The DOI matches its Crossref record; 32 of the 32 references it cites were found in a registry or an index.
Multifunctional molecular modulators for perovskite solar cells with over 20% efficiency and high operational stability
Open accessAbstract
Perovskite solar cells present one of the most prominent photovoltaic technologies, yet their stability, scalability, and engineering at the molecular level remain challenging. We demonstrate a concept of multifunctional molecular modulation of scalable and operationally stable perovskite solar cells that exhibit exceptional solar-to-electric power conversion efficiencies. The judiciously designed bifunctional molecular modulator SN links the mercapto-tetrazolium (S) and phenylammonium (N) moieties, which passivate the surface defects, while displaying a structure-directing function through interaction with the perovskite that induces the formation of large grain crystals of high electronic quality of the most thermally stable formamidinium cesium mixed lead iodide perovskite formulation. As a result, we achieve greatly enhanced solar cell performance with efficiencies exceeding 20% for active device areas above 1 cm 2 without the use of antisolvents, accompanied by outstanding operational stability under ambient conditions.
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Cites
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Self-citationCompositional engineering of perovskite materials for high-performance solar cells
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Cited by
Multifunctional Enhancement for Highly Stable and Efficient Perovskite Solar Cells
Cai, Y., Cui, J., Chen, M., Zhang, M., Han, Y., Qian, F., Zhao, H., Yang, S., Yang, Z., Bian, H., et al. (2021) · Advanced Functional Materials · doi:10.1002/adfm.202005776 · Cited by 417
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Recent progress in morphology optimization in perovskite solar cell
Tailor, N. K., Abdi-Jalebi, M., Gupta, V., Hu, H., Dar, M. I., Li, G., & Satapathi, S. (2020) · Journal of Materials Chemistry A · doi:10.1039/d0ta00143k · Cited by 268
Metadata
- Authors
- Bi, D., Li, X., Milić, J. V., Kubicki, D. J., Pellet, N., Luo, J., LaGrange, T., Mettraux, P., Emsley, L., Zakeeruddin, S. M., & Grätzel, M.
- Venue
- Nature Communications
- Published
- 2018-10-26
- Volume
- 9
- Issue
- 1
- Pages
- 4482-4482
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W2897375678
- Cited by
- 339
- References
- 32
- FWCI
- 16.37
- Type
- journal article
- Language
- en
- Open access
- gold
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- Bi, D., Li, X., Milić, J. V., Kubicki, D. J., Pellet, N., Luo, J., LaGrange, T., Mettraux, P., Emsley, L., Zakeeruddin, S. M., & Grätzel, M. (2018). Multifunctional molecular modulators for perovskite solar cells with over 20% efficiency and high operational stability. Nature Communications. https://doi.org/10.1038/s41467-018-06709-w
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