The DOI matches its Crossref record; 45 of the 45 references it cites were found in a registry or an index.
99TcO4− remediation by a cationic polymeric network
Open accessAbstract
Direct removal of 99 TcO 4− from the highly acidic solution of used nuclear fuel is highly beneficial for the recovery of uranium and plutonium and more importantly aids in the elimination of 99 Tc discharge into the environment. However, this task represents a huge challenge given the combined extreme conditions of super acidity, high ionic strength, and strong radiation field. Here we overcome this challenge using a cationic polymeric network with significant TcO 4− uptake capabilities in four aspects: the fastest sorption kinetics, the highest sorption capacity, the most promising uptake performance from highly acidic solutions, and excellent radiation-resistance and hydrolytic stability among all anion sorbent materials reported. In addition, this material is fully recyclable for multiple sorption/desorption trials, making it extremely attractive for waste partitioning and emergency remediation. The excellent TcO 4− uptake capability is elucidated by X-ray absorption spectroscopy, solid-state NMR measurement, and density functional theory analysis on anion coordination and bonding.
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Da, H.-J., Yang, C.-X., & Yan, X.-P. (2019) · Environmental Science & Technology · doi:10.1021/acs.est.8b06244 · Cited by 268
Sheng, D., Zhu, L., Dai, X., Xu, C., Li, P., Pearce, C. I., Xiao, C., Chen, J., Zhou, R., Duan, T., et al. (2019) · Angewandte Chemie International Edition · doi:10.1002/anie.201814640 · Cited by 267
Self-citationHao, M., Chen, Z., Yang, H., Waterhouse, G. I. N., Ma, S., & Wang, X. (2022) · Science Bulletin · doi:10.1016/j.scib.2022.02.012 · Cited by 161
Metadata
- Authors
- Li, J., Dai, X., Zhu, L., Xu, C., Zhang, D., Silver, M. A., Li, P., Chen, L., Li, Y., Zuo, D., Zhang, H., Xiao, C., Chen, J., Diwu, J., Farha, O. K., Albrecht-Schmitt, T. E., Chai, Z., & Wang, S.
- Venue
- Nature Communications
- Published
- 2018-08-01
- Volume
- 9
- Issue
- 1
- Pages
- 3007-3007
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W2883359628
- Cited by
- 361
- References
- 45
- FWCI
- 12.49
- Type
- journal article
- Language
- en
- Open access
- gold
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- Li, J., Dai, X., Zhu, L., Xu, C., Zhang, D., Silver, M. A., Li, P., Chen, L., Li, Y., Zuo, D., Zhang, H., Xiao, C., Chen, J., Diwu, J., Farha, O. K., Albrecht-Schmitt, T. E., Chai, Z., & Wang, S. (2018). 99TcO4− remediation by a cationic polymeric network. Nature Communications. https://doi.org/10.1038/s41467-018-05380-5
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