The DOI matches its Crossref record; 40 of the 40 references it cites were found in a registry or an index.
Liquid metal–organic frameworks
Open accessAbstract
Metal-organic frameworks (MOFs) are a family of chemically diverse materials, with applications in a wide range of fields, covering engineering, physics, chemistry, biology and medicine. Until recently, research has focused almost entirely on crystalline structures, yet now a clear trend is emerging, shifting the emphasis onto disordered states, including 'defective by design' crystals, as well as amorphous phases such as glasses and gels. Here we introduce a strongly associated MOF liquid, obtained by melting a zeolitic imidazolate framework. We combine in situ variable temperature X-ray, ex situ neutron pair distribution function experiments, and first-principles molecular dynamics simulations to study the melting phenomenon and the nature of the liquid obtained. We demonstrate from structural, dynamical, and thermodynamical information that the chemical configuration, coordinative bonding, and porosity of the parent crystalline framework survive upon formation of the MOF liquid.
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Cited by
Jiang, X., Zhang, L., Liu, S., Zhang, Y., He, Z., Li, W., Zhang, F., Shi, Y., Lü, W., Li, Y., et al. (2018) · Advanced Optical Materials · doi:10.1002/adom.201800561 · Cited by 336
Solution processable metal–organic frameworks for mixed matrix membranes using porous liquids
Knebel, A., Bavykina, A., Datta, S. J., Sundermann, L., Garzon-Tovar, L., Lebedev, Y., Durini, S., Ahmad, R., Kozlov, S. M., Shterk, G., et al. (2020) · Nature Materials · doi:10.1038/s41563-020-0764-y · Cited by 331
Carbon Capture Technologies: A Review on Technology Readiness Level
Hekmatmehr, H., Esmaeili, A., Pourmahdi, M., Atashrouz, S., Abedi, A., Ali Abuswer, M., Nedeljkovic, D., Latifi, M., Farag, S., & Mohaddespour, A. (2024) · Fuel · doi:10.1016/j.fuel.2024.130898 · Cited by 189
Metadata
- Authors
- Gaillac, R., Pullumbi, P., Beyer, K. A., Chapman, K. W., Keen, D. A., Bennett, T. D., & Coudert, F.-X.
- Venue
- Nature Materials
- Published
- 2017-10-09
- Volume
- 16
- Issue
- 11
- Pages
- 1149-1154
- ISSN
- 1476-1122 (ISSN-L)
- 1476-4660
- OpenAlex
- W2762651571
- Cited by
- 470
- References
- 40
- FWCI
- 12.89
- Type
- journal article
- Language
- en
- Open access
- green
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- Gaillac, R., Pullumbi, P., Beyer, K. A., Chapman, K. W., Keen, D. A., Bennett, T. D., & Coudert, F.-X. (2017). Liquid metal–organic frameworks. Nature Materials. https://doi.org/10.1038/nmat4998
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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