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Reversible adapting layer produces robust single-crystal electrocatalyst for oxygen evolution
Open accessAbstract
Electrochemically converting water into oxygen/hydrogen gas is ideal for high-density renewable energy storage in which robust electrocatalysts for efficient oxygen evolution play crucial roles. To date, however, electrocatalysts with long-term stability have remained elusive. Here we report that single-crystal Co 3 O 4 nanocube underlay with a thin CoO layer results in a high-performance and high-stability electrocatalyst in oxygen evolution reaction. An in situ X-ray diffraction method is developed to observe a strong correlation between the initialization of the oxygen evolution and the formation of active metal oxyhydroxide phase. The lattice of skin layer adapts to the structure of the active phase, which enables a reversible facile structural change that facilitates the chemical reactions without breaking the scaffold of the electrocatalysts. The single-crystal nanocube electrode exhibits stable, continuous oxygen evolution for >1,000 h. This robust stability is attributed to the complementary nature of defect-free single-crystal electrocatalyst and the reversible adapting layer.
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Cites
Benchmarking Heterogeneous Electrocatalysts for the Oxygen Evolution Reaction
McCrory, C. C. L., Jung, S., Peters, J. C., & Jaramillo, T. F. (2013) · Journal of the American Chemical Society · doi:10.1021/ja407115p · Cited by 7,026
Alternative energy technologies
Dresselhaus, M. S., & Thomas, I. L. (2001) · Nature · doi:10.1038/35104599 · Cited by 4,894
Universality in Oxygen Evolution Electrocatalysis on Oxide Surfaces
Man, I. C., Su, H., Calle‐Vallejo, F., Hansen, H. A., Martínez, J. I., Inoglu, N. G., Kitchin, J., Jaramillo, T. F., Nørskov, J. K., & Rossmeisl, J. (2011) · ChemCatChem · doi:10.1002/cctc.201000397 · Cited by 4,769
Water photolysis at 12.3% efficiency via perovskite photovoltaics and Earth-abundant catalysts
Luo, J., Im, J.-H., Mayer, M. T., Schreier, M., Nazeeruddin, M. K., Park, N.-G., Tilley, S. D., Fan, H. J., & Grätzel, M. (2014) · Science · doi:10.1126/science.1258307 · Cited by 2,509
Sun, Y., Liu, C., Grauer, D. C., Yano, J., Long, J. R., Yang, P., & Chang, C. J. (2013) · Journal of the American Chemical Society · doi:10.1021/ja4094764 · Cited by 556
Cited by
Electrocatalysis for the oxygen evolution reaction: recent development and future perspectives
Suen, N.-T., Hung, S.-F., Quan, Q., Zhang, N., Xu, Y.-J., & Chen, H. M. (2017) · Chemical Society Reviews · doi:10.1039/c6cs00328a · Cited by 6,307
Self-citationA review on fundamentals for designing oxygen evolution electrocatalysts
Song, J., Wei, C., Huang, Z.-F., Liu, C., Zeng, L., Wang, X., & Xu, Z. J. (2020) · Chemical Society Reviews · doi:10.1039/c9cs00607a · Cited by 2,936
Reier, T., Nong, H. N., Teschner, D., Schlögl, R., & Strasser, P. (2017) · Advanced Energy Materials · doi:10.1002/aenm.201601275 · Cited by 1,253
Bifunctional Electrocatalysts for Overall and Hybrid Water Splitting
Quan, L., Jiang, H., Mei, G., Sun, Y., & You, B. (2024) · Chemical Reviews · doi:10.1021/acs.chemrev.3c00332 · Cited by 874
Liu, Z., Cheng, H., Li, N., Ma, T. Y., & Su, Y. (2016) · Advanced Materials · doi:10.1002/adma.201506197 · Cited by 736
Metadata
- Authors
- Tung, C.-W., Hsu, Y.-Y., Shen, Y.-P., Zheng, Y., Chan, T.-S., Sheu, H.-S., Cheng, Y.-C., & Chen, H. M.
- Venue
- Nature Communications
- Published
- 2015-08-28
- Volume
- 6
- Issue
- 1
- Pages
- 8106-8106
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W2216647018
- Cited by
- 471
- References
- 5
- FWCI
- 11.73
- Type
- journal article
- Language
- en
- Open access
- gold
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- Tung, C.-W., Hsu, Y.-Y., Shen, Y.-P., Zheng, Y., Chan, T.-S., Sheu, H.-S., Cheng, Y.-C., & Chen, H. M. (2015). Reversible adapting layer produces robust single-crystal electrocatalyst for oxygen evolution. Nature Communications. https://doi.org/10.1038/ncomms9106
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