The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Rechargeable aqueous zinc-manganese dioxide batteries with high energy and power densities
Open accessAbstract
Although alkaline zinc-manganese dioxide batteries have dominated the primary battery applications, it is challenging to make them rechargeable. Here we report a high-performance rechargeable zinc-manganese dioxide system with an aqueous mild-acidic zinc triflate electrolyte. We demonstrate that the tunnel structured manganese dioxide polymorphs undergo a phase transition to layered zinc-buserite on first discharging, thus allowing subsequent intercalation of zinc cations in the latter structure. Based on this electrode mechanism, we formulate an aqueous zinc/manganese triflate electrolyte that enables the formation of a protective porous manganese oxide layer. The cathode exhibits a high reversible capacity of 225 mAh g−1 and long-term cyclability with 94% capacity retention over 2000 cycles. Remarkably, the pouch zinc-manganese dioxide battery delivers a total energy density of 75.2 Wh kg−1. As a result of the superior battery performance, the high safety of aqueous electrolyte, the facile cell assembly and the cost benefit of the source materials, this zinc-manganese dioxide system is believed to be promising for large-scale energy storage applications.
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Cites
Armand, M., & Tarascon, J.-M. (2008) · Nature · doi:10.1038/451652a · Cited by 19,612
“Water-in-salt” electrolyte enables high-voltage aqueous lithium-ion chemistries
Suo, L., Borodin, O., Gao, T., Olguin, M., Ho, J., Fan, X., Luo, C., Wang, C., & Xu, K. (2015) · Science · doi:10.1126/science.aab1595 · Cited by 3,821
Manganese oxide minerals: Crystal structures and economic and environmental significance
Post, J. E. (1999) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.96.7.3447 · Cited by 1,854
Cited by
Scientific Challenges for the Implementation of Zn-Ion Batteries
Blanc, L. E., Kundu, D., & Nazar, L. F. (2020) · Joule · doi:10.1016/j.joule.2020.03.002 · Cited by 2,113
Rechargeable Batteries for Grid Scale Energy Storage
Zhu, Z., Jiang, T., Ali, M., Meng, Y., Jin, Y., Cui, Y., & Chen, W. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.2c00289 · Cited by 1,769
Rechargeable Aqueous Zn–V2O5 Battery with High Energy Density and Long Cycle Life
Zhang, N., Dong, Y., Jia, M., Bian, X., Wang, Y., Qiu, M., Xu, J., Liu, Y., Jiao, L., & Cheng, F. (2018) · ACS Energy Letters · doi:10.1021/acsenergylett.8b00565 · Cited by 1,052
Self-citationA Metal-Organic Framework Host for Highly Reversible Dendrite-free Zinc Metal Anodes
Wang, Z., Huang, J., Guo, Z., Dong, X., Liu, Y., Wang, Y., & Xia, Y. (2019) · Joule · doi:10.1016/j.joule.2019.02.012 · Cited by 938
Expanded hydrated vanadate for high-performance aqueous zinc-ion batteries
Liu, C., Neale, Z., Zheng, J., Jia, X., Huang, J., Yan, M., Tian, M., Wang, M., Yang, J., & Cao, G. (2019) · Energy & Environmental Science · doi:10.1039/c9ee00956f · Cited by 804
Metadata
- Authors
- Zhang, N., Cheng, F., Liu, J., Wang, L., Long, X., Liu, X., Li, F., & Chen, J.
- Venue
- Nature Communications
- Published
- 2017-09-01
- Volume
- 8
- Issue
- 1
- Pages
- 405-405
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W2747631106
- Cited by
- 1,796
- References
- 3
- FWCI
- 60.97
- Type
- journal article
- Language
- en
- Open access
- gold
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