The DOI matches its Crossref record; 40 of the 40 references it cites were found in a registry or an index.
Self-powered H2 production with bifunctional hydrazine as sole consumable
Open accessAbstract
Splitting hydrazine into H 2 and N 2 by electro-catalyzing hydrogen evolution and hydrazine oxidation reactions is promising for replacing fossil energy with H 2. However, current hydrazine splitting is achieved using external powers to drive the two reactions, which is inapplicable to outdoor use. Here, Fe-doped CoS 2 nanosheets are developed as a bifunctional electrocatalyst for the two reactions, by which direct hydrazine fuel cells and overall-hydrazine-splitting units are realized and integrated to form a self-powered H 2 production system. Without external powers, this system employs hydrazine bifunctionally as the fuel of direct hydrazine fuel cell and the splitting target, namely a sole consumable, and exhibits an H 2 evolution rate of 9.95 mmol h−1, a 98% Faradaic efficiency and a 20-h stability, all comparable to the best reported for self-powered water splitting. These performances are due to that Fe doping decreases the free-energy changes of H adsorption and adsorbed NH 2 NH 2 dehydrogenation on CoS 2.
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Cited by
Bifunctional Electrocatalysts for Overall and Hybrid Water Splitting
Quan, L., Jiang, H., Mei, G., Sun, Y., & You, B. (2024) · Chemical Reviews · doi:10.1021/acs.chemrev.3c00332 · Cited by 874
Jin, H., Wang, X., Tang, C., Vasileff, A., Li, L., Slattery, A., & Qiao, S. (2021) · Advanced Materials · doi:10.1002/adma.202007508 · Cited by 538
Emerging materials and technologies for electrocatalytic seawater splitting
Jin, H., Xu, J., Liu, H., Shen, H., Yu, H., Jaroniec, M., Zheng, Y., & Qiao, S.-Z. (2023) · Science Advances · doi:10.1126/sciadv.adi7755 · Cited by 417
Liu, Y., Zhang, J., Li, Y., Qian, Q., Li, Z., Zhu, Y., & Zhang, G. (2020) · Nature Communications · doi:10.1038/s41467-020-15563-8 · Cited by 411
Self-citationRecent Advancements in Electrochemical Hydrogen Production via Hybrid Water Splitting
Qian, Q., Zhu, Y., Ahmad, N., Feng, Y., Zhang, H., Cheng, M., Liu, H., Xiao, C., Zhang, G., & Xie, Y. (2024) · Advanced Materials · doi:10.1002/adma.202306108 · Cited by 399
Metadata
- Authors
- Liu, X., He, J., Zhao, S., Liu, Y., Zhao, Z., Luo, J., Hu, G., Sun, X., & Ding, Y.
- Venue
- Nature Communications
- Published
- 2018-10-19
- Volume
- 9
- Issue
- 1
- Pages
- 4365-4365
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W2896188784
- Cited by
- 267
- References
- 40
- FWCI
- 4.47
- Type
- journal article
- Language
- en
- Open access
- gold
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