millet, P., Braatz, R. D., Bazant, M. Z., Eikerling, M., Staffell, I., et al. (2022) · Chemical Society Reviews · doi:10.1039/d0cs01079k · Cited by 2,025
Bifunctional Electrocatalysts for Overall and Hybrid Water Splitting
Quan, L., Jiang, H., Mei, G., Sun, Y., & You, B. (2024) · Chemical Reviews · doi:10.1021/acs.chemrev.3c00332 · Cited by 874
Huang, Z., Wang, J., Peng, Y., Jung, C., Fisher, A., & Wang, X. (2017) · Advanced Energy Materials · doi:10.1002/aenm.201700544 · Cited by 835
Electrocatalysis in Alkaline Media and Alkaline Membrane-Based Energy Technologies
Yang, Y., Peltier, C. R., Zeng, R., Schimmenti, R., Li, Q., Huang, X., Yan, Z., Potsi, G., Selhorst, R., Lu, X., et al. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00331 · Cited by 544
Wang, Q., Shang, L., Shi, R., Zhang, X., Zhao, Y., Waterhouse, G. I. N., Wu, L., Tung, C., & Zhang, T. (2017) · Advanced Energy Materials · doi:10.1002/aenm.201700467 · Cited by 508
Metadata
- Authors
- Li, C., Han, X., Cheng, F., Hu, Y., Chen, C., & Chen, J.
- Venue
- Nature Communications
- Published
- 2015-06-04
- Volume
- 6
- Issue
- 1
- Pages
- 7345-7345
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W2198128057
- Cited by
- 646
- References
- 4
- FWCI
- 20.92
- Type
- journal article
- Language
- en
- Open access
- gold
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