The DOI matches its Crossref record; 65 of the 65 references it cites were found in a registry or an index.
Achieving three-dimensional lithium sulfide growth in lithium-sulfur batteries using high-donor-number anions
Open accessAbstract
Uncontrolled growth of insulating lithium sulfide leads to passivation of sulfur cathodes, which limits high sulfur utilization in lithium-sulfur batteries. Sulfur utilization can be augmented in electrolytes based on solvents with high Gutmann Donor Number; however, violent lithium metal corrosion is a drawback. Here we report that particulate lithium sulfide growth can be achieved using a salt anion with a high donor number, such as bromide or triflate. The use of bromide leads to ~95 % sulfur utilization by suppressing electrode passivation. More importantly, the electrolytes with high-donor-number salt anions are notably compatible with lithium metal electrodes. The approach enables a high sulfur-loaded cell with areal capacity higher than 4 mA h cm−2 and high sulfur utilization ( > 90 %). This work offers a simple but practical strategy to modulate lithium sulfide growth, while conserving stability for high-performance lithium-sulfur batteries.
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Cation-doped ZnS catalysts for polysulfide conversion in lithium–sulfur batteries
Shen, Z., Jin, X., Tian, J., Li, M., Yuan, Y., Zhang, S., Fang, S., Fan, X., Xu, W., Lu, H., et al. (2022) · Nature Catalysis · doi:10.1038/s41929-022-00804-4 · Cited by 621
Shi, P., Ma, J., Liu, M., Guo, S., Huang, Y., Wang, S., Zhang, L., Chen, L., Yang, K., Liu, X., et al. (2023) · Nature Nanotechnology · doi:10.1038/s41565-023-01341-2 · Cited by 578
Designing Advanced Lithium‐Based Batteries for Low‐Temperature Conditions
Gupta, A., & Manthiram, A. (2020) · Advanced Energy Materials · doi:10.1002/aenm.202001972 · Cited by 462
Metadata
- Authors
- Chu, H., Noh, H., Kim, Y.-J., Yuk, S., Lee, J.-H., Lee, J., Kwack, H., Kim, Y., Yang, D.-K., & Kim, H.-T.
- Venue
- Nature Communications
- Published
- 2019-01-14
- Volume
- 10
- Issue
- 1
- Pages
- 188-188
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W2910256922
- Cited by
- 353
- References
- 65
- FWCI
- 13.13
- Type
- journal article
- Language
- en
- Open access
- gold
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- Chu, H., Noh, H., Kim, Y.-J., Yuk, S., Lee, J.-H., Lee, J., Kwack, H., Kim, Y., Yang, D.-K., & Kim, H.-T. (2019). Achieving three-dimensional lithium sulfide growth in lithium-sulfur batteries using high-donor-number anions. Nature Communications. https://doi.org/10.1038/s41467-018-07975-4
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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